data_VBiRu2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.05
_cell_length_b   5.05
_cell_length_c   5.05
_cell_angle_alpha   134.41
_cell_angle_beta   134.41
_cell_angle_gamma   66.45
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VBiRu2
_chemical_formula_sum   'V1 Bi1 Ru2'
_cell_volume   64.72
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.0  1.0
  Bi  Bi0  1  0.96  0.0  0.11  1.0
  Ru  Ru1  1  0.0  0.0  0.23  1.0
  Ru  Ru2  1  0.0  0.96  0.11  1.0

data_VBiRu2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.91
_cell_length_b   3.91
_cell_length_c   5.05
_cell_angle_alpha   112.8
_cell_angle_beta   112.8
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VBiRu2
_chemical_formula_sum   'V1 Bi1 Ru2'
_cell_volume   64.72
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  1  0.0  0.0  0.0  1.0
  Bi  Bi1  1  0.89  0.0  0.84  1.0
  Ru  Ru2  1  0.77  0.0  0.77  1.0
  Ru  Ru3  1  0.84  0.96  0.84  1.0

V Bi Ru Ru
V Bi Ru Ru 0 1 - o o 0 3 o - o 1 3 + - o 1 2 + o o 2 3 o - o 
VRu2Bi crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one VRu2Bi cluster. V(1) is bonded in a 2-coordinate geometry to one Ru(2) and one Bi(1) atom. The V(1)-Ru(2) bond length is 0.74 Å. The V(1)-Bi(1) bond length is 0.74 Å. There are two inequivalent Ru sites. In the first Ru site, Ru(1) is bonded in a 2-coordinate geometry to one Ru(2) and one Bi(1) atom. The Ru(1)-Ru(2) bond length is 0.44 Å. The Ru(1)-Bi(1) bond length is 0.44 Å. In the second Ru site, Ru(2) is bonded in a single-bond geometry to one V(1), one Ru(1), and one Bi(1) atom. The Ru(2)-Bi(1) bond length is 0.24 Å. Bi(1) is bonded in a single-bond geometry to one V(1), one Ru(1), and one Ru(2) atom.