data_Cd2GeSb
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.04
_cell_length_b   5.07
_cell_length_c   6.33
_cell_angle_alpha   90.0
_cell_angle_beta   95.77
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cd2GeSb
_chemical_formula_sum   'Cd2 Ge1 Sb1'
_cell_volume   96.84
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.98  0.0  0.2  1.0
  Cd  Cd1  1  0.44  0.53  0.47  1.0
  Ge  Ge2  1  0.16  0.0  0.19  1.0
  Sb  Sb3  1  0.49  0.53  0.58  1.0

data_Cd2GeSb
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.04
_cell_length_b   5.07
_cell_length_c   6.33
_cell_angle_alpha   90.0
_cell_angle_beta   95.77
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Cd2GeSb
_chemical_formula_sum   'Cd2 Ge1 Sb1'
_cell_volume   96.84
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cd  Cd0  1  0.44  0.53  0.47  1.0
  Cd  Cd1  1  0.98  0.0  0.2  1.0
  Ge  Ge2  1  0.16  0.0  0.19  1.0
  Sb  Sb3  1  0.49  0.53  0.58  1.0

Cd Cd Ge Sb
Cd Cd Ge Sb 0 2 + o o 1 3 o o o 
GeCdCdSb crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one CdSb cluster and one GeCd cluster. In the CdSb cluster, Cd(2) is bonded in a single-bond geometry to one Sb(1) atom. The Cd(2)-Sb(1) bond length is 0.67 Å. Sb(1) is bonded in a single-bond geometry to one Cd(2) atom. In the GeCd cluster, Cd(1) is bonded in a distorted single-bond geometry to one Ge(1) atom. The Cd(1)-Ge(1) bond length is 0.54 Å. Ge(1) is bonded in a distorted single-bond geometry to one Cd(1) atom.