data_SbP2Au
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.77
_cell_length_b   4.77
_cell_length_c   3.3
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SbP2Au
_chemical_formula_sum   'Sb1 P2 Au1'
_cell_volume   74.88
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb3  1  0.0  0.0  0.0  1.0
  P  P1  1  0.38  0.0  0.65  1.0
  P  P2  1  0.0  0.38  0.65  1.0
  Au  Au0  1  0.38  0.38  0.0  1.0

data_SbP2Au
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.74
_cell_length_b   6.74
_cell_length_c   3.3
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   SbP2Au
_chemical_formula_sum   'Sb2 P4 Au2'
_cell_volume   149.76
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  2  0.0  0.0  0.0  1.0
  P  P1  4  0.19  0.19  0.65  1.0
  Au  Au2  2  0.38  0.0  0.0  1.0

Sb P P Au
Sb P P Au 0 1 o o - 0 2 o o - 0 3 o o o 1 2 o o o 1 3 o o + 2 3 o o + 
AuSbP2 crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two AuSbP2 clusters. Au(1) is bonded in a 2-coordinate geometry to two equivalent P(1) atoms. Both Au(1)-P(1) bond lengths are 2.16 Å. Sb(1) is bonded in a 2-coordinate geometry to two equivalent P(1) atoms. Both Sb(1)-P(1) bond lengths are 2.16 Å. P(1) is bonded in a 2-coordinate geometry to one Au(1) and one Sb(1) atom.