data_KV2Te
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.38
_cell_length_b   5.04
_cell_length_c   5.97
_cell_angle_alpha   90.0
_cell_angle_beta   93.7
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   KV2Te
_chemical_formula_sum   'K1 V2 Te1'
_cell_volume   101.67
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.0  0.0  0.0  1.0
  V  V2  1  0.94  0.52  0.78  1.0
  V  V3  1  0.06  0.52  0.18  1.0
  Te  Te1  1  0.5  0.0  0.98  1.0

data_KV2Te
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.38
_cell_length_b   5.04
_cell_length_c   5.97
_cell_angle_alpha   90.0
_cell_angle_beta   93.7
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   KV2Te
_chemical_formula_sum   'K1 V2 Te1'
_cell_volume   101.67
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.0  0.0  0.0  1.0
  V  V1  1  0.06  0.52  0.18  1.0
  V  V2  1  0.94  0.52  0.78  1.0
  Te  Te3  1  0.5  0.0  0.98  1.0

K V V Te
K V V Te 0 3 - o - 0 3 o o - 0 1 - o - 0 1 - - - 0 2 o o o 0 2 o - o 1 3 o + o 1 2 + o + 2 3 o + - 
KV2Te crystallizes in the triclinic P1 space group. K(1) is bonded in a distorted linear geometry to two equivalent V(1), two equivalent V(2), and two equivalent Te(1) atoms. There is one shorter (2.76 Å) and one longer (2.95 Å) K(1)-V(1) bond length. There is one shorter (2.65 Å) and one longer (2.85 Å) K(1)-V(2) bond length. There is one shorter (1.69 Å) and one longer (1.70 Å) K(1)-Te(1) bond length. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 10-coordinate geometry to two equivalent K(1), two equivalent V(1), two equivalent V(2), and four equivalent Te(1) atoms. Both V(1)-V(1) bond lengths are 3.38 Å. There is one shorter (2.42 Å) and one longer (3.60 Å) V(1)-V(2) bond length. There are a spread of V(1)-Te(1) bond distances ranging from 3.12-3.41 Å. In the second V site, V(2) is bonded in a 3-coordinate geometry to two equivalent K(1) and two equivalent V(1) atoms. Te(1) is bonded in a linear geometry to two equivalent K(1) and four equivalent V(1) atoms.