data_V2BiRu
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.53
_cell_length_b   8.53
_cell_length_c   8.53
_cell_angle_alpha   21.45
_cell_angle_beta   21.45
_cell_angle_gamma   21.45
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2BiRu
_chemical_formula_sum   'V2 Bi1 Ru1'
_cell_volume   72.8
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.0  0.0  0.59  1.0
  V  V3  1  0.0  0.0  0.41  1.0
  Bi  Bi0  1  0.0  0.0  0.5  1.0
  Ru  Ru1  1  0.0  0.0  0.0  1.0

data_V2BiRu
_symmetry_space_group_name_H-M   C2/m
_cell_length_a   5.5
_cell_length_b   3.18
_cell_length_c   8.53
_cell_angle_alpha   90.0
_cell_angle_beta   102.41
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   12
_chemical_formula_structural   V2BiRu
_chemical_formula_sum   'V4 Bi2 Ru2'
_cell_volume   145.6
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-x, -y, -z'
  3  '-x, y, -z'
  4  'x, -y, z'
  5  'x+1/2, y+1/2, z'
  6  '-x+1/2, -y+1/2, -z'
  7  '-x+1/2, y+1/2, -z'
  8  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  4  -0.0  0.0  0.09  1.0
  Bi  Bi1  2  0.0  0.0  0.0  1.0
  Ru  Ru2  2  0.0  0.0  0.5  1.0

V V Bi Ru
V V Bi Ru 0 2 o o o 0 3 o o + 1 2 o o o 1 3 o o o 3 3 o + - 3 3 + - o 3 3 + o - 
V2RuBi crystallizes in the monoclinic C2/m space group. V(1) is bonded in a single-bond geometry to one Ru(1) and one Bi(1) atom. The V(1)-Ru(1) bond length is 3.50 Å. The V(1)-Bi(1) bond length is 0.76 Å. Ru(1) is bonded to two equivalent V(1) and six equivalent Ru(1) atoms to form a mixture of distorted corner and edge-sharing RuV2Ru6 hexagonal bipyramids. All Ru(1)-Ru(1) bond lengths are 3.18 Å. Bi(1) is bonded in a linear geometry to two equivalent V(1) atoms.