data_ReBiPd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.12
_cell_length_b   3.12
_cell_length_c   7.43
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ReBiPd2
_chemical_formula_sum   'Re1 Bi1 Pd2'
_cell_volume   72.16
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re3  1  0.0  0.0  0.44  1.0
  Bi  Bi0  1  0.56  0.56  0.56  1.0
  Pd  Pd1  1  0.0  0.0  0.2  1.0
  Pd  Pd2  1  0.56  0.56  0.95  1.0

data_ReBiPd2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.41
_cell_length_b   4.41
_cell_length_c   7.43
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   ReBiPd2
_chemical_formula_sum   'Re2 Bi2 Pd4'
_cell_volume   144.33
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Re  Re0  2  0.0  0.0  0.44  1.0
  Bi  Bi1  2  0.06  0.5  0.56  1.0
  Pd  Pd2  2  0.0  0.0  0.2  1.0
  Pd  Pd3  2  0.06  0.5  0.95  1.0

Re Bi Pd Pd
Re Bi Pd Pd 0 2 o o o 0 1 o o o 0 1 o - o 0 1 - o o 0 1 - - o 1 3 o o o 2 3 o o - 2 3 o - - 2 3 - o - 2 3 - - - 3 3 + o o 3 3 o + o 
RePd2Bi crystallizes in the monoclinic Cm space group. Re(1) is bonded in a 5-coordinate geometry to one Pd(1) and four equivalent Bi(1) atoms. The Re(1)-Pd(1) bond length is 1.73 Å. There are a spread of Re(1)-Bi(1) bond distances ranging from 2.15-2.62 Å. There are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a single-bond geometry to one Re(1) and four equivalent Pd(2) atoms. There are a spread of Pd(1)-Pd(2) bond distances ranging from 2.71-3.10 Å. In the second Pd site, Pd(2) is bonded in a 9-coordinate geometry to four equivalent Pd(1), four equivalent Pd(2), and one Bi(1) atom. All Pd(2)-Pd(2) bond lengths are 3.12 Å. The Pd(2)-Bi(1) bond length is 2.90 Å. Bi(1) is bonded in a 5-coordinate geometry to four equivalent Re(1) and one Pd(2) atom.