data_KZn2Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.92
_cell_length_b   4.92
_cell_length_c   3.05
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   KZn2Rh
_chemical_formula_sum   'K1 Zn2 Rh1'
_cell_volume   73.66
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  1  0.0  0.0  0.0  1.0
  Zn  Zn2  1  0.46  0.0  0.52  1.0
  Zn  Zn3  1  0.0  0.46  0.52  1.0
  Rh  Rh1  1  0.46  0.46  0.0  1.0

data_KZn2Rh
_symmetry_space_group_name_H-M   Cm
_cell_length_a   6.95
_cell_length_b   6.95
_cell_length_c   3.05
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   KZn2Rh
_chemical_formula_sum   'K2 Zn4 Rh2'
_cell_volume   147.31
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  2  0.0  0.0  0.0  1.0
  Zn  Zn1  4  0.23  0.23  0.52  1.0
  Rh  Rh2  2  0.46  0.0  0.0  1.0

K Zn Zn Rh
K Zn Zn Rh 0 1 - o - 0 1 - o o 0 1 o o - 0 1 o o o 0 2 o - - 0 2 o - o 0 2 o o - 0 2 o o o 0 0 o o + 0 3 o o o 1 2 o o o 1 3 o - o 1 3 o - + 1 3 o o o 1 3 o o + 1 1 o o + 2 3 - o o 2 3 - o + 2 3 o o o 2 3 o o + 2 2 o o + 3 3 o o + 
KRhZn2 is alpha iridium vanadium-derived structured and crystallizes in the monoclinic Cm space group. K(1) is bonded in a 8-coordinate geometry to eight equivalent Zn(1) atoms. There are a spread of K(1)-Zn(1) bond distances ranging from 2.68-3.10 Å. Rh(1) is bonded in a 8-coordinate geometry to eight equivalent Zn(1) atoms. There are a spread of Rh(1)-Zn(1) bond distances ranging from 2.68-3.10 Å. Zn(1) is bonded in a distorted body-centered cubic geometry to four equivalent K(1) and four equivalent Rh(1) atoms.