data_Cr2PdCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.98
_cell_length_b   2.87
_cell_length_c   7.16
_cell_angle_alpha   90.0
_cell_angle_beta   91.45
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cr2PdCl
_chemical_formula_sum   'Cr2 Pd1 Cl1'
_cell_volume   61.35
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr1  1  0.99  0.44  0.84  1.0
  Cr  Cr2  1  0.85  0.0  0.6  1.0
  Pd  Pd3  1  0.21  0.44  0.92  1.0
  Cl  Cl0  1  0.95  0.0  0.55  1.0

data_Cr2PdCl
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.87
_cell_length_b   2.98
_cell_length_c   7.16
_cell_angle_alpha   91.45
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cr2PdCl
_chemical_formula_sum   'Cr2 Pd1 Cl1'
_cell_volume   61.35
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cr  Cr0  1  0.0  0.15  0.4  1.0
  Cr  Cr1  1  0.56  0.01  0.16  1.0
  Pd  Pd2  1  0.56  0.79  0.08  1.0
  Cl  Cl3  1  0.0  0.05  0.45  1.0

Cr Cr Pd Cl
Cr Cr Pd Cl 0 2 + o o 1 3 o o o 
PdCrCrCl is High Pressure (4-7GPa) Tellurium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one CrCl cluster and one PdCr cluster. In the CrCl cluster, Cr(2) is bonded in a single-bond geometry to one Cl(1) atom. The Cr(2)-Cl(1) bond length is 0.46 Å. Cl(1) is bonded in a single-bond geometry to one Cr(2) atom. In the PdCr cluster, Cr(1) is bonded in a single-bond geometry to one Pd(1) atom. The Cr(1)-Pd(1) bond length is 0.89 Å. Pd(1) is bonded in a single-bond geometry to one Cr(1) atom.