data_NaReP2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.4
_cell_length_b   4.4
_cell_length_c   3.09
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   100.75
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaReP2
_chemical_formula_sum   'Na1 Re1 P2'
_cell_volume   58.66
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.0  0.0  0.0  1.0
  Re  Re3  1  0.8  0.0  0.0  1.0
  P  P1  1  0.4  0.69  0.54  1.0
  P  P2  1  0.4  0.31  0.54  1.0

data_NaReP2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.09
_cell_length_b   4.4
_cell_length_c   4.4
_cell_angle_alpha   100.75
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaReP2
_chemical_formula_sum   'Na1 Re1 P2'
_cell_volume   58.66
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.0  0.0  0.0  1.0
  Re  Re1  1  0.0  0.8  0.0  1.0
  P  P2  1  0.54  0.4  0.31  1.0
  P  P3  1  0.54  0.4  0.69  1.0

Na Re P P
Na Re P P 0 1 - o o 2 3 o o o 
NaReP2 crystallizes in the triclinic P1 space group. Na(1) is bonded in a distorted single-bond geometry to one Re(1), two equivalent P(1), and two equivalent P(2) atoms. The Na(1)-Re(1) bond length is 0.86 Å. There is one shorter (2.80 Å) and one longer (2.94 Å) Na(1)-P(1) bond length. There is one shorter (2.46 Å) and one longer (2.62 Å) Na(1)-P(2) bond length. Re(1) is bonded in a single-bond geometry to one Na(1), two equivalent P(1), and two equivalent P(2) atoms. There is one shorter (2.46 Å) and one longer (2.62 Å) Re(1)-P(1) bond length. There is one shorter (2.80 Å) and one longer (2.94 Å) Re(1)-P(2) bond length. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 5-coordinate geometry to two equivalent Na(1), two equivalent Re(1), and two equivalent P(2) atoms. There is one shorter (1.71 Å) and one longer (2.69 Å) P(1)-P(2) bond length. In the second P site, P(2) is bonded in a 6-coordinate geometry to two equivalent Na(1), two equivalent Re(1), and two equivalent P(1) atoms.