data_TiPbCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.82
_cell_length_b   7.82
_cell_length_c   7.82
_cell_angle_alpha   156.73
_cell_angle_beta   156.73
_cell_angle_gamma   33.14
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TiPbCl
_chemical_formula_sum   'Ti1 Pb1 Cl1'
_cell_volume   74.64
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti2  1  0.0  0.0  0.64  1.0
  Pb  Pb1  1  0.0  0.0  0.5  1.0
  Cl  Cl0  1  0.0  0.0  0.86  1.0

data_TiPbCl
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.46
_cell_length_b   4.46
_cell_length_c   7.82
_cell_angle_alpha   90.0
_cell_angle_beta   106.57
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   TiPbCl
_chemical_formula_sum   'Ti2 Pb2 Cl2'
_cell_volume   149.27
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  2  0.0  0.0  0.36  1.0
  Pb  Pb1  2  0.0  0.0  0.5  1.0
  Cl  Cl2  2  0.0  0.0  0.14  1.0

Ti Pb Cl
Ti Pb Cl 0 1 o o o 0 2 o o o 
TiPbCl is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two TiPbCl clusters. Ti(1) is bonded in a linear geometry to one Pb(1) and one Cl(1) atom. The Ti(1)-Pb(1) bond length is 1.15 Å. The Ti(1)-Cl(1) bond length is 1.67 Å. Pb(1) is bonded in a single-bond geometry to one Ti(1) atom. Cl(1) is bonded in a single-bond geometry to one Ti(1) atom.