data_Pd2W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.81
_cell_length_b   2.81
_cell_length_c   6.82
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Pd2W
_chemical_formula_sum   'Pd2 W1'
_cell_volume   46.8
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  0.41  0.81  0.23  1.0
  Pd  Pd1  1  0.0  0.62  0.59  1.0
  W  W2  1  0.0  0.0  0.0  1.0

data_Pd2W
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.81
_cell_length_b   2.81
_cell_length_c   6.82
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Pd2W
_chemical_formula_sum   'Pd2 W1'
_cell_volume   46.8
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Pd  Pd0  1  -0.0  0.62  0.59  1.0
  Pd  Pd1  1  0.41  0.81  0.23  1.0
  W  W2  1  0.0  0.0  0.0  1.0

Pd Pd W
Pd Pd W 0 2 o o o 0 2 o + o 0 2 + + o 0 1 o o o 0 1 + + o 0 1 + o o 1 1 + + o 1 1 o + o 1 1 + o o 1 2 o + + 1 2 o o + 
WPd2 crystallizes in the triclinic P1 space group. W(1) is bonded in a 2-coordinate geometry to two equivalent Pd(1) and two equivalent Pd(2) atoms. Both W(1)-Pd(1) bond lengths are 2.16 Å. There is one shorter (2.97 Å) and one longer (3.28 Å) W(1)-Pd(2) bond length. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 2-coordinate geometry to two equivalent W(1) and one Pd(2) atom. The Pd(1)-Pd(2) bond length is 2.67 Å. In the second Pd site, Pd(2) is bonded in a 9-coordinate geometry to two equivalent W(1), one Pd(1), and six equivalent Pd(2) atoms. All Pd(2)-Pd(2) bond lengths are 2.81 Å.