data_GaTcP2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.83
_cell_length_b   4.83
_cell_length_c   4.83
_cell_angle_alpha   142.39
_cell_angle_beta   123.25
_cell_angle_gamma   70.09
_symmetry_Int_Tables_number   1
_chemical_formula_structural   GaTcP2
_chemical_formula_sum   'Ga1 Tc1 P2'
_cell_volume   56.63
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.0  0.0  0.06  1.0
  Tc  Tc3  1  0.56  0.0  0.8  1.0
  P  P1  1  0.56  0.0  0.13  1.0
  P  P2  1  0.0  0.0  0.89  1.0

data_GaTcP2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.12
_cell_length_b   4.59
_cell_length_c   4.83
_cell_angle_alpha   118.37
_cell_angle_beta   108.8
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   GaTcP2
_chemical_formula_sum   'Ga1 Tc1 P2'
_cell_volume   56.63
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.0  0.06  0.06  1.0
  Tc  Tc1  1  0.0  0.8  0.24  1.0
  P  P2  1  0.0  0.13  0.57  1.0
  P  P3  1  0.0  0.89  0.89  1.0

Ga Tc P P
Ga Tc P P 0 3 o o - 0 1 - o - 1 3 + o o 1 2 o o + 
Tc(P)GaP crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one gallium phosphide molecule and one Tc(P) cluster. In the Tc(P) cluster, Tc(1) is bonded in a 1-coordinate geometry to one P(1) atom. The Tc(1)-P(1) bond length is 1.59 Å. P(1) is bonded in a single-bond geometry to one Tc(1) atom.