data_In3Co2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.91
_cell_length_b   6.91
_cell_length_c   6.91
_cell_angle_alpha   52.92
_cell_angle_beta   52.92
_cell_angle_gamma   52.92
_symmetry_Int_Tables_number   1
_chemical_formula_structural   In3Co2
_chemical_formula_sum   'In6 Co4'
_cell_volume   195.0
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In4  1  0.1  0.74  0.38  1.0
  In  In5  1  0.18  0.49  0.38  1.0
  In  In6  1  0.72  0.78  0.38  1.0
  In  In7  1  0.28  0.22  0.41  1.0
  In  In8  1  0.82  0.51  0.41  1.0
  In  In9  1  0.9  0.26  0.41  1.0
  Co  Co0  1  0.0  0.0  0.54  1.0
  Co  Co1  1  0.0  0.0  0.14  1.0
  Co  Co2  1  0.0  0.0  0.65  1.0
  Co  Co3  1  0.0  0.0  0.24  1.0

data_In3Co2
_symmetry_space_group_name_H-M   P-1
_cell_length_a   6.16
_cell_length_b   6.16
_cell_length_c   6.91
_cell_angle_alpha   63.54
_cell_angle_beta   63.54
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   2
_chemical_formula_structural   In3Co2
_chemical_formula_sum   'In6 Co4'
_cell_volume   195.0
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-x, -y, -z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  2  0.22  0.52  0.48  1.0
  In  In1  2  0.26  0.52  0.82  1.0
  In  In2  2  0.49  0.48  0.35  1.0
  Co  Co3  2  0.0  0.24  0.26  1.0
  Co  Co4  2  0.0  0.35  0.15  1.0

In In In In In In Co Co Co Co
In In In In In In Co Co Co Co 0 1 o o o 0 9 o + o 0 7 o + o 1 3 o o o 2 4 o o o 4 5 o o o 5 8 + o o 5 6 + o o 6 8 o o o 7 9 o o o 
Co2In3 is Copper structured and crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of one Co2In3 cluster. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a distorted water-like geometry to one Co(2) and one In(1) atom. The Co(1)-Co(2) bond length is 0.73 Å. The Co(1)-In(1) bond length is 1.37 Å. In the second Co site, Co(2) is bonded in a 1-coordinate geometry to one Co(1) and one In(3) atom. The Co(2)-In(3) bond length is 2.33 Å. There are three inequivalent In sites. In the first In site, In(1) is bonded in a 1-coordinate geometry to one Co(1) and one In(2) atom. The In(1)-In(2) bond length is 1.46 Å. In the second In site, In(2) is bonded in a 2-coordinate geometry to one In(1) and one In(3) atom. The In(2)-In(3) bond length is 1.42 Å. In the third In site, In(3) is bonded in a 2-coordinate geometry to one Co(2) and one In(2) atom.