data_LiZnCu2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.61
_cell_length_b   3.77
_cell_length_c   5.21
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiZnCu2
_chemical_formula_sum   'Li1 Zn1 Cu2'
_cell_volume   51.12
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li2  1  0.0  0.0  0.56  1.0
  Zn  Zn3  1  0.3  0.88  0.95  1.0
  Cu  Cu0  1  0.0  0.0  0.02  1.0
  Cu  Cu1  1  0.3  0.88  0.29  1.0

data_LiZnCu2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.61
_cell_length_b   3.77
_cell_length_c   5.21
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiZnCu2
_chemical_formula_sum   'Li1 Zn1 Cu2'
_cell_volume   51.12
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.0  0.0  0.56  1.0
  Zn  Zn1  1  0.3  0.88  0.95  1.0
  Cu  Cu2  1  0.0  0.0  0.02  1.0
  Cu  Cu3  1  0.3  0.88  0.29  1.0

Li Zn Cu Cu
Li Zn Cu Cu 0 3 o - o 1 2 o + + 1 3 o o + 2 3 o - o 
LiCuCuZn is High Pressure Cadmuum Telluride structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one cuprojodid molecule and one CuZn cluster. In the CuZn cluster, Cu(1) is bonded in a distorted single-bond geometry to one Zn(1) atom. The Cu(1)-Zn(1) bond length is 0.98 Å. Zn(1) is bonded in a distorted single-bond geometry to one Cu(1) atom.