data_CdAg2Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.08
_cell_length_b   5.08
_cell_length_c   5.08
_cell_angle_alpha   132.07
_cell_angle_beta   132.07
_cell_angle_gamma   70.13
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CdAg2Pd
_chemical_formula_sum   'Cd1 Ag2 Pd1'
_cell_volume   70.66
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd2  1  0.0  0.0  0.15  1.0
  Ag  Ag0  1  0.06  0.0  0.08  1.0
  Ag  Ag1  1  0.0  0.06  0.08  1.0
  Pd  Pd3  1  0.0  0.0  0.0  1.0

data_CdAg2Pd
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.83
_cell_length_b   5.83
_cell_length_c   5.08
_cell_angle_alpha   90.0
_cell_angle_beta   125.06
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   CdAg2Pd
_chemical_formula_sum   'Cd2 Ag4 Pd2'
_cell_volume   141.31
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  2  0.0  0.0  0.15  1.0
  Ag  Ag1  4  0.47  0.47  0.02  1.0
  Pd  Pd2  2  0.0  0.0  0.0  1.0

Cd Ag Ag Pd
Cd Ag Ag Pd 0 2 o o o 0 1 o o o 1 3 o o o 2 3 o o o 
PdAg2Cd is Indium-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two PdAg2Cd clusters. Pd(1) is bonded in a distorted L-shaped geometry to two equivalent Ag(1) atoms. Both Pd(1)-Ag(1) bond lengths are 0.30 Å. Ag(1) is bonded in a 3-coordinate geometry to one Pd(1), one Ag(1), and one Cd(1) atom. The Ag(1)-Ag(1) bond length is 0.36 Å. The Ag(1)-Cd(1) bond length is 0.65 Å. Cd(1) is bonded in a 2-coordinate geometry to two equivalent Ag(1) atoms.