data_SnBPd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.23
_cell_length_b   3.23
_cell_length_c   7.43
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   121.16
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SnBPd2
_chemical_formula_sum   'Sn1 B1 Pd2'
_cell_volume   66.2
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn3  1  0.0  0.0  0.71  1.0
  B  B0  1  0.0  0.0  0.0  1.0
  Pd  Pd1  1  0.59  0.0  0.37  1.0
  Pd  Pd2  1  0.59  0.0  0.06  1.0

data_SnBPd2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   3.23
_cell_length_b   5.52
_cell_length_c   7.43
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   SnBPd2
_chemical_formula_sum   'Sn2 B2 Pd4'
_cell_volume   132.42
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  2  0.0  0.0  0.29  1.0
  B  B1  2  0.0  0.0  0.0  1.0
  Pd  Pd2  2  0.41  0.0  0.63  1.0
  Pd  Pd3  2  0.41  0.0  0.94  1.0

Sn B Pd Pd
Sn B Pd Pd 0 1 o o + 0 2 o o o 0 2 - o o 1 3 - o o 1 2 o o o 1 2 - o o 2 2 + + o 2 2 o + o 2 2 + o o 2 3 o o o 
Pd2BSn crystallizes in the triclinic P1 space group. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a 9-coordinate geometry to one Pd(2), six equivalent Pd(1), and two equivalent Sn(1) atoms. The Pd(1)-Pd(2) bond length is 2.30 Å. There are two shorter (3.17 Å) and four longer (3.23 Å) Pd(1)-Pd(1) bond lengths. There is one shorter (2.89 Å) and one longer (3.18 Å) Pd(1)-Sn(1) bond length. In the second Pd site, Pd(2) is bonded in a distorted bent 150 degrees geometry to one Pd(1) and two equivalent B(1) atoms. There is one shorter (1.41 Å) and one longer (1.94 Å) Pd(2)-B(1) bond length. B(1) is bonded in a 3-coordinate geometry to two equivalent Pd(2) and one Sn(1) atom. The B(1)-Sn(1) bond length is 2.12 Å. Sn(1) is bonded in a 1-coordinate geometry to two equivalent Pd(1) and one B(1) atom.