data_AsRh2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.18
_cell_length_b   6.18
_cell_length_c   6.18
_cell_angle_alpha   151.76
_cell_angle_beta   143.08
_cell_angle_gamma   47.12
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AsRh2Cl
_chemical_formula_sum   'As1 Rh2 Cl1'
_cell_volume   66.89
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.51  0.0  0.23  1.0
  Rh  Rh2  1  0.51  0.0  0.22  1.0
  Rh  Rh3  1  0.0  0.0  0.23  1.0
  Cl  Cl1  1  0.0  0.0  0.31  1.0

data_AsRh2Cl
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.02
_cell_length_b   3.91
_cell_length_c   6.18
_cell_angle_alpha   108.46
_cell_angle_beta   104.12
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AsRh2Cl
_chemical_formula_sum   'As1 Rh2 Cl1'
_cell_volume   66.89
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  As  As0  1  0.0  0.23  0.73  1.0
  Rh  Rh1  1  0.0  0.22  0.72  1.0
  Rh  Rh2  1  0.0  0.23  0.23  1.0
  Cl  Cl3  1  0.0  0.31  0.31  1.0

As Rh Rh Cl
As Rh Rh Cl 0 1 o o o 2 3 o o o 
RhAsRhCl crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one arsenic;rhodium molecule and one RhCl cluster. In the RhCl cluster, Rh(2) is bonded in a single-bond geometry to one Cl(1) atom. The Rh(2)-Cl(1) bond length is 0.55 Å. Cl(1) is bonded in a single-bond geometry to one Rh(2) atom.