data_MnRh2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.34
_cell_length_b   4.34
_cell_length_c   5.06
_cell_angle_alpha   98.65
_cell_angle_beta   98.65
_cell_angle_gamma   38.24
_symmetry_Int_Tables_number   1
_chemical_formula_structural   MnRh2Cl
_chemical_formula_sum   'Mn1 Rh2 Cl1'
_cell_volume   58.28
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn1  1  0.7  0.0  0.5  1.0
  Rh  Rh2  1  0.02  0.0  0.36  1.0
  Rh  Rh3  1  0.38  0.0  0.64  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_MnRh2Cl
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.84
_cell_length_b   4.34
_cell_length_c   5.06
_cell_angle_alpha   98.65
_cell_angle_beta   90.0
_cell_angle_gamma   109.12
_symmetry_Int_Tables_number   1
_chemical_formula_structural   MnRh2Cl
_chemical_formula_sum   'Mn1 Rh2 Cl1'
_cell_volume   58.28
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.0  0.3  0.5  1.0
  Rh  Rh1  1  0.0  0.62  0.36  1.0
  Rh  Rh2  1  0.0  0.98  0.64  1.0
  Cl  Cl3  1  0.0  0.0  0.0  1.0

Mn Rh Rh Cl
Mn Rh Rh Cl 0 2 o o o 0 1 + o o 1 3 o o o 1 2 o o o 
MnRh2Cl crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one MnRh2Cl cluster. Mn(1) is bonded in a distorted linear geometry to one Rh(1) and one Rh(2) atom. The Mn(1)-Rh(1) bond length is 1.64 Å. The Mn(1)-Rh(2) bond length is 1.64 Å. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a distorted bent 120 degrees geometry to one Mn(1) and one Cl(1) atom. The Rh(1)-Cl(1) bond length is 1.83 Å. In the second Rh site, Rh(2) is bonded in a distorted single-bond geometry to one Mn(1) atom. Cl(1) is bonded in a 1-coordinate geometry to one Rh(1) atom.