data_Tl2RhW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.36
_cell_length_b   9.36
_cell_length_c   9.36
_cell_angle_alpha   19.09
_cell_angle_beta   19.09
_cell_angle_gamma   19.09
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Tl2RhW
_chemical_formula_sum   'Tl2 Rh1 W1'
_cell_volume   76.7
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl1  1  0.0  0.0  0.56  1.0
  Tl  Tl2  1  0.0  0.0  0.01  1.0
  Rh  Rh0  1  0.0  0.0  0.0  1.0
  W  W3  1  0.0  0.0  0.78  1.0

data_Tl2RhW
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.38
_cell_length_b   3.1
_cell_length_c   9.36
_cell_angle_alpha   90.0
_cell_angle_beta   101.04
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Tl2RhW
_chemical_formula_sum   'Tl4 Rh2 W2'
_cell_volume   153.4
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  2  -0.0  0.0  0.44  1.0
  Tl  Tl1  2  0.0  0.0  0.99  1.0
  Rh  Rh2  2  0.0  0.0  0.0  1.0
  W  W3  2  -0.0  0.0  0.22  1.0

Tl Tl Rh W
Tl Tl Rh W 0 3 o o o 1 2 o o o 1 3 o o - 2 3 o o - 
WRhTl2 crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two WRhTl2 clusters. W(1) is bonded in a distorted linear geometry to one Rh(1) and one Tl(1) atom. The W(1)-Rh(1) bond length is 2.02 Å. The W(1)-Tl(1) bond length is 2.09 Å. Rh(1) is bonded in a single-bond geometry to one W(1) and one Tl(2) atom. The Rh(1)-Tl(2) bond length is 0.07 Å. There are two inequivalent Tl sites. In the first Tl site, Tl(1) is bonded in a single-bond geometry to one W(1) atom. In the second Tl site, Tl(2) is bonded in a single-bond geometry to one Rh(1) atom.