data_TiAgBi2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.41
_cell_length_b   4.92
_cell_length_c   5.91
_cell_angle_alpha   90.0
_cell_angle_beta   106.68
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TiAgBi2
_chemical_formula_sum   'Ti1 Ag1 Bi2'
_cell_volume   94.97
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti3  1  0.22  0.0  0.7  1.0
  Ag  Ag0  1  0.22  0.46  0.42  1.0
  Bi  Bi1  1  0.56  0.0  0.19  1.0
  Bi  Bi2  1  0.88  0.46  0.84  1.0

data_TiAgBi2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.41
_cell_length_b   4.92
_cell_length_c   5.91
_cell_angle_alpha   90.0
_cell_angle_beta   106.68
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TiAgBi2
_chemical_formula_sum   'Ti1 Ag1 Bi2'
_cell_volume   94.97
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.22  0.0  0.7  1.0
  Ag  Ag1  1  0.22  0.46  0.42  1.0
  Bi  Bi2  1  0.56  0.0  0.19  1.0
  Bi  Bi3  1  0.88  0.46  0.84  1.0

Ti Ag Bi Bi
Ti Ag Bi Bi 0 1 o - o 0 1 o o o 0 3 - - o 0 3 - o o 0 3 o - o 0 3 o o o 0 2 - o o 0 2 o o + 0 2 o o o 0 0 + o o 1 2 - o o 1 2 - + o 1 2 o o o 1 2 o + o 1 3 - o - 1 3 - o o 1 3 o o o 1 1 + o o 2 3 - - - 2 3 - o - 2 3 o - - 2 3 o o - 2 2 + o o 3 3 + o o 
TiAgBi2 crystallizes in the triclinic P1 space group. Ti(1) is bonded in a 11-coordinate geometry to two equivalent Ti(1), two equivalent Ag(1), three equivalent Bi(1), and four equivalent Bi(2) atoms. Both Ti(1)-Ti(1) bond lengths are 3.41 Å. There is one shorter (2.84 Å) and one longer (3.14 Å) Ti(1)-Ag(1) bond length. There are a spread of Ti(1)-Bi(1) bond distances ranging from 2.75-3.58 Å. There are a spread of Ti(1)-Bi(2) bond distances ranging from 2.77-3.41 Å. Ag(1) is bonded in a 11-coordinate geometry to two equivalent Ti(1), two equivalent Ag(1), three equivalent Bi(2), and four equivalent Bi(1) atoms. Both Ag(1)-Ag(1) bond lengths are 3.41 Å. There are a spread of Ag(1)-Bi(2) bond distances ranging from 2.83-3.28 Å. There are a spread of Ag(1)-Bi(1) bond distances ranging from 3.06-3.47 Å. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a 1-coordinate geometry to three equivalent Ti(1) and four equivalent Ag(1) atoms. In the second Bi site, Bi(2) is bonded in a 7-coordinate geometry to four equivalent Ti(1) and three equivalent Ag(1) atoms.