data_V2BiRu
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.11
_cell_length_b   3.11
_cell_length_c   7.12
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   V2BiRu
_chemical_formula_sum   'V2 Bi1 Ru1'
_cell_volume   68.86
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.55  0.55  0.09  1.0
  V  V3  1  0.0  0.0  0.42  1.0
  Bi  Bi0  1  0.55  0.55  0.49  1.0
  Ru  Ru1  1  0.0  0.0  0.8  1.0

data_V2BiRu
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.4
_cell_length_b   4.4
_cell_length_c   7.12
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   V2BiRu
_chemical_formula_sum   'V4 Bi2 Ru2'
_cell_volume   137.72
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.0  0.0  0.42  1.0
  V  V1  2  0.05  0.5  0.09  1.0
  Bi  Bi2  2  0.05  0.5  0.49  1.0
  Ru  Ru3  2  0.0  0.0  0.8  1.0

V V Bi Ru
V V Bi Ru 0 3 o o - 0 3 o + - 0 3 + o - 0 3 + + - 0 1 o o o 0 1 o + o 0 1 + o o 0 1 + + o 0 0 + o o 0 0 o + o 0 2 o o o 1 2 - - o 1 2 - o o 1 2 o - o 1 2 o o o 1 3 o o o 2 3 + + o 2 3 + o o 2 3 o + o 2 3 o o o 3 3 + o o 3 3 o + o 
V2RuBi crystallizes in the monoclinic Cm space group. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 5-coordinate geometry to four equivalent Ru(1) and one Bi(1) atom. There are a spread of V(1)-Ru(1) bond distances ranging from 2.82-3.18 Å. The V(1)-Bi(1) bond length is 2.90 Å. In the second V site, V(2) is bonded in a 5-coordinate geometry to one Ru(1) and four equivalent Bi(1) atoms. The V(2)-Ru(1) bond length is 2.69 Å. There are a spread of V(2)-Bi(1) bond distances ranging from 2.02-2.49 Å. Ru(1) is bonded in a 13-coordinate geometry to one V(2), four equivalent V(1), four equivalent Ru(1), and four equivalent Bi(1) atoms. All Ru(1)-Ru(1) bond lengths are 3.11 Å. There are a spread of Ru(1)-Bi(1) bond distances ranging from 2.94-3.28 Å. Bi(1) is bonded in a 4-coordinate geometry to one V(1), four equivalent V(2), and four equivalent Ru(1) atoms.