data_LiPdRh2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.68
_cell_length_b   2.68
_cell_length_c   9.05
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   117.65
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiPdRh2
_chemical_formula_sum   'Li1 Pd1 Rh2'
_cell_volume   57.44
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.0  0.0  0.0  1.0
  Pd  Pd1  1  0.0  0.0  0.52  1.0
  Rh  Rh2  1  0.39  0.0  0.87  1.0
  Rh  Rh3  1  0.39  0.0  0.17  1.0

data_LiPdRh2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   2.68
_cell_length_b   4.75
_cell_length_c   9.05
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   LiPdRh2
_chemical_formula_sum   'Li2 Pd2 Rh4'
_cell_volume   114.98
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  2  0.0  0.0  0.0  1.0
  Pd  Pd1  2  0.0  0.0  0.52  1.0
  Rh  Rh2  2  0.39  0.0  0.17  1.0
  Rh  Rh3  2  0.39  0.0  0.87  1.0

Li Pd Rh Rh
Li Pd Rh Rh 0 2 o o - 0 3 o o o 0 3 - o o 1 1 + + o 1 1 o + o 1 1 + o o 
LiRh2Pd crystallizes in the triclinic P1 space group. Li(1) is bonded in a 4-coordinate geometry to two equivalent Rh(1) and two equivalent Rh(2) atoms. There is one shorter (1.54 Å) and one longer (2.00 Å) Li(1)-Rh(1) bond length. There is one shorter (1.88 Å) and one longer (2.28 Å) Li(1)-Rh(2) bond length. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a distorted water-like geometry to two equivalent Li(1) and one Pd(1) atom. The Rh(1)-Pd(1) bond length is 3.33 Å. In the second Rh site, Rh(2) is bonded in a 2-coordinate geometry to two equivalent Li(1) and one Pd(1) atom. The Rh(2)-Pd(1) bond length is 3.33 Å. Pd(1) is bonded in a 8-coordinate geometry to one Rh(1), one Rh(2), and six equivalent Pd(1) atoms. There are four shorter (2.68 Å) and two longer (2.77 Å) Pd(1)-Pd(1) bond lengths.