data_CdSb2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.23
_cell_length_b   6.23
_cell_length_c   3.18
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   122.83
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CdSb2Cl
_chemical_formula_sum   'Cd1 Sb2 Cl1'
_cell_volume   103.75
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.98  0.0  0.0  1.0
  Sb  Sb2  1  0.49  0.74  0.59  1.0
  Sb  Sb3  1  0.49  0.26  0.59  1.0
  Cl  Cl1  1  0.0  0.0  0.0  1.0

data_CdSb2Cl
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.18
_cell_length_b   5.96
_cell_length_c   6.23
_cell_angle_alpha   118.58
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CdSb2Cl
_chemical_formula_sum   'Cd1 Sb2 Cl1'
_cell_volume   103.75
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.0  0.0  0.98  1.0
  Sb  Sb1  1  0.59  0.26  0.75  1.0
  Sb  Sb2  1  0.59  0.74  0.23  1.0
  Cl  Cl3  1  0.0  0.0  0.0  1.0

Cd Sb Sb Cl
Cd Sb Sb Cl 0 3 + o o 0 1 o - o 0 1 o - - 0 2 + o o 0 2 + o - 1 2 o + o 1 2 o o o 1 3 + + o 1 3 + + + 1 1 o o + 2 3 o o o 2 3 o o + 2 2 o o + 
CdSb2Cl crystallizes in the triclinic P1 space group. Cd(1) is bonded in a single-bond geometry to two equivalent Sb(1) and one Cl(1) atom. There is one shorter (2.88 Å) and one longer (3.18 Å) Cd(1)-Sb(1) bond length. The Cd(1)-Cl(1) bond length is 0.12 Å. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 6-coordinate geometry to two equivalent Cd(1), two equivalent Sb(1), and two equivalent Sb(2) atoms. Both Sb(1)-Sb(1) bond lengths are 3.18 Å. There is one shorter (2.93 Å) and one longer (3.30 Å) Sb(1)-Sb(2) bond length. In the second Sb site, Sb(2) is bonded in a distorted single-bond geometry to two equivalent Sb(1) and one Cl(1) atom. The Sb(2)-Cl(1) bond length is 2.88 Å. Cl(1) is bonded in a single-bond geometry to one Cd(1) and one Sb(2) atom.