data_V2InRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.85
_cell_length_b   3.85
_cell_length_c   4.13
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2InRh
_chemical_formula_sum   'V2 In1 Rh1'
_cell_volume   61.21
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.0  0.93  0.06  1.0
  V  V3  1  0.93  0.0  0.06  1.0
  In  In0  1  0.93  0.93  0.0  1.0
  Rh  Rh1  1  0.0  0.0  0.0  1.0

data_V2InRh
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.45
_cell_length_b   5.45
_cell_length_c   4.13
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   V2InRh
_chemical_formula_sum   'V4 In2 Rh2'
_cell_volume   122.42
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  4  0.46  0.46  0.06  1.0
  In  In1  2  0.43  0.5  0.0  1.0
  Rh  Rh2  2  0.0  0.0  0.0  1.0

V V In Rh
V V In Rh 0 2 - o o 0 1 - + o 0 3 o + o 1 2 o - o 1 3 + o o 2 3 + + o 
V2RhIn is alpha Po structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two V2RhIn clusters. V(1) is bonded in a 2-coordinate geometry to one Rh(1) and one In(1) atom. The V(1)-Rh(1) bond length is 0.39 Å. The V(1)-In(1) bond length is 0.39 Å. Rh(1) is bonded in a 3-coordinate geometry to two equivalent V(1) and one In(1) atom. The Rh(1)-In(1) bond length is 0.40 Å. In(1) is bonded in a 3-coordinate geometry to two equivalent V(1) and one Rh(1) atom.