data_KBiPd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.66
_cell_length_b   4.66
_cell_length_c   5.18
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   KBiPd
_chemical_formula_sum   'K1 Bi1 Pd1'
_cell_volume   97.6
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K1  1  0.0  0.0  0.0  1.0
  Bi  Bi0  1  1.0  0.69  0.59  1.0
  Pd  Pd2  1  0.33  0.35  0.59  1.0

data_KBiPd
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.66
_cell_length_b   4.66
_cell_length_c   5.18
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   KBiPd
_chemical_formula_sum   'K1 Bi1 Pd1'
_cell_volume   97.6
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.0  0.0  0.0  1.0
  Bi  Bi1  1  1.0  0.69  0.59  1.0
  Pd  Pd2  1  0.33  0.35  0.59  1.0

K Bi Pd
K Bi Pd 0 1 - - - 0 2 o o - 1 2 o o o 1 2 + o o 1 2 + + o 
KPdBi crystallizes in the triclinic P1 space group. K(1) is bonded in a 2-coordinate geometry to two equivalent Pd(1) and two equivalent Bi(1) atoms. There is one shorter (2.64 Å) and one longer (3.45 Å) K(1)-Pd(1) bond length. There is one shorter (2.56 Å) and one longer (3.39 Å) K(1)-Bi(1) bond length. Pd(1) is bonded in a 5-coordinate geometry to two equivalent K(1) and three equivalent Bi(1) atoms. There are a spread of Pd(1)-Bi(1) bond distances ranging from 2.64-2.74 Å. Bi(1) is bonded in a 5-coordinate geometry to two equivalent K(1) and three equivalent Pd(1) atoms.