data_Fe3Co5
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.69
_cell_length_b   4.69
_cell_length_c   4.7
_cell_angle_alpha   94.74
_cell_angle_beta   117.18
_cell_angle_gamma   95.55
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Fe3Co5
_chemical_formula_sum   'Fe3 Co5'
_cell_volume   90.55
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe5  1  0.52  0.98  0.6  1.0
  Fe  Fe6  1  0.0  0.0  0.0  1.0
  Fe  Fe7  1  0.57  0.09  0.54  1.0
  Co  Co0  1  0.45  0.17  0.02  1.0
  Co  Co1  1  0.97  0.27  0.53  1.0
  Co  Co2  1  0.27  0.7  0.07  1.0
  Co  Co3  1  0.12  0.81  0.61  1.0
  Co  Co4  1  0.64  0.91  0.12  1.0

data_Fe3Co5
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.69
_cell_length_b   4.69
_cell_length_c   4.7
_cell_angle_alpha   94.74
_cell_angle_beta   117.18
_cell_angle_gamma   95.55
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Fe3Co5
_chemical_formula_sum   'Fe3 Co5'
_cell_volume   90.55
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Fe  Fe0  1  0.0  0.0  0.0  1.0
  Fe  Fe1  1  0.52  0.98  0.6  1.0
  Fe  Fe2  1  0.57  0.09  0.54  1.0
  Co  Co3  1  0.12  0.81  0.61  1.0
  Co  Co4  1  0.27  0.7  0.07  1.0
  Co  Co5  1  0.45  0.17  0.02  1.0
  Co  Co6  1  0.64  0.91  0.12  1.0
  Co  Co7  1  0.97  0.27  0.53  1.0

Fe Fe Fe Co Co Co Co Co
Fe Fe Fe Co Co Co Co Co 0 2 o + o 0 1 + + + 0 4 o + o 0 6 o o o 1 7 - - o 1 2 - o - 1 5 o - o 1 6 o - - 1 3 o o o 1 4 - o - 2 4 o o o 2 6 o - o 3 7 o - o 3 4 o o o 3 4 - o - 3 6 o - - 4 7 o - o 4 6 + - o 4 6 + o o 5 6 o o - 5 7 o o o 6 7 - o o 6 7 o o + 
Fe3Co5 crystallizes in the triclinic P1 space group. There are three inequivalent Fe sites. In the first Fe site, Fe(1) is bonded in a distorted single-bond geometry to one Fe(3) and one Co(4) atom. The Fe(1)-Fe(3) bond length is 0.68 Å. The Fe(1)-Co(4) bond length is 1.99 Å. In the second Fe site, Fe(2) is bonded in a 3-coordinate geometry to one Co(1), one Co(3), one Co(4), and one Co(5) atom. The Fe(2)-Co(1) bond length is 2.13 Å. The Fe(2)-Co(3) bond length is 1.93 Å. The Fe(2)-Co(4) bond length is 2.30 Å. The Fe(2)-Co(5) bond length is 2.02 Å. In the third Fe site, Fe(3) is bonded in a distorted single-bond geometry to one Fe(1) and one Co(2) atom. The Fe(3)-Co(2) bond length is 1.99 Å. There are five inequivalent Co sites. In the first Co site, Co(1) is bonded in a 1-coordinate geometry to one Fe(2), one Co(4), and one Co(5) atom. The Co(1)-Co(4) bond length is 2.28 Å. The Co(1)-Co(5) bond length is 1.55 Å. In the second Co site, Co(2) is bonded in a distorted single-bond geometry to one Fe(3) and two equivalent Co(4) atoms. There is one shorter (2.35 Å) and one longer (2.51 Å) Co(2)-Co(4) bond length. In the third Co site, Co(3) is bonded in a 2-coordinate geometry to one Fe(2), one Co(4), and one Co(5) atom. The Co(3)-Co(4) bond length is 2.05 Å. The Co(3)-Co(5) bond length is 1.80 Å. In the fourth Co site, Co(4) is bonded in a 7-coordinate geometry to one Fe(1), one Fe(2), one Co(1), one Co(3), one Co(5), and two equivalent Co(2) atoms. The Co(4)-Co(5) bond length is 2.51 Å. In the fifth Co site, Co(5) is bonded in a 3-coordinate geometry to one Fe(2), one Co(1), one Co(3), and one Co(4) atom.