data_KNaTe2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.24
_cell_length_b   4.48
_cell_length_c   8.66
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   KNaTe2
_chemical_formula_sum   'K1 Na1 Te2'
_cell_volume   125.84
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.0  0.0  0.33  1.0
  Na  Na1  1  0.0  0.0  0.0  1.0
  Te  Te2  1  0.62  0.24  0.99  1.0
  Te  Te3  1  0.62  0.24  0.67  1.0

data_KNaTe2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.24
_cell_length_b   4.48
_cell_length_c   8.66
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   KNaTe2
_chemical_formula_sum   'K1 Na1 Te2'
_cell_volume   125.84
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.0  0.0  0.33  1.0
  Na  Na1  1  0.0  0.0  0.0  1.0
  Te  Te2  1  0.62  0.24  0.67  1.0
  Te  Te3  1  0.62  0.24  0.99  1.0

K Na Te Te
K Na Te Te 0 2 - o - 0 2 o o - 0 3 - o o 0 3 o o o 0 0 + o o 0 1 o o o 1 2 - o - 1 3 o o - 1 3 - o - 2 3 o o o 3 3 + o o 
KNaTe2 crystallizes in the triclinic P1 space group. K(1) is bonded in a 9-coordinate geometry to four equivalent K(1), one Na(1), two equivalent Te(1), and two equivalent Te(2) atoms. There are two shorter (3.24 Å) and two longer (4.48 Å) K(1)-K(1) bond lengths. The K(1)-Na(1) bond length is 2.86 Å. There is one shorter (3.38 Å) and one longer (3.74 Å) K(1)-Te(1) bond length. There is one shorter (3.38 Å) and one longer (3.74 Å) K(1)-Te(2) bond length. Na(1) is bonded in a distorted water-like geometry to one K(1), two equivalent Te(1), and two equivalent Te(2) atoms. There is one shorter (1.63 Å) and one longer (2.29 Å) Na(1)-Te(1) bond length. There is one shorter (3.27 Å) and one longer (3.64 Å) Na(1)-Te(2) bond length. There are two inequivalent Te sites. In the first Te site, Te(1) is bonded in a distorted water-like geometry to two equivalent K(1), two equivalent Na(1), and one Te(2) atom. The Te(1)-Te(2) bond length is 2.73 Å. In the second Te site, Te(2) is bonded in a 7-coordinate geometry to two equivalent K(1), two equivalent Na(1), one Te(1), and two equivalent Te(2) atoms. Both Te(2)-Te(2) bond lengths are 3.24 Å.