data_K2MnIn
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.56
_cell_length_b   6.56
_cell_length_c   3.78
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   119.23
_symmetry_Int_Tables_number   1
_chemical_formula_structural   K2MnIn
_chemical_formula_sum   'K2 Mn1 In1'
_cell_volume   141.86
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K1  1  0.66  0.17  0.89  1.0
  K  K2  1  0.66  0.83  0.89  1.0
  Mn  Mn3  1  0.0  0.0  0.0  1.0
  In  In0  1  0.32  0.0  0.0  1.0

data_K2MnIn
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.78
_cell_length_b   6.56
_cell_length_c   6.56
_cell_angle_alpha   119.23
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   K2MnIn
_chemical_formula_sum   'K2 Mn1 In1'
_cell_volume   141.86
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.89  0.66  0.17  1.0
  K  K1  1  0.89  0.66  0.83  1.0
  Mn  Mn2  1  0.0  0.0  0.0  1.0
  In  In3  1  0.0  0.32  0.0  1.0

K K Mn In
K K Mn In 0 3 o o + 0 1 o - o 1 2 + + + 2 3 o o o 
K2MnIn crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one K2MnIn cluster. There are two inequivalent K sites. In the first K site, K(1) is bonded in a distorted single-bond geometry to one In(1) atom. The K(1)-In(1) bond length is 2.00 Å. In the second K site, K(2) is bonded in a distorted single-bond geometry to one Mn(1) atom. The K(2)-Mn(1) bond length is 2.00 Å. Mn(1) is bonded in a distorted bent 150 degrees geometry to one K(2) and one In(1) atom. The Mn(1)-In(1) bond length is 2.09 Å. In(1) is bonded in a 2-coordinate geometry to one K(1) and one Mn(1) atom.