data_Cd2TcCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.65
_cell_length_b   5.65
_cell_length_c   5.17
_cell_angle_alpha   106.99
_cell_angle_beta   106.99
_cell_angle_gamma   30.22
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cd2TcCl
_chemical_formula_sum   'Cd2 Tc1 Cl1'
_cell_volume   79.11
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.32  0.0  0.35  1.0
  Cd  Cd1  1  0.45  0.0  0.55  1.0
  Tc  Tc3  1  0.15  0.0  0.08  1.0
  Cl  Cl2  1  0.08  0.0  0.41  1.0

data_Cd2TcCl
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.94
_cell_length_b   5.17
_cell_length_c   5.65
_cell_angle_alpha   106.99
_cell_angle_beta   105.11
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cd2TcCl
_chemical_formula_sum   'Cd2 Tc1 Cl1'
_cell_volume   79.11
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.0  0.35  0.32  1.0
  Cd  Cd1  1  0.0  0.55  0.45  1.0
  Tc  Tc2  1  0.0  0.08  0.15  1.0
  Cl  Cl3  1  0.0  0.41  0.08  1.0

Cd Cd Tc Cl
Cd Cd Tc Cl 0 1 o o o 0 2 o o o 0 3 o o o 
TcCd2Cl crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one TcCd2Cl cluster. Tc(1) is bonded in a 2-coordinate geometry to one Cd(1) and one Cl(1) atom. The Tc(1)-Cd(1) bond length is 1.47 Å. The Tc(1)-Cl(1) bond length is 1.87 Å. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a distorted single-bond geometry to one Tc(1), one Cd(2), and one Cl(1) atom. The Cd(1)-Cd(2) bond length is 1.04 Å. The Cd(1)-Cl(1) bond length is 1.49 Å. In the second Cd site, Cd(2) is bonded in a 2-coordinate geometry to one Cd(1) and one Cl(1) atom. The Cd(2)-Cl(1) bond length is 2.00 Å. Cl(1) is bonded in a distorted single-bond geometry to one Tc(1), one Cd(1), and one Cd(2) atom.