data_ScVSb2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.01
_cell_length_b   7.01
_cell_length_c   7.01
_cell_angle_alpha   32.74
_cell_angle_beta   32.74
_cell_angle_gamma   32.74
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ScVSb2
_chemical_formula_sum   'Sc1 V1 Sb2'
_cell_volume   89.66
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc2  1  0.0  0.0  0.0  1.0
  V  V3  1  0.0  0.0  0.94  1.0
  Sb  Sb0  1  0.0  0.0  0.82  1.0
  Sb  Sb1  1  0.0  0.0  0.06  1.0

data_ScVSb2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.85
_cell_length_b   3.95
_cell_length_c   7.01
_cell_angle_alpha   90.0
_cell_angle_beta   108.99
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   ScVSb2
_chemical_formula_sum   'Sc2 V2 Sb4'
_cell_volume   179.33
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  2  0.0  0.0  0.0  1.0
  V  V1  2  -0.0  0.0  0.06  1.0
  Sb  Sb2  2  -0.0  0.0  0.94  1.0
  Sb  Sb3  2  -0.0  0.0  0.18  1.0

Sc V Sb Sb
Sc V Sb Sb 0 1 o o - 0 3 o o o 1 2 o o o 
ScVSb2 is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two ScVSb2 clusters. Sc(1) is bonded in a linear geometry to one V(1) and one Sb(2) atom. The Sc(1)-V(1) bond length is 0.40 Å. The Sc(1)-Sb(2) bond length is 0.45 Å. V(1) is bonded in a linear geometry to one Sc(1) and one Sb(1) atom. The V(1)-Sb(1) bond length is 0.85 Å. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a single-bond geometry to one V(1) atom. In the second Sb site, Sb(2) is bonded in a single-bond geometry to one Sc(1) atom.