data_ZnAuCl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.51
_cell_length_b   6.51
_cell_length_c   6.51
_cell_angle_alpha   152.43
_cell_angle_beta   152.43
_cell_angle_gamma   39.39
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnAuCl
_chemical_formula_sum   'Zn1 Au1 Cl1'
_cell_volume   59.08
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn2  1  0.0  0.0  0.08  1.0
  Au  Au0  1  0.0  0.0  0.83  1.0
  Cl  Cl1  1  0.0  0.0  0.62  1.0

data_ZnAuCl
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.39
_cell_length_b   4.39
_cell_length_c   6.51
_cell_angle_alpha   90.0
_cell_angle_beta   109.7
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   ZnAuCl
_chemical_formula_sum   'Zn2 Au2 Cl2'
_cell_volume   118.15
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  2  0.0  0.0  0.92  1.0
  Au  Au1  2  0.0  0.0  0.17  1.0
  Cl  Cl2  2  0.0  0.0  0.38  1.0

Zn Au Cl
Zn Au Cl 0 1 o o - 1 2 o o o 
AuZnCl is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two AuZnCl clusters. Au(1) is bonded in a linear geometry to one Zn(1) and one Cl(1) atom. The Au(1)-Zn(1) bond length is 1.62 Å. The Au(1)-Cl(1) bond length is 1.36 Å. Zn(1) is bonded in a single-bond geometry to one Au(1) atom. Cl(1) is bonded in a single-bond geometry to one Au(1) atom.