data_Zn2SbCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.15
_cell_length_b   7.15
_cell_length_c   7.15
_cell_angle_alpha   31.68
_cell_angle_beta   31.68
_cell_angle_gamma   31.68
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Zn2SbCl
_chemical_formula_sum   'Zn2 Sb1 Cl1'
_cell_volume   89.55
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn2  1  0.0  0.0  0.95  1.0
  Zn  Zn3  1  0.0  0.0  0.41  1.0
  Sb  Sb1  1  0.0  0.0  0.18  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_Zn2SbCl
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.76
_cell_length_b   3.9
_cell_length_c   7.15
_cell_angle_alpha   90.0
_cell_angle_beta   108.37
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Zn2SbCl
_chemical_formula_sum   'Zn4 Sb2 Cl2'
_cell_volume   179.11
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  2  0.0  0.0  0.05  1.0
  Zn  Zn1  2  0.0  0.0  0.59  1.0
  Sb  Sb2  2  0.0  0.0  0.82  1.0
  Cl  Cl3  2  0.0  0.0  0.0  1.0

Zn Zn Sb Cl
Zn Zn Sb Cl 0 3 o o + 1 2 o o o 2 3 o o o 
Zn2SbCl is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two Zn2SbCl clusters. There are two inequivalent Zn sites. In the first Zn site, Zn(1) is bonded in a single-bond geometry to one Cl(1) atom. The Zn(1)-Cl(1) bond length is 0.35 Å. In the second Zn site, Zn(2) is bonded in a single-bond geometry to one Sb(1) atom. The Zn(2)-Sb(1) bond length is 1.63 Å. Sb(1) is bonded in a linear geometry to one Zn(2) and one Cl(1) atom. The Sb(1)-Cl(1) bond length is 1.28 Å. Cl(1) is bonded in a linear geometry to one Zn(1) and one Sb(1) atom.