data_B(SbP)2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.38
_cell_length_b   3.38
_cell_length_c   11.24
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   B(SbP)2
_chemical_formula_sum   'B1 Sb2 P2'
_cell_volume   110.94
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.0  0.0  0.0  1.0
  Sb  Sb3  1  0.0  0.95  0.48  1.0
  Sb  Sb4  1  0.69  0.97  0.76  1.0
  P  P1  1  0.0  0.95  0.23  1.0
  P  P2  1  0.69  0.97  0.01  1.0

data_B(SbP)2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.38
_cell_length_b   3.38
_cell_length_c   11.24
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   B(SbP)2
_chemical_formula_sum   'B1 Sb2 P2'
_cell_volume   110.94
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  B  B0  1  0.0  0.0  0.0  1.0
  Sb  Sb1  1  0.0  0.95  0.48  1.0
  Sb  Sb2  1  0.69  0.97  0.76  1.0
  P  P3  1  0.0  0.95  0.23  1.0
  P  P4  1  0.69  0.97  0.01  1.0

B Sb Sb P P
B Sb Sb P P 0 4 - - o 0 2 o - - 0 2 - - - 0 3 o - o 1 1 + + o 1 1 o + o 1 1 + o o 1 2 - o o 1 3 o o o 2 2 + + o 2 2 o + o 2 2 + o o 2 4 o o + 3 4 - o o 
B(SbP)2 crystallizes in the triclinic P1 space group. B(1) is bonded in a distorted single-bond geometry to one Sb(2), one P(1), and one P(2) atom. The B(1)-Sb(2) bond length is 2.84 Å. The B(1)-P(1) bond length is 2.57 Å. The B(1)-P(2) bond length is 1.02 Å. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a single-bond geometry to one Sb(2) and one P(1) atom. The Sb(1)-Sb(2) bond length is 3.43 Å. The Sb(1)-P(1) bond length is 2.78 Å. In the second Sb site, Sb(2) is bonded in a 9-coordinate geometry to one B(1), one Sb(1), six equivalent Sb(2), and one P(2) atom. All Sb(2)-Sb(2) bond lengths are 3.38 Å. The Sb(2)-P(2) bond length is 2.78 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 3-coordinate geometry to one B(1), one Sb(1), and one P(2) atom. The P(1)-P(2) bond length is 2.66 Å. In the second P site, P(2) is bonded in a distorted single-bond geometry to one B(1), one Sb(2), and one P(1) atom.