data_NaInW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.88
_cell_length_b   7.88
_cell_length_c   7.88
_cell_angle_alpha   159.27
_cell_angle_beta   159.27
_cell_angle_gamma   29.49
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaInW
_chemical_formula_sum   'Na1 In1 W1'
_cell_volume   61.35
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na1  1  0.0  0.0  0.06  1.0
  In  In0  1  0.0  0.0  0.14  1.0
  W  W2  1  0.0  0.0  0.05  1.0

data_NaInW
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.01
_cell_length_b   4.01
_cell_length_c   7.88
_cell_angle_alpha   90.0
_cell_angle_beta   104.74
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   NaInW
_chemical_formula_sum   'Na2 In2 W2'
_cell_volume   122.7
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  2  0.0  0.0  0.94  1.0
  In  In1  2  0.0  0.0  0.86  1.0
  W  W2  2  0.0  0.0  0.95  1.0

Na In W
Na In W 0 2 o o o 0 1 o o o 1 2 o o o 
NaWIn is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two NaWIn clusters. Na(1) is bonded in a linear geometry to one W(1) and one In(1) atom. The Na(1)-W(1) bond length is 0.08 Å. The Na(1)-In(1) bond length is 0.67 Å. W(1) is bonded in a single-bond geometry to one Na(1) atom. In(1) is bonded in a single-bond geometry to one Na(1) atom.