data_VSn2Pd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.08
_cell_length_b   3.08
_cell_length_c   8.35
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   91.24
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VSn2Pd
_chemical_formula_sum   'V1 Sn2 Pd1'
_cell_volume   79.37
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.91  1.0
  Sn  Sn1  1  0.0  0.0  0.39  1.0
  Sn  Sn2  1  0.16  0.0  0.86  1.0
  Pd  Pd0  1  0.16  0.0  0.36  1.0

data_VSn2Pd
_symmetry_space_group_name_H-M   Pm
_cell_length_a   3.08
_cell_length_b   3.08
_cell_length_c   8.35
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   6
_chemical_formula_structural   VSn2Pd
_chemical_formula_sum   'V1 Sn2 Pd1'
_cell_volume   79.39
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.0  0.91  1.0
  Sn  Sn1  1  0.0  0.0  0.39  1.0
  Sn  Sn2  1  0.16  0.0  0.86  1.0
  Pd  Pd3  1  0.16  0.0  0.36  1.0

V Sn Sn Pd
V Sn Sn Pd 0 2 o o o 1 3 o o o 
VSnPdSn crystallizes in the monoclinic Pm space group. The structure is zero-dimensional and consists of one PdSn cluster and one VSn cluster. In the PdSn cluster, Pd(1) is bonded in a single-bond geometry to one Sn(1) atom. The Pd(1)-Sn(1) bond length is 0.55 Å. Sn(1) is bonded in a single-bond geometry to one Pd(1) atom. In the VSn cluster, V(1) is bonded in a single-bond geometry to one Sn(2) atom. The V(1)-Sn(2) bond length is 0.65 Å. Sn(2) is bonded in a single-bond geometry to one V(1) atom.