data_NaMn2Ag
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.14
_cell_length_b   4.71
_cell_length_c   4.85
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaMn2Ag
_chemical_formula_sum   'Na1 Mn2 Ag1'
_cell_volume   71.66
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na3  1  0.0  0.0  0.0  1.0
  Mn  Mn1  1  0.57  0.0  0.42  1.0
  Mn  Mn2  1  0.0  0.36  0.42  1.0
  Ag  Ag0  1  0.57  0.36  0.0  1.0

data_NaMn2Ag
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.14
_cell_length_b   4.71
_cell_length_c   4.85
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaMn2Ag
_chemical_formula_sum   'Na1 Mn2 Ag1'
_cell_volume   71.66
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.0  0.0  0.0  1.0
  Mn  Mn1  1  0.0  0.36  0.42  1.0
  Mn  Mn2  1  0.57  0.0  0.42  1.0
  Ag  Ag3  1  0.57  0.36  0.0  1.0

Na Mn Mn Ag
Na Mn Mn Ag 0 3 - o o 0 3 o o o 0 1 - o o 0 1 o o o 0 2 o o o 1 2 o o o 1 2 + o o 1 3 o o o 2 3 - o o 2 3 o o o 
NaMn2Ag crystallizes in the triclinic P1 space group. Na(1) is bonded in a 3-coordinate geometry to three equivalent Mn(2), four equivalent Mn(1), and two equivalent Ag(1) atoms. There are a spread of Na(1)-Mn(2) bond distances ranging from 2.65-3.67 Å. There are a spread of Na(1)-Mn(1) bond distances ranging from 2.46-3.31 Å. There is one shorter (2.15 Å) and one longer (2.45 Å) Na(1)-Ag(1) bond length. There are two inequivalent Mn sites. In the first Mn site, Mn(1) is bonded in a 7-coordinate geometry to four equivalent Na(1), four equivalent Mn(2), and one Ag(1) atom. There are a spread of Mn(1)-Mn(2) bond distances ranging from 2.15-3.52 Å. The Mn(1)-Ag(1) bond length is 2.65 Å. In the second Mn site, Mn(2) is bonded in a 13-coordinate geometry to three equivalent Na(1), two equivalent Mn(2), four equivalent Mn(1), and four equivalent Ag(1) atoms. Both Mn(2)-Mn(2) bond lengths are 3.14 Å. There are a spread of Mn(2)-Ag(1) bond distances ranging from 2.46-3.31 Å. Ag(1) is bonded in a 2-coordinate geometry to two equivalent Na(1), one Mn(1), and four equivalent Mn(2) atoms.