data_LaTlV
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.32
_cell_length_b   6.32
_cell_length_c   6.32
_cell_angle_alpha   149.4
_cell_angle_beta   144.76
_cell_angle_gamma   47.35
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaTlV
_chemical_formula_sum   'La1 Tl1 V1'
_cell_volume   73.84
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.0  0.0  0.12  1.0
  Tl  Tl1  1  0.0  0.0  0.47  1.0
  V  V2  1  0.0  0.0  0.99  1.0

data_LaTlV
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.33
_cell_length_b   3.83
_cell_length_c   6.32
_cell_angle_alpha   107.62
_cell_angle_beta   105.3
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaTlV
_chemical_formula_sum   'La1 Tl1 V1'
_cell_volume   73.84
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.88  0.88  0.88  1.0
  Tl  Tl1  1  0.53  0.53  0.53  1.0
  V  V2  1  0.01  0.01  0.01  1.0

La Tl V
La Tl V 0 2 o o - 0 1 o o o 
LaVTl is alpha Niobium phosphide-derived structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one LaVTl cluster. La(1) is bonded in a distorted single-bond geometry to one V(1) and one Tl(1) atom. The La(1)-V(1) bond length is 0.84 Å. The La(1)-Tl(1) bond length is 2.21 Å. V(1) is bonded in a single-bond geometry to one La(1) atom. Tl(1) is bonded in a single-bond geometry to one La(1) atom.