data_V2Te
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.76
_cell_length_b   4.76
_cell_length_c   8.07
_cell_angle_alpha   101.16
_cell_angle_beta   101.16
_cell_angle_gamma   40.91
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2Te
_chemical_formula_sum   'V4 Te2'
_cell_volume   117.41
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.47  0.0  0.5  1.0
  V  V3  1  0.6  0.0  0.37  1.0
  V  V4  1  0.66  0.0  0.53  1.0
  V  V5  1  0.79  0.0  0.4  1.0
  Te  Te0  1  0.02  0.0  0.46  1.0
  Te  Te1  1  0.24  0.0  0.43  1.0

data_V2Te
_symmetry_space_group_name_H-M   P-1
_cell_length_a   3.33
_cell_length_b   4.76
_cell_length_c   8.07
_cell_angle_alpha   101.16
_cell_angle_beta   90.0
_cell_angle_gamma   110.45
_symmetry_Int_Tables_number   2
_chemical_formula_structural   V2Te
_chemical_formula_sum   'V4 Te2'
_cell_volume   117.41
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-x, -y, -z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.0  0.03  0.58  1.0
  V  V1  2  0.0  0.16  0.45  1.0
  Te  Te2  2  0.0  0.39  0.51  1.0

V V V V Te Te
V V V V Te Te 0 2 o o o 0 5 o o o 1 3 o o o 3 4 + o o 4 5 o o o 
V2Te crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one V2Te cluster. There are two inequivalent V sites. In the first V site, V(1) is bonded in a single-bond geometry to two equivalent V(2) and one Te(1) atom. There is one shorter (0.90 Å) and one longer (1.33 Å) V(1)-V(2) bond length. The V(1)-Te(1) bond length is 1.12 Å. In the second V site, V(2) is bonded in a 3-coordinate geometry to one V(2) and two equivalent V(1) atoms. The V(2)-V(2) bond length is 1.28 Å. Te(1) is bonded in a distorted single-bond geometry to one V(1) atom.