data_VMo2Ru
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.08
_cell_length_b   3.08
_cell_length_c   6.24
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VMo2Ru
_chemical_formula_sum   'V1 Mo2 Ru1'
_cell_volume   59.09
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.7  1.0
  Mo  Mo0  1  0.54  0.54  0.19  1.0
  Mo  Mo1  1  0.0  0.0  0.5  1.0
  Ru  Ru2  1  0.54  0.54  0.21  1.0

data_VMo2Ru
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.35
_cell_length_b   4.35
_cell_length_c   6.24
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   VMo2Ru
_chemical_formula_sum   'V2 Mo4 Ru2'
_cell_volume   118.19
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.0  0.0  0.7  1.0
  Mo  Mo1  2  0.0  0.0  0.5  1.0
  Mo  Mo2  2  0.04  0.5  0.19  1.0
  Ru  Ru3  2  0.04  0.5  0.21  1.0

V Mo Mo Ru
V Mo Mo Ru 0 2 o o o 1 3 o o o 
MoVRuMo is Cubic alpha N2-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two molybdenum--ruthenium (1/1) molecules and two MoV clusters. In each MoV cluster, V(1) is bonded in a single-bond geometry to one Mo(2) atom. The V(1)-Mo(2) bond length is 1.21 Å. Mo(2) is bonded in a single-bond geometry to one V(1) atom.