data_Ga2SbRh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.38
_cell_length_b   5.38
_cell_length_c   5.38
_cell_angle_alpha   144.0
_cell_angle_beta   123.62
_cell_angle_gamma   68.73
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ga2SbRh
_chemical_formula_sum   'Ga2 Sb1 Rh1'
_cell_volume   75.25
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.0  0.54  0.46  1.0
  Ga  Ga1  1  0.66  0.0  0.98  1.0
  Sb  Sb3  1  0.0  0.0  0.44  1.0
  Rh  Rh2  1  0.0  0.0  0.0  1.0

data_Ga2SbRh
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.33
_cell_length_b   5.09
_cell_length_c   5.38
_cell_angle_alpha   118.19
_cell_angle_beta   108.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ga2SbRh
_chemical_formula_sum   'Ga2 Sb1 Rh1'
_cell_volume   75.25
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.0  0.98  0.32  1.0
  Ga  Ga1  1  0.46  0.92  0.92  1.0
  Sb  Sb2  1  0.0  0.44  0.44  1.0
  Rh  Rh3  1  0.0  0.0  0.0  1.0

Ga Ga Sb Rh
Ga Ga Sb Rh 0 3 o + + 0 3 o o o 0 2 o + o 1 3 + o + 1 2 + o + 2 3 o o o 
RhGa2Sb crystallizes in the triclinic P1 space group. Rh(1) is bonded in a 3-coordinate geometry to one Ga(2), two equivalent Ga(1), and one Sb(1) atom. The Rh(1)-Ga(2) bond length is 1.75 Å. There is one shorter (1.70 Å) and one longer (1.73 Å) Rh(1)-Ga(1) bond length. The Rh(1)-Sb(1) bond length is 2.39 Å. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a distorted bent 150 degrees geometry to two equivalent Rh(1) and one Sb(1) atom. The Ga(1)-Sb(1) bond length is 2.54 Å. In the second Ga site, Ga(2) is bonded in a 1-coordinate geometry to one Rh(1) and two equivalent Sb(1) atoms. There is one shorter (2.13 Å) and one longer (3.11 Å) Ga(2)-Sb(1) bond length. Sb(1) is bonded in a 4-coordinate geometry to one Rh(1), one Ga(1), and two equivalent Ga(2) atoms.