data_K2InCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.91
_cell_length_b   6.0
_cell_length_c   6.13
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   K2InCl
_chemical_formula_sum   'K2 In1 Cl1'
_cell_volume   144.01
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K2  1  0.96  1.0  0.0  1.0
  K  K3  1  0.96  0.0  0.07  1.0
  In  In1  1  0.0  1.0  0.07  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_K2InCl
_symmetry_space_group_name_H-M   Pm
_cell_length_a   3.91
_cell_length_b   6.0
_cell_length_c   6.13
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   6
_chemical_formula_structural   K2InCl
_chemical_formula_sum   'K2 In1 Cl1'
_cell_volume   144.01
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.96  0.5  0.0  1.0
  K  K1  1  0.96  0.5  0.07  1.0
  In  In2  1  -0.0  0.5  0.07  1.0
  Cl  Cl3  1  0.0  0.5  0.0  1.0

K K In Cl
K K In Cl 0 3 + + o 1 2 + - o 
K2InCl crystallizes in the monoclinic Pm space group. The structure is zero-dimensional and consists of one K2InCl cluster. There are two inequivalent K sites. In the first K site, K(1) is bonded in a single-bond geometry to one Cl(1) atom. The K(1)-Cl(1) bond length is 0.17 Å. In the second K site, K(2) is bonded in a single-bond geometry to one In(1) atom. The K(2)-In(1) bond length is 0.17 Å. In(1) is bonded in an L-shaped geometry to one K(2) and one Cl(1) atom. The In(1)-Cl(1) bond length is 0.41 Å. Cl(1) is bonded in an L-shaped geometry to one K(1) and one In(1) atom.