data_V2ZnSb
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.34
_cell_length_b   3.34
_cell_length_c   5.68
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2ZnSb
_chemical_formula_sum   'V2 Zn1 Sb1'
_cell_volume   63.21
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V1  1  0.67  0.67  0.27  1.0
  V  V2  1  0.67  0.67  0.42  1.0
  Zn  Zn3  1  0.0  0.0  0.0  1.0
  Sb  Sb0  1  0.0  0.0  0.84  1.0

data_V2ZnSb
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.72
_cell_length_b   4.72
_cell_length_c   5.68
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   V2ZnSb
_chemical_formula_sum   'V4 Zn2 Sb2'
_cell_volume   126.41
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.17  0.5  0.27  1.0
  V  V1  2  0.17  0.5  0.42  1.0
  Zn  Zn2  2  0.0  0.0  0.0  1.0
  Sb  Sb3  2  0.0  0.0  0.84  1.0

V V Zn Sb
V V Zn Sb 0 1 o o o 2 3 o o - 
(V)2ZnSb is High Pressure Cadmuum Telluride structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two vanadium molecules and two ZnSb clusters. In each ZnSb cluster, Zn(1) is bonded in a single-bond geometry to one Sb(1) atom. The Zn(1)-Sb(1) bond length is 0.90 Å. Sb(1) is bonded in a single-bond geometry to one Zn(1) atom.