data_V2InP
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.97
_cell_length_b   2.97
_cell_length_c   6.95
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2InP
_chemical_formula_sum   'V2 In1 P1'
_cell_volume   61.2
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.48  0.48  0.28  1.0
  V  V3  1  0.48  0.48  0.67  1.0
  In  In0  1  0.0  0.0  0.48  1.0
  P  P1  1  0.0  0.0  0.0  1.0

data_V2InP
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.2
_cell_length_b   4.2
_cell_length_c   6.95
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   V2InP
_chemical_formula_sum   'V4 In2 P2'
_cell_volume   122.41
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.48  0.0  0.28  1.0
  V  V1  2  0.48  0.0  0.67  1.0
  In  In2  2  0.0  0.0  0.48  1.0
  P  P3  2  0.0  0.0  0.0  1.0

V V In P
V V In P 0 3 o o o 0 3 o + o 0 3 + o o 0 3 + + o 0 2 o o o 0 2 o + o 0 2 + o o 0 2 + + o 0 0 + o o 0 0 o + o 0 1 o o o 1 2 o o o 1 2 o + o 1 2 + o o 1 2 + + o 1 3 o o + 1 3 + + + 1 3 + o + 1 3 o + + 1 1 + o o 1 1 o + o 2 3 o o o 3 3 + o o 3 3 o + o 
V2InP crystallizes in the monoclinic Cm space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 8-coordinate geometry to one V(2), four equivalent In(1), and four equivalent P(1) atoms. The V(1)-V(2) bond length is 2.65 Å. There are a spread of V(1)-In(1) bond distances ranging from 2.42-2.54 Å. There are a spread of V(1)-P(1) bond distances ranging from 2.84-2.94 Å. In the second V site, V(2) is bonded in a 13-coordinate geometry to one V(1), four equivalent V(2), four equivalent In(1), and four equivalent P(1) atoms. All V(2)-V(2) bond lengths are 2.97 Å. There are a spread of V(2)-In(1) bond distances ranging from 2.42-2.54 Å. There are a spread of V(2)-P(1) bond distances ranging from 3.08-3.18 Å. In(1) is bonded in a body-centered cubic geometry to four equivalent V(1) and four equivalent V(2) atoms. P(1) is bonded in a 8-coordinate geometry to four equivalent V(1) and four equivalent V(2) atoms.