data_VSnPt2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.77
_cell_length_b   4.77
_cell_length_c   4.85
_cell_angle_alpha   100.4
_cell_angle_beta   100.4
_cell_angle_gamma   38.34
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VSnPt2
_chemical_formula_sum   'V1 Sn1 Pt2'
_cell_volume   67.05
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.0  1.0
  Sn  Sn2  1  0.04  0.0  0.38  1.0
  Pt  Pt0  1  0.61  0.0  0.67  1.0
  Pt  Pt1  1  0.47  0.0  0.09  1.0

data_VSnPt2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.13
_cell_length_b   4.77
_cell_length_c   4.85
_cell_angle_alpha   100.4
_cell_angle_beta   90.0
_cell_angle_gamma   109.17
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VSnPt2
_chemical_formula_sum   'V1 Sn1 Pt2'
_cell_volume   67.05
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.0  0.0  1.0
  Sn  Sn1  1  0.0  0.96  0.62  1.0
  Pt  Pt2  1  0.0  0.39  0.33  1.0
  Pt  Pt3  1  0.0  0.53  0.91  1.0

V Sn Pt Pt
V Sn Pt Pt 0 2 - o - 0 3 o o o 0 3 - o o 0 1 o o o 1 2 - o o 1 3 o o o 2 3 o o o 2 3 o o + 
VPt2Sn crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one VPt2Sn cluster. V(1) is bonded in a 3-coordinate geometry to one Pt(1), one Pt(2), and one Sn(1) atom. The V(1)-Pt(1) bond length is 2.24 Å. The V(1)-Pt(2) bond length is 2.20 Å. The V(1)-Sn(1) bond length is 1.82 Å. There are two inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a 1-coordinate geometry to one V(1) atom. In the second Pt site, Pt(2) is bonded in a distorted single-bond geometry to one V(1) atom. Sn(1) is bonded in a distorted single-bond geometry to one V(1) atom.