data_CoAgP2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.38
_cell_length_b   4.38
_cell_length_c   3.01
_cell_angle_alpha   92.67
_cell_angle_beta   92.67
_cell_angle_gamma   98.71
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CoAgP2
_chemical_formula_sum   'Co1 Ag1 P2'
_cell_volume   56.92
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co1  1  0.0  0.0  0.0  1.0
  Ag  Ag0  1  0.85  0.0  0.0  1.0
  P  P2  1  0.32  0.34  0.5  1.0
  P  P3  1  0.32  0.66  0.5  1.0

data_CoAgP2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.01
_cell_length_b   4.38
_cell_length_c   4.38
_cell_angle_alpha   98.71
_cell_angle_beta   92.67
_cell_angle_gamma   92.67
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CoAgP2
_chemical_formula_sum   'Co1 Ag1 P2'
_cell_volume   56.92
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Co  Co0  1  0.0  0.0  0.0  1.0
  Ag  Ag1  1  -0.0  0.85  0.0  1.0
  P  P2  1  0.5  0.32  0.34  1.0
  P  P3  1  0.5  0.32  0.66  1.0

Co Ag P P
Co Ag P P 0 1 - o o 2 3 o o o 
CoAgP2 crystallizes in the triclinic P1 space group. Co(1) is bonded in a distorted single-bond geometry to one Ag(1), two equivalent P(1), and two equivalent P(2) atoms. The Co(1)-Ag(1) bond length is 0.65 Å. There is one shorter (2.32 Å) and one longer (2.49 Å) Co(1)-P(1) bond length. There is one shorter (2.65 Å) and one longer (2.66 Å) Co(1)-P(2) bond length. Ag(1) is bonded in a single-bond geometry to one Co(1) and two equivalent P(2) atoms. There is one shorter (2.89 Å) and one longer (3.07 Å) Ag(1)-P(2) bond length. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 3-coordinate geometry to two equivalent Co(1) and one P(2) atom. The P(1)-P(2) bond length is 1.41 Å. In the second P site, P(2) is bonded in a 5-coordinate geometry to two equivalent Co(1), two equivalent Ag(1), and one P(1) atom.