data_VCd2Bi
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.67
_cell_length_b   3.67
_cell_length_c   6.4
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VCd2Bi
_chemical_formula_sum   'V1 Cd2 Bi1'
_cell_volume   86.26
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.27  1.0
  Cd  Cd1  1  0.0  0.0  0.14  1.0
  Cd  Cd2  1  0.84  0.84  0.62  1.0
  Bi  Bi0  1  0.84  0.84  0.57  1.0

data_VCd2Bi
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.19
_cell_length_b   5.19
_cell_length_c   6.4
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   VCd2Bi
_chemical_formula_sum   'V2 Cd4 Bi2'
_cell_volume   172.52
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.0  0.0  0.27  1.0
  Cd  Cd1  2  0.0  0.0  0.14  1.0
  Cd  Cd2  2  0.34  0.5  0.62  1.0
  Bi  Bi3  2  0.34  0.5  0.57  1.0

V Cd Cd Bi
V Cd Cd Bi 0 1 o o o 2 3 o o o 
VCd2Bi crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two VCd2Bi clusters. V(1) is bonded in a bent 150 degrees geometry to one Cd(1) and one Bi(1) atom. The V(1)-Cd(1) bond length is 0.79 Å. The V(1)-Bi(1) bond length is 2.13 Å. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a single-bond geometry to one V(1) atom. In the second Cd site, Cd(2) is bonded in a single-bond geometry to one Bi(1) atom. The Cd(2)-Bi(1) bond length is 0.34 Å. Bi(1) is bonded in a distorted single-bond geometry to one V(1) and one Cd(2) atom.