data_NaInPd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.82
_cell_length_b   4.82
_cell_length_c   4.82
_cell_angle_alpha   125.71
_cell_angle_beta   125.71
_cell_angle_gamma   80.36
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaInPd2
_chemical_formula_sum   'Na1 In1 Pd2'
_cell_volume   71.31
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na1  1  0.0  0.0  0.0  1.0
  In  In0  1  0.0  0.0  0.68  1.0
  Pd  Pd2  1  0.0  0.2  0.84  1.0
  Pd  Pd3  1  0.2  0.0  0.84  1.0

data_NaInPd2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.22
_cell_length_b   6.22
_cell_length_c   4.82
_cell_angle_alpha   90.0
_cell_angle_beta   130.18
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   NaInPd2
_chemical_formula_sum   'Na2 In2 Pd4'
_cell_volume   142.62
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  2  0.0  0.0  0.0  1.0
  In  In1  2  0.32  0.0  0.32  1.0
  Pd  Pd2  4  0.26  0.1  0.36  1.0

Na In Pd Pd
Na In Pd Pd 0 2 o o - 0 3 o o - 0 1 o o - 1 2 o o o 1 3 o o o 
NaPd2In crystallizes in the monoclinic Cm space group. Na(1) is bonded in a 6-coordinate geometry to four equivalent Pd(1) and two equivalent In(1) atoms. There are two shorter (1.54 Å) and two longer (3.47 Å) Na(1)-Pd(1) bond lengths. There is one shorter (1.52 Å) and one longer (3.30 Å) Na(1)-In(1) bond length. Pd(1) is bonded in a distorted single-bond geometry to two equivalent Na(1) and one In(1) atom. The Pd(1)-In(1) bond length is 0.81 Å. In(1) is bonded in a water-like geometry to two equivalent Na(1) and two equivalent Pd(1) atoms.