data_TcSn2Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.54
_cell_length_b   5.54
_cell_length_c   5.54
_cell_angle_alpha   138.69
_cell_angle_beta   138.69
_cell_angle_gamma   59.85
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TcSn2Pd
_chemical_formula_sum   'Tc1 Sn2 Pd1'
_cell_volume   73.31
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tc  Tc3  1  0.0  0.0  0.0  1.0
  Sn  Sn1  1  0.0  0.0  0.8  1.0
  Sn  Sn2  1  0.0  0.95  0.4  1.0
  Pd  Pd0  1  0.95  0.0  0.4  1.0

data_TcSn2Pd
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.91
_cell_length_b   3.91
_cell_length_c   5.54
_cell_angle_alpha   110.65
_cell_angle_beta   110.65
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TcSn2Pd
_chemical_formula_sum   'Tc1 Sn2 Pd1'
_cell_volume   73.31
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tc  Tc0  1  0.0  0.0  0.0  1.0
  Sn  Sn1  1  0.45  0.4  0.45  1.0
  Sn  Sn2  1  0.8  0.8  0.8  1.0
  Pd  Pd3  1  0.4  0.45  0.45  1.0

Tc Sn Sn Pd
Tc Sn Sn Pd 0 1 o o - 2 3 - + o 
TcSnPdSn crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one 12066-69-2 molecule and one TcSn cluster. In the TcSn cluster, Tc(1) is bonded in a distorted single-bond geometry to one Sn(1) atom. The Tc(1)-Sn(1) bond length is 1.10 Å. Sn(1) is bonded in a distorted single-bond geometry to one Tc(1) atom.