data_Sr4VRe
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.67
_cell_length_b   6.67
_cell_length_c   6.67
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Sr4VRe
_chemical_formula_sum   'Sr4 V1 Re1'
_cell_volume   209.88
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr1  1  0.54  0.54  0.89  1.0
  Sr  Sr2  1  0.54  0.89  0.54  1.0
  Sr  Sr3  1  0.89  0.54  0.54  1.0
  Sr  Sr4  1  0.89  0.89  0.89  1.0
  V  V5  1  0.0  0.0  0.0  1.0
  Re  Re0  1  0.36  0.36  0.36  1.0

data_Sr4VRe
_symmetry_space_group_name_H-M   R3m
_cell_length_a   6.67
_cell_length_b   6.67
_cell_length_c   16.34
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   Sr4VRe
_chemical_formula_sum   'Sr12 V3 Re3'
_cell_volume   629.63
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  9  0.1  0.55  0.01  1.0
  Sr  Sr1  3  0.0  0.0  0.11  1.0
  V  V2  3  0.0  0.0  0.0  1.0
  Re  Re3  3  0.0  0.0  0.64  1.0

Sr Sr Sr Sr V Re
Sr Sr Sr Sr V Re 0 5 o o + 0 2 o o o 0 1 o o o 1 5 o + o 1 2 o o o 2 5 + o o 3 4 + + + 
VSrSr3Re is alpha As structured and crystallizes in the trigonal R3m space group. The structure is zero-dimensional and consists of three strontium;vanadium molecules and three Sr3Re clusters. In each Sr3Re cluster, Sr(1) is bonded in a distorted single-bond geometry to one Re(1) atom. The Sr(1)-Re(1) bond length is 2.55 Å. Re(1) is bonded in a trigonal non-coplanar geometry to three equivalent Sr(1) atoms.