data_Co2Sn2P
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.38
_cell_length_b   6.38
_cell_length_c   3.93
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Co2Sn2P
_chemical_formula_sum   'Co4 Sn4 P2'
_cell_volume   159.99
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.19  0.99  0.0  1.0
  Co  Co1  1  0.2  0.39  0.0  1.0
  Co  Co2  1  0.39  0.19  0.0  1.0
  Co  Co3  1  0.99  0.2  0.0  1.0
  Sn  Sn6  1  0.03  0.22  0.96  1.0
  Sn  Sn7  1  0.36  0.17  0.96  1.0
  Sn  Sn8  1  0.17  0.03  0.96  1.0
  Sn  Sn9  1  0.22  0.36  0.96  1.0
  P  P4  1  0.0  0.0  0.0  1.0
  P  P5  1  0.19  0.19  0.0  1.0

data_Co2Sn2P
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.93
_cell_length_b   6.38
_cell_length_c   6.38
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Co2Sn2P
_chemical_formula_sum   'Co4 Sn4 P2'
_cell_volume   159.99
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.0  0.39  0.19  1.0
  Co  Co1  1  0.0  0.2  0.39  1.0
  Co  Co2  1  0.0  0.19  0.99  1.0
  Co  Co3  1  0.0  0.99  0.2  1.0
  Sn  Sn4  1  0.96  0.03  0.22  1.0
  Sn  Sn5  1  0.96  0.17  0.03  1.0
  Sn  Sn6  1  0.96  0.22  0.36  1.0
  Sn  Sn7  1  0.96  0.36  0.17  1.0
  P  P8  1  0.0  0.0  0.0  1.0
  P  P9  1  0.0  0.19  0.19  1.0

Co Co Co Co Sn Sn Sn Sn P P
Co Co Co Co Sn Sn Sn Sn P P 0 6 o + - 0 8 o + o 0 9 o + o 1 7 o o - 1 9 o o o 2 5 o o - 2 9 o o o 3 4 + o - 3 8 + o o 3 9 + o o 4 9 o o + 5 9 o o + 6 8 o o + 6 9 o o + 7 9 o o + 
Co2Sn2P is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Co2Sn2P cluster. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded in a single-bond geometry to one Sn(3) atom. The Co(1)-Sn(3) bond length is 0.28 Å. In the second Co site, Co(2) is bonded in a single-bond geometry to one Sn(4) atom. The Co(2)-Sn(4) bond length is 0.28 Å. In the third Co site, Co(3) is bonded in a single-bond geometry to one Sn(2) atom. The Co(3)-Sn(2) bond length is 0.28 Å. In the fourth Co site, Co(4) is bonded in a distorted bent 120 degrees geometry to one Sn(1) and one P(1) atom. The Co(4)-Sn(1) bond length is 0.28 Å. The Co(4)-P(1) bond length is 1.25 Å. There are four inequivalent Sn sites. In the first Sn site, Sn(1) is bonded in a bent 120 degrees geometry to one Co(4) and one P(2) atom. The Sn(1)-P(2) bond length is 1.08 Å. In the second Sn site, Sn(2) is bonded in a bent 120 degrees geometry to one Co(3) and one P(2) atom. The Sn(2)-P(2) bond length is 1.08 Å. In the third Sn site, Sn(3) is bonded in a 3-coordinate geometry to one Co(1), one P(1), and one P(2) atom. The Sn(3)-P(1) bond length is 1.08 Å. The Sn(3)-P(2) bond length is 1.08 Å. In the fourth Sn site, Sn(4) is bonded in a bent 120 degrees geometry to one Co(2) and one P(2) atom. The Sn(4)-P(2) bond length is 1.08 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded in a distorted L-shaped geometry to one Co(4) and one Sn(3) atom. In the second P site, P(2) is bonded in a square co-planar geometry to one Sn(1), one Sn(2), one Sn(3), and one Sn(4) atom.