data_VReTe2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.44
_cell_length_b   8.44
_cell_length_c   8.44
_cell_angle_alpha   22.06
_cell_angle_beta   22.06
_cell_angle_gamma   22.06
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VReTe2
_chemical_formula_sum   'V1 Re1 Te2'
_cell_volume   74.35
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.0  1.0
  Re  Re0  1  0.0  0.0  0.35  1.0
  Te  Te1  1  0.0  0.0  0.49  1.0
  Te  Te2  1  0.0  0.0  0.2  1.0

data_VReTe2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.59
_cell_length_b   3.23
_cell_length_c   8.44
_cell_angle_alpha   90.0
_cell_angle_beta   102.76
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   VReTe2
_chemical_formula_sum   'V2 Re2 Te4'
_cell_volume   148.7
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.0  0.0  0.0  1.0
  Re  Re1  2  0.0  0.0  0.65  1.0
  Te  Te2  2  0.0  0.0  0.51  1.0
  Te  Te3  2  0.0  0.0  0.8  1.0

V Re Te Te
V Re Te Te 0 3 o o o 1 3 o o o 1 2 o o o 
VReTe2 is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two VReTe2 clusters. V(1) is bonded in a single-bond geometry to one Te(2) atom. The V(1)-Te(2) bond length is 1.70 Å. Re(1) is bonded in a linear geometry to one Te(1) and one Te(2) atom. The Re(1)-Te(1) bond length is 1.24 Å. The Re(1)-Te(2) bond length is 1.24 Å. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a single-bond geometry to one Re(1) atom. In the second Te site, Te(2) is bonded in a linear geometry to one V(1) and one Re(1) atom.