data_VSiAg2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.7
_cell_length_b   5.7
_cell_length_c   2.72
_cell_angle_alpha   103.2
_cell_angle_beta   103.2
_cell_angle_gamma   123.9
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VSiAg2
_chemical_formula_sum   'V1 Si1 Ag2'
_cell_volume   64.24
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.68  0.0  0.0  1.0
  Si  Si2  1  0.0  0.0  0.0  1.0
  Ag  Ag0  1  0.68  0.48  0.19  1.0
  Ag  Ag1  1  0.68  0.52  0.19  1.0

data_VSiAg2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.72
_cell_length_b   4.69
_cell_length_c   5.7
_cell_angle_alpha   113.91
_cell_angle_beta   103.2
_cell_angle_gamma   91.44
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VSiAg2
_chemical_formula_sum   'V1 Si1 Ag2'
_cell_volume   64.24
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.0  0.68  1.0
  Si  Si1  1  0.0  0.0  0.0  1.0
  Ag  Ag2  1  0.67  0.48  0.16  1.0
  Ag  Ag3  1  0.71  0.52  0.2  1.0

V Si Ag Ag
V Si Ag Ag 0 1 + o o 2 3 o o o 
VSi(Ag)2 is Millerite-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one 7230-74-2 (name error) molecule and one VSi cluster. In the VSi cluster, V(1) is bonded in a 1-coordinate geometry to one Si(1) atom. The V(1)-Si(1) bond length is 1.81 Å. Si(1) is bonded in a distorted single-bond geometry to one V(1) atom.