data_VCdCo2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.85
_cell_length_b   2.85
_cell_length_c   6.62
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   92.44
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VCdCo2
_chemical_formula_sum   'V1 Cd1 Co2'
_cell_volume   53.59
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.0  1.0
  Cd  Cd0  1  0.0  0.0  0.31  1.0
  Co  Co1  1  0.97  0.0  0.3  1.0
  Co  Co2  1  0.97  0.0  0.32  1.0

data_VCdCo2
_symmetry_space_group_name_H-M   Pm
_cell_length_a   2.85
_cell_length_b   2.85
_cell_length_c   6.62
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   6
_chemical_formula_structural   VCdCo2
_chemical_formula_sum   'V1 Cd1 Co2'
_cell_volume   53.64
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.0  0.0  1.0
  Cd  Cd1  1  0.0  0.0  0.31  1.0
  Co  Co2  1  0.97  0.0  0.3  1.0
  Co  Co3  1  0.97  0.0  0.32  1.0

V Cd Co Co
V Cd Co Co 0 3 - o o 0 2 - o o 0 1 o o o 1 2 - o o 1 3 - o o 
VCo2Cd crystallizes in the monoclinic Pm space group. The structure is zero-dimensional and consists of one VCo2Cd cluster. V(1) is bonded in a single-bond geometry to one Co(1) atom. The V(1)-Co(1) bond length is 1.98 Å. There are two inequivalent Co sites. In the first Co site, Co(1) is bonded in a single-bond geometry to one V(1) and one Cd(1) atom. The Co(1)-Cd(1) bond length is 0.12 Å. In the second Co site, Co(2) is bonded in a distorted single-bond geometry to one Cd(1) atom. The Co(2)-Cd(1) bond length is 0.12 Å. Cd(1) is bonded in an L-shaped geometry to one Co(1) and one Co(2) atom.