data_Y6AgP2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   21.49
_cell_length_b   3.94
_cell_length_c   11.08
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Y6AgP2
_chemical_formula_sum   'Y24 Ag4 P8'
_cell_volume   937.62
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y12  1  0.4  0.95  0.41  1.0
  Y  Y13  1  0.35  0.98  0.87  1.0
  Y  Y14  1  0.09  0.98  0.67  1.0
  Y  Y15  1  0.15  0.95  0.21  1.0
  Y  Y16  1  0.7  0.95  0.8  1.0
  Y  Y17  1  0.05  0.98  0.26  1.0
  Y  Y18  1  0.8  0.98  0.28  1.0
  Y  Y19  1  0.44  0.95  0.82  1.0
  Y  Y20  1  0.56  0.95  0.55  1.0
  Y  Y21  1  0.19  0.98  0.09  1.0
  Y  Y22  1  0.94  0.98  0.53  1.0
  Y  Y23  1  0.31  0.95  0.99  1.0
  Y  Y24  1  0.82  0.95  0.92  1.0
  Y  Y25  1  0.92  0.98  0.38  1.0
  Y  Y26  1  0.67  0.98  0.16  1.0
  Y  Y27  1  0.57  0.95  0.7  1.0
  Y  Y28  1  0.4  0.95  0.04  1.0
  Y  Y29  1  0.35  0.98  0.5  1.0
  Y  Y30  1  0.1  0.98  0.04  1.0
  Y  Y31  1  0.14  0.95  0.58  1.0
  Y  Y32  1  0.46  0.95  0.23  1.0
  Y  Y33  1  0.28  0.98  0.77  1.0
  Y  Y34  1  0.03  0.98  0.85  1.0
  Y  Y35  1  0.21  0.95  0.31  1.0
  Ag  Ag0  1  0.12  0.95  0.95  1.0
  Ag  Ag1  1  0.62  0.98  0.49  1.0
  Ag  Ag2  1  0.37  0.98  0.13  1.0
  Ag  Ag3  1  0.87  0.95  0.59  1.0
  P  P4  1  0.98  0.95  0.84  1.0
  P  P5  1  0.76  0.98  0.3  1.0
  P  P6  1  0.51  0.98  0.24  1.0
  P  P7  1  0.73  0.95  0.78  1.0
  P  P8  1  0.68  0.95  0.48  1.0
  P  P9  1  0.06  0.98  0.02  1.0
  P  P10  1  0.81  0.98  0.6  1.0
  P  P11  1  0.43  0.95  0.06  1.0

data_Y6AgP2
_symmetry_space_group_name_H-M   P-1
_cell_length_a   3.94
_cell_length_b   11.08
_cell_length_c   21.49
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   2
_chemical_formula_structural   Y6AgP2
_chemical_formula_sum   'Y24 Ag4 P8'
_cell_volume   937.62
_cell_formula_units_Z   4
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-x, -y, -z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Y  Y0  2  0.48  0.17  0.9  1.0
  Y  Y1  2  0.48  0.19  0.22  1.0
  Y  Y2  2  0.48  0.27  0.96  1.0
  Y  Y3  2  0.48  0.37  0.15  1.0
  Y  Y4  2  0.48  0.51  0.31  1.0
  Y  Y5  2  0.48  0.54  0.9  1.0
  Y  Y6  2  0.48  0.66  0.32  1.0
  Y  Y7  2  0.48  0.76  0.45  1.0
  Y  Y8  2  0.48  0.78  0.2  1.0
  Y  Y9  2  0.48  0.88  0.58  1.0
  Y  Y10  2  0.48  0.95  0.06  1.0
  Y  Y11  2  0.48  1.0  0.15  1.0
  Ag  Ag12  2  0.48  0.55  0.62  1.0
  Ag  Ag13  2  0.48  0.91  0.88  1.0
  P  P14  2  0.48  0.02  0.18  1.0
  P  P15  2  0.48  0.44  0.44  1.0
  P  P16  2  0.48  0.74  0.48  1.0
  P  P17  2  0.48  0.8  0.74  1.0

Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Ag Ag Ag Ag P P P P P P P P
Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Y Ag Ag Ag Ag P P P P P P P P 0 17 o o o 1 11 o o o 1 21 o o o 1 7 o o o 2 19 o o o 3 9 o o o 3 23 o o o 3 5 o o o 4 31 o o o 4 12 o o o 5 33 o o o 5 18 o o o 6 29 o o o 6 14 o o o 7 35 o o + 7 16 o o + 8 25 o o o 8 15 o o o 10 27 o o o 10 13 o o o 12 31 o o o 14 29 o o o 16 35 o o o 16 26 o o o 18 33 o o o 18 24 o o - 20 30 o o o 22 28 - o o 25 32 o o o 27 34 o o o 
PY2Y8AgP2Y2AgP crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two PY2 clusters, two Y2AgP clusters, and two Y8AgP2 clusters. In each PY2 cluster, there are two inequivalent Y sites. In the first Y site, Y(3) is bonded in a single-bond geometry to one P(2) atom. The Y(3)-P(2) bond length is 0.76 Å. In the second Y site, Y(7) is bonded in a 1-coordinate geometry to one P(2) atom. The Y(7)-P(2) bond length is 2.56 Å. P(2) is bonded in a distorted single-bond geometry to one Y(3) and one Y(7) atom. In each Y2AgP cluster, there are two inequivalent Y sites. In the first Y site, Y(5) is bonded in a distorted single-bond geometry to one Y(8) and one Ag(2) atom. The Y(5)-Y(8) bond length is 1.69 Å. The Y(5)-Ag(2) bond length is 1.58 Å. In the second Y site, Y(8) is bonded in a distorted single-bond geometry to one Y(5) atom. Ag(2) is bonded in a bent 150 degrees geometry to one Y(5) and one P(3) atom. The Ag(2)-P(3) bond length is 1.29 Å. P(3) is bonded in a single-bond geometry to one Ag(2) atom. In each Y8AgP2 cluster, there are eight inequivalent Y sites. In the first Y site, Y(1) is bonded in a 3-coordinate geometry to one Y(10), one Y(11), and one Ag(1) atom. The Y(1)-Y(10) bond length is 1.45 Å. The Y(1)-Y(11) bond length is 2.43 Å. The Y(1)-Ag(1) bond length is 3.11 Å. In the second Y site, Y(2) is bonded in a 4-coordinate geometry to one Y(12), one Y(4), one Y(6), and one Y(9) atom. The Y(2)-Y(12) bond length is 1.77 Å. The Y(2)-Y(4) bond length is 2.14 Å. The Y(2)-Y(6) bond length is 1.62 Å. The Y(2)-Y(9) bond length is 2.16 Å. In the third Y site, Y(4) is bonded in a 2-coordinate geometry to one Y(2) and one P(4) atom. The Y(4)-P(4) bond length is 2.58 Å. In the fourth Y site, Y(6) is bonded in a distorted water-like geometry to one Y(2) and one Ag(1) atom. The Y(6)-Ag(1) bond length is 2.13 Å. In the fifth Y site, Y(9) is bonded in a distorted water-like geometry to one Y(2), one Ag(1), and one P(4) atom. The Y(9)-Ag(1) bond length is 1.21 Å. The Y(9)-P(4) bond length is 0.76 Å. In the sixth Y site, Y(10) is bonded in a distorted single-bond geometry to one Y(1) atom. In the seventh Y site, Y(11) is bonded in a distorted single-bond geometry to one Y(1) and one P(1) atom. The Y(11)-P(1) bond length is 1.00 Å. In the eighth Y site, Y(12) is bonded in a distorted single-bond geometry to one Y(2) atom. Ag(1) is bonded in a single-bond geometry to one Y(1), one Y(6), and one Y(9) atom. There are two inequivalent P sites. In the first P site, P(4) is bonded in a single-bond geometry to one Y(4) and one Y(9) atom. In the second P site, P(1) is bonded in a single-bond geometry to one Y(11) atom.