data_Tl2InRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.24
_cell_length_b   3.24
_cell_length_c   9.04
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Tl2InRh
_chemical_formula_sum   'Tl2 In1 Rh1'
_cell_volume   95.01
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl2  1  0.62  0.62  0.79  1.0
  Tl  Tl3  1  0.62  0.62  0.25  1.0
  In  In0  1  0.0  0.0  0.52  1.0
  Rh  Rh1  1  0.0  0.0  0.0  1.0

data_Tl2InRh
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.58
_cell_length_b   4.58
_cell_length_c   9.04
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Tl2InRh
_chemical_formula_sum   'Tl4 In2 Rh2'
_cell_volume   190.02
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  2  0.12  0.5  0.25  1.0
  Tl  Tl1  2  0.12  0.5  0.79  1.0
  In  In2  2  0.0  0.0  0.52  1.0
  Rh  Rh3  2  0.0  0.0  0.0  1.0

Tl Tl In Rh
Tl Tl In Rh 0 3 o o + 0 3 o + + 0 3 + o + 0 3 + + + 0 2 o + o 0 2 + o o 0 2 + + o 0 2 o o o 0 0 + o o 0 0 o + o 1 3 o o o 1 3 o + o 1 3 + o o 1 3 + + o 1 2 o + o 1 2 + o o 1 2 + + o 1 2 o o o 1 1 + o o 1 1 o + o 2 2 + o o 2 2 o + o 3 3 + o o 3 3 o + o 
RhTl2In crystallizes in the monoclinic Cm space group. Rh(1) is bonded in a 2-coordinate geometry to one Tl(1) and one Tl(2) atom. The Rh(1)-Tl(1) bond length is 2.57 Å. The Rh(1)-Tl(2) bond length is 2.84 Å. There are two inequivalent Tl sites. In the first Tl site, Tl(1) is bonded in a 1-coordinate geometry to one Rh(1) and three equivalent In(1) atoms. There is one shorter (3.01 Å) and two longer (3.40 Å) Tl(1)-In(1) bond lengths. In the second Tl site, Tl(2) is bonded in a 1-coordinate geometry to one Rh(1) and three equivalent In(1) atoms. There is one shorter (3.01 Å) and two longer (3.40 Å) Tl(2)-In(1) bond lengths. In(1) is bonded in a 10-coordinate geometry to three equivalent Tl(1), three equivalent Tl(2), and four equivalent In(1) atoms. All In(1)-In(1) bond lengths are 3.24 Å.