data_Gd3(In2Rh)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.85
_cell_length_b   7.85
_cell_length_c   3.86
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Gd3(In2Rh)2
_chemical_formula_sum   'Gd3 In4 Rh2'
_cell_volume   206.24
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.15  0.74  0.93  1.0
  Gd  Gd1  1  0.17  0.36  0.93  1.0
  Gd  Gd2  1  0.46  0.7  0.93  1.0
  In  In3  1  0.01  0.55  0.0  1.0
  In  In4  1  0.01  0.26  0.0  1.0
  In  In5  1  0.93  0.27  0.0  1.0
  In  In6  1  0.99  0.8  0.0  1.0
  Rh  Rh7  1  0.0  0.0  0.0  1.0
  Rh  Rh8  1  0.0  0.53  0.93  1.0

data_Gd3(In2Rh)2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.86
_cell_length_b   7.85
_cell_length_c   7.85
_cell_angle_alpha   120.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Gd3(In2Rh)2
_chemical_formula_sum   'Gd3 In4 Rh2'
_cell_volume   206.24
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.93  0.15  0.74  1.0
  Gd  Gd1  1  0.93  0.17  0.36  1.0
  Gd  Gd2  1  0.93  0.46  0.7  1.0
  In  In3  1  0.0  0.01  0.26  1.0
  In  In4  1  0.0  0.01  0.55  1.0
  In  In5  1  0.0  0.93  0.27  1.0
  In  In6  1  0.0  0.99  0.8  1.0
  Rh  Rh7  1  0.0  0.0  0.0  1.0
  Rh  Rh8  1  0.93  -0.0  0.53  1.0

Gd Gd Gd In In In In Rh Rh
Gd Gd Gd In In In In Rh Rh 0 3 o o + 0 8 o o o 0 6 - o + 0 2 o o o 1 4 o o + 1 2 o o o 3 8 o o - 4 5 - o o 6 7 + + o 
Gd3(RhIn2)2 crystallizes in the triclinic P1 space group. There are three inequivalent Gd sites. In the first Gd site, Gd(1) is bonded in a distorted T-shaped geometry to one Gd(3), one Rh(2), one In(1), and one In(4) atom. The Gd(1)-Gd(3) bond length is 2.60 Å. The Gd(1)-Rh(2) bond length is 1.45 Å. The Gd(1)-In(1) bond length is 1.41 Å. The Gd(1)-In(4) bond length is 1.59 Å. In the second Gd site, Gd(2) is bonded in a single-bond geometry to one Gd(3) and one In(2) atom. The Gd(2)-Gd(3) bond length is 2.53 Å. The Gd(2)-In(2) bond length is 1.18 Å. In the third Gd site, Gd(3) is bonded in a 7-coordinate geometry to one Gd(1), one Gd(2), two equivalent Gd(3), one Rh(1), one In(3), and one In(4) atom. Both Gd(3)-Gd(3) bond lengths are 3.86 Å. The Gd(3)-Rh(1) bond length is 3.69 Å. The Gd(3)-In(3) bond length is 4.11 Å. The Gd(3)-In(4) bond length is 3.82 Å. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a distorted linear geometry to one Gd(3), one In(2), and one In(4) atom. The Rh(1)-In(2) bond length is 1.98 Å. The Rh(1)-In(4) bond length is 1.49 Å. In the second Rh site, Rh(2) is bonded in a single-bond geometry to one Gd(1) and one In(1) atom. The Rh(2)-In(1) bond length is 0.28 Å. There are four inequivalent In sites. In the first In site, In(1) is bonded in a single-bond geometry to one Gd(1) and one Rh(2) atom. In the second In site, In(2) is bonded in a 3-coordinate geometry to one Gd(2), one Rh(1), and one In(3) atom. The In(2)-In(3) bond length is 0.67 Å. In the third In site, In(3) is bonded in a distorted single-bond geometry to one Gd(3) and one In(2) atom. In the fourth In site, In(4) is bonded in a distorted bent 120 degrees geometry to one Gd(1), one Gd(3), and one Rh(1) atom.