data_AlCdSnW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.77
_cell_length_b   4.77
_cell_length_c   4.77
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AlCdSnW
_chemical_formula_sum   'Al1 Cd1 Sn1 W1'
_cell_volume   76.72
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  1  0.0  0.0  0.0  1.0
  Cd  Cd1  1  0.06  0.06  0.06  1.0
  Sn  Sn2  1  0.37  0.37  0.37  1.0
  W  W3  1  0.69  0.69  0.69  1.0

data_AlCdSnW
_symmetry_space_group_name_H-M   R3m
_cell_length_a   4.77
_cell_length_b   4.77
_cell_length_c   11.68
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   AlCdSnW
_chemical_formula_sum   'Al3 Cd3 Sn3 W3'
_cell_volume   230.17
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Al  Al0  3  0.0  0.0  0.0  1.0
  Cd  Cd1  3  0.0  0.0  0.94  1.0
  Sn  Sn2  3  0.0  0.0  0.63  1.0
  W  W3  3  0.0  0.0  0.31  1.0

Al Cd Sn W
Al Cd Sn W 0 1 o o o 0 2 o o - 0 2 o - o 0 2 - o o 0 3 o - - 0 3 - o - 0 3 - - o 1 2 o o - 1 2 o - o 1 2 - o o 1 3 o - - 1 3 - o - 1 3 - - o 2 3 - o o 2 3 o - o 2 3 o o - 
WCdAlSn crystallizes in the trigonal R3m space group. W(1) is bonded in a 10-coordinate geometry to three equivalent Cd(1), three equivalent Al(1), and four equivalent Sn(1) atoms. All W(1)-Cd(1) bond lengths are 2.79 Å. All W(1)-Al(1) bond lengths are 2.76 Å. There are three shorter (2.76 Å) and one longer (3.66 Å) W(1)-Sn(1) bond length. Cd(1) is bonded in a single-bond geometry to three equivalent W(1), one Al(1), and three equivalent Sn(1) atoms. The Cd(1)-Al(1) bond length is 0.69 Å. All Cd(1)-Sn(1) bond lengths are 2.76 Å. Al(1) is bonded in a single-bond geometry to three equivalent W(1), one Cd(1), and three equivalent Sn(1) atoms. All Al(1)-Sn(1) bond lengths are 2.79 Å. Sn(1) is bonded in a 10-coordinate geometry to four equivalent W(1), three equivalent Cd(1), and three equivalent Al(1) atoms.