data_VGaOs
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.01
_cell_length_b   5.01
_cell_length_c   5.01
_cell_angle_alpha   144.56
_cell_angle_beta   144.56
_cell_angle_gamma   50.98
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VGaOs
_chemical_formula_sum   'V1 Ga1 Os1'
_cell_volume   42.04
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V2  1  0.0  0.0  0.09  1.0
  Ga  Ga0  1  0.0  0.0  0.01  1.0
  Os  Os1  1  0.0  0.0  0.94  1.0

data_VGaOs
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.31
_cell_length_b   4.31
_cell_length_c   5.01
_cell_angle_alpha   90.0
_cell_angle_beta   115.49
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   VGaOs
_chemical_formula_sum   'V2 Ga2 Os2'
_cell_volume   84.09
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.0  0.0  0.91  1.0
  Ga  Ga1  2  0.0  0.0  0.99  1.0
  Os  Os2  2  0.0  0.0  0.06  1.0

V Ga Os
V Ga Os 0 1 o o o 1 2 o o - 
VOsGa is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two VOsGa clusters. V(1) is bonded in a single-bond geometry to one Ga(1) atom. The V(1)-Ga(1) bond length is 0.39 Å. Os(1) is bonded in a single-bond geometry to one Ga(1) atom. The Os(1)-Ga(1) bond length is 0.34 Å. Ga(1) is bonded in a linear geometry to one V(1) and one Os(1) atom.