data_LiZnCd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.08
_cell_length_b   5.08
_cell_length_c   5.11
_cell_angle_alpha   99.34
_cell_angle_beta   99.34
_cell_angle_gamma   35.14
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiZnCd2
_chemical_formula_sum   'Li1 Zn1 Cd2'
_cell_volume   74.97
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li2  1  0.38  0.0  0.49  1.0
  Zn  Zn3  1  0.07  0.0  0.28  1.0
  Cd  Cd0  1  0.02  0.0  0.09  1.0
  Cd  Cd1  1  0.76  0.0  0.69  1.0

data_LiZnCd2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.07
_cell_length_b   5.08
_cell_length_c   5.11
_cell_angle_alpha   99.34
_cell_angle_beta   90.0
_cell_angle_gamma   107.57
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiZnCd2
_chemical_formula_sum   'Li1 Zn1 Cd2'
_cell_volume   74.97
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.0  0.62  0.51  1.0
  Zn  Zn1  1  0.0  0.93  0.72  1.0
  Cd  Cd2  1  0.0  0.24  0.31  1.0
  Cd  Cd3  1  0.0  0.98  0.91  1.0

Li Zn Cd Cd
Li Zn Cd Cd 0 1 o o o 0 3 o o o 1 2 o o o 2 3 - o - 
LiCd2Zn crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one LiCd2Zn cluster. Li(1) is bonded in a distorted linear geometry to one Cd(2) and one Zn(1) atom. The Li(1)-Cd(2) bond length is 2.04 Å. The Li(1)-Zn(1) bond length is 1.75 Å. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a single-bond geometry to one Zn(1) atom. The Cd(1)-Zn(1) bond length is 0.97 Å. In the second Cd site, Cd(2) is bonded in a distorted single-bond geometry to one Li(1) atom. Zn(1) is bonded in a distorted bent 120 degrees geometry to one Li(1) and one Cd(1) atom.