data_AgGe2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.04
_cell_length_b   4.81
_cell_length_c   5.6
_cell_angle_alpha   90.0
_cell_angle_beta   101.12
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AgGe2Cl
_chemical_formula_sum   'Ag1 Ge2 Cl1'
_cell_volume   80.36
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.98  0.0  0.75  1.0
  Ge  Ge2  1  1.0  0.41  0.49  1.0
  Ge  Ge3  1  0.96  0.41  0.01  1.0
  Cl  Cl1  1  0.0  0.0  0.0  1.0

data_AgGe2Cl
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.04
_cell_length_b   4.81
_cell_length_c   5.6
_cell_angle_alpha   90.0
_cell_angle_beta   101.12
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AgGe2Cl
_chemical_formula_sum   'Ag1 Ge2 Cl1'
_cell_volume   80.36
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.98  0.0  0.75  1.0
  Ge  Ge1  1  0.96  0.41  0.01  1.0
  Ge  Ge2  1  1.0  0.41  0.49  1.0
  Cl  Cl3  1  0.0  0.0  0.0  1.0

Ag Ge Ge Cl
Ag Ge Ge Cl 0 3 + o + 0 1 o o o 0 1 o - o 1 2 o o o 1 2 o o + 1 1 + o o 2 3 + o o 
AgGe2Cl crystallizes in the triclinic P1 space group. Ag(1) is bonded in a single-bond geometry to two equivalent Ge(1) and one Cl(1) atom. There is one shorter (2.44 Å) and one longer (3.21 Å) Ag(1)-Ge(1) bond length. The Ag(1)-Cl(1) bond length is 1.40 Å. There are two inequivalent Ge sites. In the first Ge site, Ge(1) is bonded in a 6-coordinate geometry to two equivalent Ag(1), two equivalent Ge(1), and two equivalent Ge(2) atoms. Both Ge(1)-Ge(1) bond lengths are 3.04 Å. There is one shorter (2.68 Å) and one longer (2.92 Å) Ge(1)-Ge(2) bond length. In the second Ge site, Ge(2) is bonded in a distorted single-bond geometry to two equivalent Ge(1) and one Cl(1) atom. The Ge(2)-Cl(1) bond length is 1.96 Å. Cl(1) is bonded in a distorted L-shaped geometry to one Ag(1) and one Ge(2) atom.