data_ScVZnCr
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.38
_cell_length_b   4.38
_cell_length_c   4.38
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ScVZnCr
_chemical_formula_sum   'Sc1 V1 Zn1 Cr1'
_cell_volume   59.61
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc1  1  0.0  0.0  0.0  1.0
  V  V2  1  0.55  0.55  0.55  1.0
  Zn  Zn3  1  0.65  0.65  0.65  1.0
  Cr  Cr0  1  0.1  0.1  0.1  1.0

data_ScVZnCr
_symmetry_space_group_name_H-M   R3m
_cell_length_a   4.38
_cell_length_b   4.38
_cell_length_c   10.74
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   ScVZnCr
_chemical_formula_sum   'Sc3 V3 Zn3 Cr3'
_cell_volume   178.84
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  3  0.0  0.0  0.0  1.0
  V  V1  3  0.0  0.0  0.45  1.0
  Zn  Zn2  3  0.0  0.0  0.35  1.0
  Cr  Cr3  3  0.0  0.0  0.9  1.0

Sc V Zn Cr
Sc V Zn Cr 0 3 o o o 1 2 o o o 
ScCrVZn is Cubane-derived structured and crystallizes in the trigonal R3m space group. The structure is zero-dimensional and consists of three ScCr clusters and three VZn clusters. In each ScCr cluster, Sc(1) is bonded in a single-bond geometry to one Cr(1) atom. The Sc(1)-Cr(1) bond length is 1.08 Å. Cr(1) is bonded in a single-bond geometry to one Sc(1) atom. In each VZn cluster, V(1) is bonded in a single-bond geometry to one Zn(1) atom. The V(1)-Zn(1) bond length is 1.08 Å. Zn(1) is bonded in a distorted single-bond geometry to one V(1) atom.