data_PRu2W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.88
_cell_length_b   2.88
_cell_length_c   6.68
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   PRu2W
_chemical_formula_sum   'P1 Ru2 W1'
_cell_volume   55.51
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  1  0.0  0.0  0.11  1.0
  Ru  Ru1  1  0.44  0.44  0.42  1.0
  Ru  Ru2  1  0.0  0.0  0.7  1.0
  W  W3  1  0.44  0.44  0.47  1.0

data_PRu2W
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.08
_cell_length_b   4.08
_cell_length_c   6.68
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   PRu2W
_chemical_formula_sum   'P2 Ru4 W2'
_cell_volume   111.02
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  P  P0  2  0.0  0.0  0.11  1.0
  Ru  Ru1  2  0.0  0.0  0.7  1.0
  Ru  Ru2  2  0.44  0.0  0.42  1.0
  W  W3  2  0.44  0.0  0.47  1.0

P Ru Ru W
P Ru Ru W 0 3 - - o 0 3 - o o 0 3 o - o 0 3 o o o 0 1 - - o 0 1 - o o 0 1 o - o 0 1 o o o 0 0 + o o 0 0 o + o 0 2 o o - 1 3 o o o 1 2 + + o 1 2 + o o 1 2 o + o 1 2 o o o 2 3 - - o 2 3 - o o 2 3 o - o 2 3 o o o 2 2 + o o 2 2 o + o 
WRu2P crystallizes in the monoclinic Cm space group. W(1) is bonded in a single-bond geometry to one Ru(1) and four Ru(2,2) atoms. The W(1)-Ru(1) bond length is 0.34 Å. There are a spread of W(1)-Ru(2,2) bond distances ranging from 2.36-2.74 Å. There are three inequivalent Ru sites. In the first Ru site, Ru(1) is bonded in a single-bond geometry to one W(1) and four equivalent P(1) atoms. There are a spread of Ru(1)-P(1) bond distances ranging from 2.78-3.11 Å. In the second Ru site, Ru(2) is bonded in a 9-coordinate geometry to four equivalent W(1), four equivalent Ru(2), and one P(1) atom. All Ru(2)-Ru(2) bond lengths are 2.88 Å. The Ru(2)-P(1) bond length is 2.69 Å. In the third Ru site, Ru(2) is bonded in a 9-coordinate geometry to four equivalent W(1), four equivalent Ru(2), and one P(1) atom. The Ru(2)-P(1) bond length is 2.69 Å. P(1) is bonded in a 9-coordinate geometry to one Ru(2), four equivalent Ru(1), and four equivalent P(1) atoms. All P(1)-P(1) bond lengths are 2.88 Å.