data_SnGeP2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.23
_cell_length_b   5.23
_cell_length_c   5.45
_cell_angle_alpha   112.02
_cell_angle_beta   112.02
_cell_angle_gamma   36.27
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SnGeP2
_chemical_formula_sum   'Sn1 Ge1 P2'
_cell_volume   81.18
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn3  1  0.86  0.0  0.67  1.0
  Ge  Ge0  1  0.85  0.0  0.78  1.0
  P  P1  1  0.62  0.0  0.88  1.0
  P  P2  1  0.17  0.0  0.19  1.0

data_SnGeP2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.26
_cell_length_b   5.23
_cell_length_c   5.45
_cell_angle_alpha   112.02
_cell_angle_beta   90.0
_cell_angle_gamma   108.14
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SnGeP2
_chemical_formula_sum   'Sn1 Ge1 P2'
_cell_volume   81.18
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sn  Sn0  1  0.0  0.14  0.33  1.0
  Ge  Ge1  1  0.0  0.15  0.22  1.0
  P  P2  1  0.0  0.38  0.12  1.0
  P  P3  1  0.0  0.83  0.81  1.0

Sn Ge P P
Sn Ge P P 0 1 o o o 0 3 + o + 1 2 o o o 1 3 + o + 2 3 + o + 
SnGeP2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one SnGeP2 cluster. Sn(1) is bonded in a single-bond geometry to one Ge(1) atom. The Sn(1)-Ge(1) bond length is 0.64 Å. Ge(1) is bonded in a 3-coordinate geometry to one Sn(1), one P(1), and one P(2) atom. The Ge(1)-P(1) bond length is 1.53 Å. The Ge(1)-P(2) bond length is 2.24 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded in a single-bond geometry to one Ge(1) atom. In the second P site, P(2) is bonded in a single-bond geometry to one Ge(1) atom.