data_Li2AgP
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.85
_cell_length_b   2.85
_cell_length_c   7.46
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   91.55
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Li2AgP
_chemical_formula_sum   'Li2 Ag1 P1'
_cell_volume   60.52
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li1  1  0.99  0.0  0.83  1.0
  Li  Li2  1  0.99  0.0  0.63  1.0
  Ag  Ag0  1  0.0  0.0  0.73  1.0
  P  P3  1  0.0  0.0  0.0  1.0

data_Li2AgP
_symmetry_space_group_name_H-M   P4mm
_cell_length_a   2.85
_cell_length_b   2.85
_cell_length_c   7.46
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   99
_chemical_formula_structural   Li2AgP
_chemical_formula_sum   'Li2 Ag1 P1'
_cell_volume   60.54
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x, z'
  3  '-x, -y, z'
  4  'y, -x, z'
  5  '-x, y, z'
  6  'y, x, z'
  7  'x, -y, z'
  8  '-y, -x, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.0  0.0  0.63  1.0
  Li  Li1  1  0.0  0.0  0.83  1.0
  Ag  Ag2  1  0.0  0.0  0.73  1.0
  P  P3  1  0.0  0.0  0.0  1.0

Li Li Ag P
Li Li Ag P 0 2 + o o 0 3 + o + 1 2 + o o 
Li2AgP is Cyanogen Chloride-like structured and crystallizes in the monoclinic Pm space group. The structure is zero-dimensional and consists of one Li2AgP cluster. There are two inequivalent Li sites. In the first Li site, Li(1) is bonded in a linear geometry to one Ag(1) and one P(1) atom. The Li(1)-Ag(1) bond length is 0.75 Å. The Li(1)-P(1) bond length is 1.28 Å. In the second Li site, Li(2) is bonded in a single-bond geometry to one Ag(1) atom. The Li(2)-Ag(1) bond length is 0.75 Å. Ag(1) is bonded in a linear geometry to one Li(1) and one Li(2) atom. P(1) is bonded in a single-bond geometry to one Li(1) atom.