data_VInNi2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.97
_cell_length_b   3.13
_cell_length_c   6.01
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VInNi2
_chemical_formula_sum   'V1 In1 Ni2'
_cell_volume   55.84
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.0  1.0
  In  In0  1  0.0  0.0  0.01  1.0
  Ni  Ni1  1  0.48  0.57  0.76  1.0
  Ni  Ni2  1  0.48  0.57  0.26  1.0

data_VInNi2
_symmetry_space_group_name_H-M   Pm
_cell_length_a   2.97
_cell_length_b   6.01
_cell_length_c   3.13
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   6
_chemical_formula_structural   VInNi2
_chemical_formula_sum   'V1 In1 Ni2'
_cell_volume   55.84
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-x, -y, z'
  3  '-x, y, z'
  4  'x, -y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.0  0.0  1.0
  In  In1  1  0.0  0.0  0.0  1.0
  Ni  Ni2  2  0.48  0.24  0.57  1.0

V In Ni Ni
V In Ni Ni 0 1 o o o 0 2 o o - 0 2 o - - 0 2 - o - 0 2 - - - 0 3 o o o 0 3 o - o 0 3 - o o 0 3 - - o 1 2 o o - 1 2 o - - 1 2 - o - 1 2 - - - 1 3 o o o 1 3 o - o 1 3 - o o 1 3 - - o 2 2 + o o 2 3 o o o 2 3 o o + 3 3 + o o 3 3 o + o 
VNi2In crystallizes in the triclinic P1 space group. V(1) is bonded in a single-bond geometry to four equivalent Ni(1) and one In(1) atom. There are a spread of V(1)-Ni(1) bond distances ranging from 2.46-2.76 Å. The V(1)-In(1) bond length is 0.04 Å. There are two inequivalent Ni sites. In the first Ni site, Ni(1) is bonded in a 4-coordinate geometry to four equivalent V(1) and two equivalent Ni(2) atoms. Both Ni(1)-Ni(2) bond lengths are 3.01 Å. In the second Ni site, Ni(2) is bonded in a 10-coordinate geometry to two equivalent Ni(1), four equivalent Ni(2), and four equivalent In(1) atoms. There are two shorter (2.97 Å) and two longer (3.13 Å) Ni(2)-Ni(2) bond lengths. There are a spread of Ni(2)-In(1) bond distances ranging from 2.48-2.78 Å. In(1) is bonded in a single-bond geometry to one V(1) and four equivalent Ni(2) atoms.