data_InNi2W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.82
_cell_length_b   2.82
_cell_length_c   7.22
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   InNi2W
_chemical_formula_sum   'In1 Ni2 W1'
_cell_volume   57.55
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  1  0.0  0.0  0.0  1.0
  Ni  Ni1  1  0.41  0.41  0.9  1.0
  Ni  Ni2  1  0.41  0.41  0.32  1.0
  W  W3  1  0.0  0.0  0.61  1.0

data_InNi2W
_symmetry_space_group_name_H-M   Cm
_cell_length_a   3.99
_cell_length_b   3.99
_cell_length_c   7.22
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   InNi2W
_chemical_formula_sum   'In2 Ni4 W2'
_cell_volume   115.11
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  2  0.0  0.0  0.0  1.0
  Ni  Ni1  2  0.41  0.0  0.32  1.0
  Ni  Ni2  2  0.41  0.0  0.9  1.0
  W  W3  2  0.0  0.0  0.61  1.0

In Ni Ni W
In Ni Ni W 0 1 - o - 0 1 o - - 0 1 o o - 0 2 o o o 0 2 o - o 0 2 - o o 0 2 - - o 0 3 o o - 1 2 o o + 1 3 + + o 1 3 + o o 1 3 o + o 1 3 o o o 2 3 o o o 2 3 o + o 2 3 + o o 2 3 + + o 2 2 + o o 2 2 o + o 3 3 + o o 3 3 o + o 
WNi2In crystallizes in the monoclinic Cm space group. W(1) is bonded in a 13-coordinate geometry to four equivalent W(1), four equivalent Ni(1), four equivalent Ni(2), and one In(1) atom. All W(1)-W(1) bond lengths are 2.82 Å. There are a spread of W(1)-Ni(1) bond distances ranging from 2.68-3.16 Å. There are a spread of W(1)-Ni(2) bond distances ranging from 2.68-3.16 Å. The W(1)-In(1) bond length is 2.81 Å. There are two inequivalent Ni sites. In the first Ni site, Ni(1) is bonded in a 3-coordinate geometry to four equivalent W(1), one Ni(2), and three equivalent In(1) atoms. The Ni(1)-Ni(2) bond length is 2.99 Å. There is one shorter (1.78 Å) and two longer (2.14 Å) Ni(1)-In(1) bond lengths. In the second Ni site, Ni(2) is bonded in a 13-coordinate geometry to four equivalent W(1), one Ni(1), four equivalent Ni(2), and four equivalent In(1) atoms. All Ni(2)-Ni(2) bond lengths are 2.82 Å. There are a spread of Ni(2)-In(1) bond distances ranging from 2.82-3.28 Å. In(1) is bonded in a 3-coordinate geometry to one W(1), three equivalent Ni(1), and four equivalent Ni(2) atoms.