data_VAs2P
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.18
_cell_length_b   3.18
_cell_length_c   6.21
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VAs2P
_chemical_formula_sum   'V1 As2 P1'
_cell_volume   62.86
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.1  1.0
  As  As0  1  0.59  0.59  0.45  1.0
  As  As1  1  0.59  0.59  0.76  1.0
  P  P2  1  0.0  0.0  0.0  1.0

data_VAs2P
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.5
_cell_length_b   4.5
_cell_length_c   6.21
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   VAs2P
_chemical_formula_sum   'V2 As4 P2'
_cell_volume   125.73
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  2  0.0  0.0  0.1  1.0
  As  As1  2  0.09  0.5  0.45  1.0
  As  As2  2  0.09  0.5  0.76  1.0
  P  P3  2  0.0  0.0  0.0  1.0

V As As P
V As As P 0 3 o o o 1 2 o o o 
VAs2P crystallizes in the monoclinic Cm space group. V(1) is bonded in a single-bond geometry to three equivalent As(1) and one P(1) atom. There is one shorter (2.83 Å) and two longer (3.14 Å) V(1)-As(1) bond lengths. The V(1)-P(1) bond length is 0.64 Å. There are two inequivalent As sites. In the first As site, As(1) is bonded in a 4-coordinate geometry to three equivalent V(1) and one As(2) atom. The As(1)-As(2) bond length is 1.90 Å. In the second As site, As(2) is bonded in a 4-coordinate geometry to one As(1) and three equivalent P(1) atoms. There is one shorter (2.38 Å) and two longer (2.74 Å) As(2)-P(1) bond lengths. P(1) is bonded in a single-bond geometry to one V(1) and three equivalent As(2) atoms.