data_Gd3OsO7
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.44
_cell_length_b   6.44
_cell_length_c   7.4
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   69.3
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Gd3OsO7
_chemical_formula_sum   'Gd6 Os2 O14'
_cell_volume   287.05
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.0  0.0  0.0  1.0
  Gd  Gd1  1  0.92  0.52  0.85  1.0
  Gd  Gd2  1  0.67  0.52  0.85  1.0
  Gd  Gd3  1  0.0  0.0  0.7  1.0
  Gd  Gd4  1  0.92  0.48  0.55  1.0
  Gd  Gd5  1  0.67  0.48  0.55  1.0
  Os  Os20  1  0.3  0.0  0.0  1.0
  Os  Os21  1  0.3  0.0  0.7  1.0
  O  O6  1  0.94  0.4  0.29  1.0
  O  O7  1  0.65  0.4  0.29  1.0
  O  O8  1  0.41  0.18  0.85  1.0
  O  O9  1  0.3  0.33  0.85  1.0
  O  O10  1  0.19  0.18  0.85  1.0
  O  O11  1  0.94  0.4  0.41  1.0
  O  O12  1  0.65  0.4  0.41  1.0
  O  O13  1  0.94  0.6  0.99  1.0
  O  O14  1  0.65  0.6  0.99  1.0
  O  O15  1  0.41  0.82  0.55  1.0
  O  O16  1  0.3  0.67  0.55  1.0
  O  O17  1  0.19  0.82  0.55  1.0
  O  O18  1  0.94  0.6  0.11  1.0
  O  O19  1  0.65  0.6  0.11  1.0

data_Gd3OsO7
_symmetry_space_group_name_H-M   P1
_cell_length_a   6.44
_cell_length_b   6.44
_cell_length_c   7.4
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   110.7
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Gd3OsO7
_chemical_formula_sum   'Gd6 Os2 O14'
_cell_volume   287.05
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Gd  Gd0  1  0.0  0.0  0.0  1.0
  Gd  Gd1  1  0.0  0.0  0.3  1.0
  Gd  Gd2  1  0.67  0.48  0.15  1.0
  Gd  Gd3  1  0.67  0.52  0.45  1.0
  Gd  Gd4  1  0.92  0.48  0.15  1.0
  Gd  Gd5  1  0.92  0.52  0.45  1.0
  Os  Os6  1  0.3  0.0  0.0  1.0
  Os  Os7  1  0.3  0.0  0.3  1.0
  O  O8  1  0.19  0.18  0.45  1.0
  O  O9  1  0.19  0.82  0.15  1.0
  O  O10  1  0.3  0.33  0.45  1.0
  O  O11  1  0.3  0.67  0.15  1.0
  O  O12  1  0.41  0.18  0.45  1.0
  O  O13  1  0.41  0.82  0.15  1.0
  O  O14  1  0.65  0.4  0.01  1.0
  O  O15  1  0.65  0.4  0.89  1.0
  O  O16  1  0.65  0.6  0.59  1.0
  O  O17  1  0.65  0.6  0.71  1.0
  O  O18  1  0.94  0.4  0.01  1.0
  O  O19  1  0.94  0.4  0.89  1.0
  O  O20  1  0.94  0.6  0.59  1.0
  O  O21  1  0.94  0.6  0.71  1.0

Gd Gd Gd Gd Gd Gd Os Os O O O O O O O O O O O O O O
Gd Gd Gd Gd Gd Gd Os Os O O O O O O O O O O O O O O 0 12 o o - 0 3 o o - 0 6 o o o 1 15 o o o 2 16 o o o 3 19 o - o 3 7 o o o 4 13 o o o 5 14 o o o 6 12 o o - 6 10 o o - 7 19 o - o 7 12 o o o 7 17 o - o 7 10 o o o 8 13 o o o 9 14 o o o 10 11 o o o 10 12 o o o 11 12 o o o 15 20 o o + 16 21 o o + 17 18 o o o 17 19 o o o 18 19 o o o 
Gd3OsO7 crystallizes in the triclinic P1 space group. There are six inequivalent Gd sites. In the first Gd site, Gd(1) is bonded in a 6-coordinate geometry to one Gd(4), one Os(1), one O(1), one O(13), one O(5), and one O(8) atom. The Gd(1)-Gd(4) bond length is 2.21 Å. The Gd(1)-Os(1) bond length is 1.91 Å. The Gd(1)-O(1) bond length is 3.29 Å. The Gd(1)-O(13) bond length is 2.86 Å. The Gd(1)-O(5) bond length is 2.21 Å. The Gd(1)-O(8) bond length is 2.74 Å. In the second Gd site, Gd(2) is bonded in a single-bond geometry to one O(4) and one O(8) atom. The Gd(2)-O(4) bond length is 2.31 Å. The Gd(2)-O(8) bond length is 1.20 Å. In the third Gd site, Gd(3) is bonded in a single-bond geometry to one O(4) and one O(9) atom. The Gd(3)-O(4) bond length is 3.10 Å. The Gd(3)-O(9) bond length is 1.16 Å. In the fourth Gd site, Gd(4) is bonded in a 3-coordinate geometry to one Gd(1), one Os(2), one O(12), and one O(5) atom. The Gd(4)-Os(2) bond length is 1.91 Å. The Gd(4)-O(12) bond length is 1.72 Å. The Gd(4)-O(5) bond length is 2.21 Å. In the fifth Gd site, Gd(5) is bonded in a single-bond geometry to one O(11) and one O(6) atom. The Gd(5)-O(11) bond length is 3.10 Å. The Gd(5)-O(6) bond length is 1.16 Å. In the sixth Gd site, Gd(6) is bonded in a single-bond geometry to one O(10), one O(11), and one O(7) atom. The Gd(6)-O(10) bond length is 2.28 Å. The Gd(6)-O(11) bond length is 2.31 Å. The Gd(6)-O(7) bond length is 1.20 Å. There are two inequivalent Os sites. In the first Os site, Os(1) is bonded in a 1-coordinate geometry to one Gd(1), one O(3), and one O(5) atom. The Os(1)-O(3) bond length is 1.89 Å. The Os(1)-O(5) bond length is 1.56 Å. In the second Os site, Os(2) is bonded in a 5-coordinate geometry to one Gd(4), one O(10), one O(12), one O(3), and one O(5) atom. The Os(2)-O(10) bond length is 1.56 Å. The Os(2)-O(12) bond length is 1.89 Å. The Os(2)-O(3) bond length is 1.89 Å. The Os(2)-O(5) bond length is 1.56 Å. There are fourteen inequivalent O sites. In the first O site, O(1) is bonded in a 4-coordinate geometry to one Gd(1), one O(13), one O(2), and one O(6) atom. The O(1)-O(13) bond length is 1.84 Å. The O(1)-O(2) bond length is 1.88 Å. The O(1)-O(6) bond length is 0.87 Å. In the second O site, O(2) is bonded in a 3-coordinate geometry to one O(1), one O(14), and one O(7) atom. The O(2)-O(14) bond length is 1.84 Å. The O(2)-O(7) bond length is 0.87 Å. In the third O site, O(3) is bonded in a 4-coordinate geometry to one Os(1), one Os(2), one O(4), and one O(5) atom. The O(3)-O(4) bond length is 0.99 Å. The O(3)-O(5) bond length is 1.42 Å. In the fourth O site, O(4) is bonded in a 4-coordinate geometry to one Gd(2), one Gd(3), one O(3), and one O(5) atom. The O(4)-O(5) bond length is 1.40 Å. In the fifth O site, O(5) is bonded in a 2-coordinate geometry to one Gd(1), one Gd(4), one Os(1), one Os(2), one O(3), and one O(4) atom. In the sixth O site, O(6) is bonded in a single-bond geometry to one Gd(5) and one O(1) atom. In the seventh O site, O(7) is bonded in a single-bond geometry to one Gd(6) and one O(2) atom. In the eighth O site, O(8) is bonded in a distorted single-bond geometry to one Gd(1), one Gd(2), and one O(13) atom. The O(8)-O(13) bond length is 0.87 Å. In the ninth O site, O(9) is bonded in a distorted single-bond geometry to one Gd(3) and one O(14) atom. The O(9)-O(14) bond length is 0.87 Å. In the tenth O site, O(10) is bonded in a 2-coordinate geometry to one Gd(6), one Os(2), and one O(11) atom. The O(10)-O(11) bond length is 1.40 Å. In the eleventh O site, O(11) is bonded in a 4-coordinate geometry to one Gd(5), one Gd(6), one O(10), and one O(12) atom. The O(11)-O(12) bond length is 0.99 Å. In the twelfth O site, O(12) is bonded in a 1-coordinate geometry to one Gd(4), one Os(2), and one O(11) atom. In the thirteenth O site, O(13) is bonded in a distorted single-bond geometry to one Gd(1), one O(1), and one O(8) atom. In the fourteenth O site, O(14) is bonded in a distorted single-bond geometry to one O(2) and one O(9) atom.