data_MnTlSn2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.29
_cell_length_b   7.29
_cell_length_c   7.29
_cell_angle_alpha   154.52
_cell_angle_beta   143.44
_cell_angle_gamma   45.09
_symmetry_Int_Tables_number   1
_chemical_formula_structural   MnTlSn2
_chemical_formula_sum   'Mn1 Tl1 Sn2'
_cell_volume   98.97
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.0  0.0  0.27  1.0
  Tl  Tl3  1  0.61  0.0  0.88  1.0
  Sn  Sn1  1  0.61  0.0  0.94  1.0
  Sn  Sn2  1  0.0  0.0  0.1  1.0

data_MnTlSn2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.22
_cell_length_b   4.57
_cell_length_c   7.29
_cell_angle_alpha   108.28
_cell_angle_beta   102.74
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   MnTlSn2
_chemical_formula_sum   'Mn1 Tl1 Sn2'
_cell_volume   98.97
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.73  0.73  0.73  1.0
  Tl  Tl1  1  0.72  0.12  0.72  1.0
  Sn  Sn2  1  0.67  0.06  0.67  1.0
  Sn  Sn3  1  0.9  0.9  0.9  1.0

Mn Tl Sn Sn
Mn Tl Sn Sn 0 3 o o o 1 2 o o o 
MnSnTlSn crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one thallium;tin molecule and one MnSn cluster. In the MnSn cluster, Mn(1) is bonded in a distorted single-bond geometry to one Sn(2) atom. The Mn(1)-Sn(2) bond length is 1.24 Å. Sn(2) is bonded in a distorted single-bond geometry to one Mn(1) atom.