data_VGa2Re
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.79
_cell_length_b   3.79
_cell_length_c   4.05
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VGa2Re
_chemical_formula_sum   'V1 Ga2 Re1'
_cell_volume   57.98
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.0  1.0
  Ga  Ga0  1  0.0  0.89  0.02  1.0
  Ga  Ga1  1  0.89  0.0  0.02  1.0
  Re  Re2  1  0.89  0.89  0.0  1.0

data_VGa2Re
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.35
_cell_length_b   5.35
_cell_length_c   4.05
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   VGa2Re
_chemical_formula_sum   'V2 Ga4 Re2'
_cell_volume   115.96
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.0  0.0  0.0  1.0
  Ga  Ga1  4  0.45  0.45  0.02  1.0
  Re  Re2  2  0.39  0.5  -0.0  1.0

V Ga Ga Re
V Ga Ga Re 0 2 - o o 0 1 o - o 1 3 - o o 2 3 o - o 
VReGa2 is alpha Po structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two VReGa2 clusters. V(1) is bonded in an L-shaped geometry to two equivalent Ga(1) atoms. Both V(1)-Ga(1) bond lengths are 0.42 Å. Re(1) is bonded in an L-shaped geometry to two equivalent Ga(1) atoms. Both Re(1)-Ga(1) bond lengths are 0.42 Å. Ga(1) is bonded in an L-shaped geometry to one V(1) and one Re(1) atom.