data_ZrRh2W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.4
_cell_length_b   9.4
_cell_length_c   9.4
_cell_angle_alpha   17.52
_cell_angle_beta   17.52
_cell_angle_gamma   17.52
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZrRh2W
_chemical_formula_sum   'Zr1 Rh2 W1'
_cell_volume   65.71
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr3  1  0.0  0.0  0.0  1.0
  Rh  Rh0  1  0.0  0.0  0.97  1.0
  Rh  Rh1  1  0.0  0.0  0.8  1.0
  W  W2  1  0.0  0.0  0.88  1.0

data_ZrRh2W
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.96
_cell_length_b   2.86
_cell_length_c   9.4
_cell_angle_alpha   90.0
_cell_angle_beta   100.13
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   ZrRh2W
_chemical_formula_sum   'Zr2 Rh4 W2'
_cell_volume   131.42
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  2  0.0  0.0  0.0  1.0
  Rh  Rh1  2  -0.0  0.0  0.2  1.0
  Rh  Rh2  2  -0.0  0.0  0.03  1.0
  W  W3  2  -0.0  0.0  0.12  1.0

Zr Rh Rh W
Zr Rh Rh W 0 1 o o - 1 3 o o o 2 3 o o o 
ZrWRh2 is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two ZrWRh2 clusters. Zr(1) is bonded in a single-bond geometry to one Rh(1) atom. The Zr(1)-Rh(1) bond length is 0.32 Å. W(1) is bonded in a linear geometry to one Rh(1) and one Rh(2) atom. The W(1)-Rh(1) bond length is 0.77 Å. The W(1)-Rh(2) bond length is 0.77 Å. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a distorted single-bond geometry to one Zr(1) and one W(1) atom. In the second Rh site, Rh(2) is bonded in a single-bond geometry to one W(1) atom.