data_Ag2GeO3
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.66
_cell_length_b   7.08
_cell_length_c   10.46
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ag2GeO3
_chemical_formula_sum   'Ag8 Ge4 O12'
_cell_volume   345.01
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.44  0.44  0.29  1.0
  Ag  Ag1  1  0.42  0.33  0.37  1.0
  Ag  Ag2  1  0.24  0.79  0.86  1.0
  Ag  Ag3  1  0.22  0.9  0.94  1.0
  Ag  Ag4  1  0.89  0.64  0.52  1.0
  Ag  Ag5  1  0.57  0.74  0.6  1.0
  Ag  Ag6  1  0.09  0.28  0.1  1.0
  Ag  Ag7  1  0.77  0.18  0.17  1.0
  Ge  Ge8  1  0.14  0.93  0.68  1.0
  Ge  Ge9  1  0.52  0.46  0.55  1.0
  Ge  Ge10  1  0.19  0.15  0.91  1.0
  Ge  Ge11  1  0.47  0.61  0.78  1.0
  O  O12  1  0.03  0.46  0.43  1.0
  O  O13  1  0.66  0.32  0.64  1.0
  O  O14  1  0.96  0.0  0.25  1.0
  O  O15  1  0.7  0.54  0.98  1.0
  O  O16  1  1.0  0.86  0.59  1.0
  O  O17  1  0.63  0.92  0.8  1.0
  O  O18  1  0.96  0.61  0.66  1.0
  O  O19  1  0.33  0.75  0.87  1.0
  O  O20  1  0.37  0.07  0.48  1.0
  O  O21  1  0.29  0.53  0.22  1.0
  O  O22  1  0.33  0.22  0.82  1.0
  O  O23  1  0.7  0.15  0.03  1.0

data_Ag2GeO3
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.66
_cell_length_b   7.08
_cell_length_c   10.46
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ag2GeO3
_chemical_formula_sum   'Ag8 Ge4 O12'
_cell_volume   345.01
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.09  0.28  0.1  1.0
  Ag  Ag1  1  0.22  0.9  0.94  1.0
  Ag  Ag2  1  0.24  0.79  0.86  1.0
  Ag  Ag3  1  0.42  0.33  0.37  1.0
  Ag  Ag4  1  0.44  0.44  0.29  1.0
  Ag  Ag5  1  0.57  0.74  0.6  1.0
  Ag  Ag6  1  0.77  0.18  0.17  1.0
  Ag  Ag7  1  0.89  0.64  0.52  1.0
  Ge  Ge8  1  0.14  0.93  0.68  1.0
  Ge  Ge9  1  0.19  0.15  0.91  1.0
  Ge  Ge10  1  0.47  0.61  0.78  1.0
  Ge  Ge11  1  0.52  0.46  0.55  1.0
  O  O12  1  0.03  0.46  0.43  1.0
  O  O13  1  0.29  0.53  0.22  1.0
  O  O14  1  0.33  0.75  0.87  1.0
  O  O15  1  0.33  0.22  0.82  1.0
  O  O16  1  0.37  0.07  0.48  1.0
  O  O17  1  0.63  0.92  0.8  1.0
  O  O18  1  0.66  0.32  0.64  1.0
  O  O19  1  0.7  0.54  0.98  1.0
  O  O20  1  0.7  0.15  0.03  1.0
  O  O21  1  0.96  0.61  0.66  1.0
  O  O22  1  0.96  0.0  0.25  1.0
  O  O23  1  1.0  0.86  0.59  1.0

Ag Ag Ag Ag Ag Ag Ag Ag Ge Ge Ge Ge O O O O O O O O O O O O
Ag Ag Ag Ag Ag Ag Ag Ag Ge Ge Ge Ge O O O O O O O O O O O O 0 1 o o o 0 21 o o o 1 20 o o o 2 19 o o o 2 3 o o o 2 15 o o o 2 17 o o o 3 17 o o o 4 5 o o o 4 12 + o o 4 18 o o o 4 16 o o o 5 9 o o o 5 11 o o o 5 18 o o o 5 16 o o o 5 17 o o o 5 20 o + o 6 23 - o o 6 7 - o o 6 10 o o - 6 15 - o - 7 23 o o o 7 14 o o o 8 16 - o o 8 17 o o o 8 20 o + o 9 13 o o o 10 22 o o o 11 19 o o o 11 15 o o o 11 17 o o o 13 20 o o o 15 21 o o + 15 19 o o o 15 23 o o + 16 20 + + o 17 19 o o o 17 22 o + o 
Ag2GeO3 crystallizes in the triclinic P1 space group. There are eight inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a distorted single-bond geometry to one Ag(2) and one O(10) atom. The Ag(1)-Ag(2) bond length is 1.11 Å. The Ag(1)-O(10) bond length is 1.24 Å. In the second Ag site, Ag(2) is bonded in a 4-coordinate geometry to one Ag(1), one Ge(2), one O(1), and one O(9) atom. The Ag(2)-Ge(2) bond length is 2.18 Å. The Ag(2)-O(1) bond length is 2.11 Å. The Ag(2)-O(9) bond length is 2.19 Å. In the third Ag site, Ag(3) is bonded in a single-bond geometry to one Ag(4), one O(6), and one O(8) atom. The Ag(3)-Ag(4) bond length is 1.11 Å. The Ag(3)-O(6) bond length is 2.11 Å. The Ag(3)-O(8) bond length is 0.49 Å. In the fourth Ag site, Ag(4) is bonded in a 4-coordinate geometry to one Ag(3), one Ge(3), one O(6), and one O(8) atom. The Ag(4)-Ge(3) bond length is 1.83 Å. The Ag(4)-O(6) bond length is 2.42 Å. The Ag(4)-O(8) bond length is 1.35 Å. In the fifth Ag site, Ag(5) is bonded in a 3-coordinate geometry to one Ag(6), one O(1), one O(5), and one O(7) atom. The Ag(5)-Ag(6) bond length is 1.83 Å. The Ag(5)-O(1) bond length is 1.70 Å. The Ag(5)-O(5) bond length is 1.80 Å. The Ag(5)-O(7) bond length is 1.53 Å. In the sixth Ag site, Ag(6) is bonded in a 9-coordinate geometry to one Ag(5), one Ge(1), one Ge(2), one Ge(4), one O(6), one O(7), one O(9), and two equivalent O(5) atoms. The Ag(6)-Ge(1) bond length is 2.53 Å. The Ag(6)-Ge(2) bond length is 2.07 Å. The Ag(6)-Ge(4) bond length is 2.18 Å. The Ag(6)-O(6) bond length is 2.50 Å. The Ag(6)-O(7) bond length is 2.11 Å. The Ag(6)-O(9) bond length is 2.80 Å. There is one shorter (2.14 Å) and one longer (2.81 Å) Ag(6)-O(5) bond length. In the seventh Ag site, Ag(7) is bonded in a 6-coordinate geometry to one Ag(8), one Ge(3), one O(10), one O(12), one O(3), and one O(4) atom. The Ag(7)-Ag(8) bond length is 1.83 Å. The Ag(7)-Ge(3) bond length is 2.18 Å. The Ag(7)-O(10) bond length is 2.37 Å. The Ag(7)-O(12) bond length is 2.11 Å. The Ag(7)-O(3) bond length is 2.59 Å. The Ag(7)-O(4) bond length is 2.82 Å. In the eighth Ag site, Ag(8) is bonded in a bent 120 degrees geometry to one Ag(7), one O(12), and one O(3) atom. The Ag(8)-O(12) bond length is 1.53 Å. The Ag(8)-O(3) bond length is 1.69 Å. There are four inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a single-bond geometry to one Ag(6), one O(5), and one O(6) atom. The Ge(1)-O(5) bond length is 1.27 Å. The Ge(1)-O(6) bond length is 2.57 Å. In the second Ge site, Ge(2) is bonded in a single-bond geometry to one Ag(2), one Ag(6), and one O(2) atom. The Ge(2)-O(2) bond length is 1.55 Å. In the third Ge site, Ge(3) is bonded in a distorted single-bond geometry to one Ag(4), one Ag(7), and one O(11) atom. The Ge(3)-O(11) bond length is 1.27 Å. In the fourth Ge site, Ge(4) is bonded in a distorted single-bond geometry to one Ag(6), one O(4), one O(6), and one O(8) atom. The Ge(4)-O(4) bond length is 2.43 Å. The Ge(4)-O(6) bond length is 2.32 Å. The Ge(4)-O(8) bond length is 1.55 Å. There are twelve inequivalent O sites. In the first O site, O(1) is bonded in a distorted bent 150 degrees geometry to one Ag(2) and one Ag(5) atom. In the second O site, O(2) is bonded in a single-bond geometry to one Ge(2) atom. In the third O site, O(3) is bonded in a single-bond geometry to one Ag(7) and one Ag(8) atom. In the fourth O site, O(4) is bonded in a distorted single-bond geometry to one Ag(7) and one Ge(4) atom. In the fifth O site, O(5) is bonded in a distorted single-bond geometry to one Ag(5), two equivalent Ag(6), and one Ge(1) atom. In the sixth O site, O(6) is bonded in a 6-coordinate geometry to one Ag(3), one Ag(4), one Ag(6), one Ge(1), one Ge(4), and one O(8) atom. The O(6)-O(8) bond length is 1.99 Å. In the seventh O site, O(7) is bonded in a distorted single-bond geometry to one Ag(5) and one Ag(6) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Ag(3), one Ag(4), one Ge(4), and one O(6) atom. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Ag(2) and one Ag(6) atom. In the tenth O site, O(10) is bonded in a distorted single-bond geometry to one Ag(1) and one Ag(7) atom. In the eleventh O site, O(11) is bonded in a single-bond geometry to one Ge(3) atom. In the twelfth O site, O(12) is bonded in a distorted single-bond geometry to one Ag(7) and one Ag(8) atom.