data_NaCdGa2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.35
_cell_length_b   5.35
_cell_length_c   5.35
_cell_angle_alpha   130.78
_cell_angle_beta   130.78
_cell_angle_gamma   72.17
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaCdGa2
_chemical_formula_sum   'Na1 Cd1 Ga2'
_cell_volume   86.05
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na3  1  0.0  0.0  0.0  1.0
  Cd  Cd0  1  0.23  0.0  0.16  1.0
  Ga  Ga1  1  0.0  0.0  0.33  1.0
  Ga  Ga2  1  0.0  0.23  0.16  1.0

data_NaCdGa2
_symmetry_space_group_name_H-M   P1
_cell_length_a   4.46
_cell_length_b   4.46
_cell_length_c   5.35
_cell_angle_alpha   114.61
_cell_angle_beta   114.61
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaCdGa2
_chemical_formula_sum   'Na1 Cd1 Ga2'
_cell_volume   86.05
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.0  0.0  0.0  1.0
  Cd  Cd1  1  0.84  0.0  0.07  1.0
  Ga  Ga2  1  0.07  0.23  0.07  1.0
  Ga  Ga3  1  0.67  0.0  0.67  1.0

Na Cd Ga Ga
Na Cd Ga Ga 0 3 o o o 0 1 o o o 0 2 o o o 1 2 o o o 2 3 o o o 
NaCdGa2 is Indium-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one NaCdGa2 cluster. Na(1) is bonded in a water-like geometry to one Cd(1), one Ga(1), and one Ga(2) atom. The Na(1)-Cd(1) bond length is 0.93 Å. The Na(1)-Ga(1) bond length is 1.75 Å. The Na(1)-Ga(2) bond length is 0.93 Å. Cd(1) is bonded in a single-bond geometry to one Na(1) atom. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a distorted single-bond geometry to one Na(1) atom. In the second Ga site, Ga(2) is bonded in a single-bond geometry to one Na(1) atom.