data_Ho3Co4Ge13
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   8.81
_cell_length_b   8.81
_cell_length_c   8.81
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ho3Co4Ge13
_chemical_formula_sum   'Ho6 Co8 Ge26'
_cell_volume   683.87
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  1  0.0  0.41  0.61  1.0
  Ho  Ho1  1  0.41  0.2  0.0  1.0
  Ho  Ho2  1  0.61  0.0  0.41  1.0
  Ho  Ho3  1  0.0  0.41  0.2  1.0
  Ho  Ho4  1  0.41  0.61  0.0  1.0
  Ho  Ho5  1  0.2  0.0  0.41  1.0
  Co  Co6  1  0.61  0.2  0.61  1.0
  Co  Co7  1  0.2  0.61  0.2  1.0
  Co  Co8  1  0.61  0.61  0.2  1.0
  Co  Co9  1  0.2  0.2  0.61  1.0
  Co  Co10  1  0.2  0.61  0.61  1.0
  Co  Co11  1  0.61  0.2  0.2  1.0
  Co  Co12  1  0.2  0.2  0.2  1.0
  Co  Co13  1  0.61  0.61  0.61  1.0
  Ge  Ge14  1  0.41  0.41  0.41  1.0
  Ge  Ge15  1  0.0  0.0  0.0  1.0
  Ge  Ge16  1  0.1  0.05  0.41  1.0
  Ge  Ge17  1  0.76  0.41  0.1  1.0
  Ge  Ge18  1  0.41  0.71  0.76  1.0
  Ge  Ge19  1  0.71  0.76  0.41  1.0
  Ge  Ge20  1  0.05  0.41  0.71  1.0
  Ge  Ge21  1  0.41  0.1  0.05  1.0
  Ge  Ge22  1  0.1  0.76  0.41  1.0
  Ge  Ge23  1  0.76  0.41  0.71  1.0
  Ge  Ge24  1  0.71  0.05  0.41  1.0
  Ge  Ge25  1  0.05  0.41  0.1  1.0
  Ge  Ge26  1  0.41  0.1  0.76  1.0
  Ge  Ge27  1  0.41  0.71  0.05  1.0
  Ge  Ge28  1  0.69  0.0  0.46  1.0
  Ge  Ge29  1  0.35  0.69  0.0  1.0
  Ge  Ge30  1  0.0  0.35  0.12  1.0
  Ge  Ge31  1  0.12  0.0  0.35  1.0
  Ge  Ge32  1  0.46  0.12  0.0  1.0
  Ge  Ge33  1  0.0  0.46  0.69  1.0
  Ge  Ge34  1  0.69  0.0  0.35  1.0
  Ge  Ge35  1  0.35  0.12  0.0  1.0
  Ge  Ge36  1  0.12  0.0  0.46  1.0
  Ge  Ge37  1  0.46  0.69  0.0  1.0
  Ge  Ge38  1  0.0  0.35  0.69  1.0
  Ge  Ge39  1  0.0  0.46  0.12  1.0

data_Ho3Co4Ge13
_symmetry_space_group_name_H-M   R3
_cell_length_a   12.46
_cell_length_b   12.46
_cell_length_c   15.26
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   146
_chemical_formula_structural   Ho3Co4Ge13
_chemical_formula_sum   'Ho18 Co24 Ge78'
_cell_volume   2051.61
_cell_formula_units_Z   6
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  'x+1/3, y+2/3, z+2/3'
  5  '-y+1/3, x-y+2/3, z+2/3'
  6  '-x+y+1/3, -x+2/3, z+2/3'
  7  'x+2/3, y+1/3, z+1/3'
  8  '-y+2/3, x-y+1/3, z+1/3'
  9  '-x+y+2/3, -x+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ho  Ho0  9  -0.0  0.8  0.2  1.0
  Ho  Ho1  9  0.07  0.34  0.34  1.0
  Co  Co2  9  0.06  0.53  0.14  1.0
  Co  Co3  9  0.2  0.4  0.0  1.0
  Co  Co4  3  0.0  0.0  0.2  1.0
  Co  Co5  3  0.0  0.0  0.61  1.0
  Ge  Ge6  9  0.01  0.35  0.35  1.0
  Ge  Ge7  9  0.01  0.66  0.75  1.0
  Ge  Ge8  9  0.01  0.34  0.39  1.0
  Ge  Ge9  9  0.07  0.38  0.38  1.0
  Ge  Ge10  9  0.09  0.22  0.63  1.0
  Ge  Ge11  9  0.14  0.74  0.86  1.0
  Ge  Ge12  9  0.18  0.7  0.82  1.0
  Ge  Ge13  9  0.2  0.76  0.85  1.0
  Ge  Ge14  3  0.0  0.0  0.0  1.0
  Ge  Ge15  3  0.0  0.0  0.41  1.0

Ho Ho Ho Ho Ho Ho Co Co Co Co Co Co Co Co Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge
Ho Ho Ho Ho Ho Ho Co Co Co Co Co Co Co Co Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge Ge 0 38 o o o 0 33 o o o 0 9 o o o 0 10 o o o 0 23 - o o 1 35 o o o 1 32 o o o 1 11 o o o 1 12 o o o 1 15 o o o 1 26 o o - 2 34 o o o 2 28 o o o 2 6 o o o 2 11 o o o 2 19 o - o 3 30 o o o 3 39 o o o 3 7 o o o 3 12 o o o 3 15 o o o 3 17 - o o 4 29 o o o 4 37 o o o 4 7 o o o 4 8 o o o 4 18 o o - 5 31 o o o 5 36 o o o 5 9 o o o 5 12 o o o 5 15 o o o 5 22 o - o 6 26 o o o 6 28 o o o 6 24 o o o 6 23 o o o 6 14 o o o 7 39 o o o 7 25 o o o 7 22 o o o 7 27 o o o 7 29 o o o 7 14 o o o 7 15 o + o 8 37 o o o 8 27 o o o 8 17 o o o 8 19 o o o 8 14 o o o 9 36 o o o 9 16 o o o 9 38 o o o 9 20 o o o 9 26 o o o 9 14 o o o 9 15 o o + 10 33 o o o 10 20 o o o 10 22 o o o 10 18 o o o 10 14 o o o 11 21 o o o 11 32 o o o 11 34 o o o 11 24 o o o 11 17 o o o 11 14 o o o 11 15 + o o 12 31 o o o 12 16 o o o 12 30 o o o 12 25 o o o 12 21 o o o 12 35 o o o 12 14 o o o 12 15 o o o 13 18 o o o 13 23 o o o 13 19 o o o 13 14 o o o 15 34 - o o 15 17 - o o 15 22 o - o 15 29 o - o 15 38 o o - 15 26 o o - 15 39 o o o 15 36 o o o 15 31 o o o 15 30 o o o 15 25 o o o 15 21 o o o 15 16 o o o 15 35 o o o 15 32 o o o 16 31 o o o 16 36 o o o 16 22 o - o 17 30 + o o 17 39 + o o 17 25 + o o 18 29 o o + 18 37 o o + 18 27 o o + 19 34 o + o 19 28 o + o 19 24 o + o 20 38 o o o 20 33 o o o 20 23 - o o 21 35 o o o 21 32 o o o 21 26 o o - 22 31 o + o 22 36 o + o 23 38 + o o 23 33 + o o 24 34 o o o 24 28 o o o 25 30 o o o 25 39 o o o 26 35 o o + 26 32 o o + 27 29 o o o 27 37 o o o 
Ho3Co4Ge13 crystallizes in the trigonal R3 space group. There are two inequivalent Ho sites. In the first Ho site, Ho(1) is bonded in a 2-coordinate geometry to one Co(1), one Co(2), one Ge(5), one Ge(6), one Ge(7), and one Ge(8) atom. The Ho(1)-Co(1) bond length is 2.52 Å. The Ho(1)-Co(2) bond length is 2.52 Å. The Ho(1)-Ge(5) bond length is 2.32 Å. The Ho(1)-Ge(6) bond length is 1.05 Å. The Ho(1)-Ge(7) bond length is 0.86 Å. The Ho(1)-Ge(8) bond length is 0.86 Å. In the second Ho site, Ho(2) is bonded in a 2-coordinate geometry to one Co(2), one Co(3), one Ge(10), one Ge(3), and one Ge(9) atom. The Ho(2)-Co(2) bond length is 2.52 Å. The Ho(2)-Co(3) bond length is 2.52 Å. The Ho(2)-Ge(10) bond length is 0.86 Å. The Ho(2)-Ge(3) bond length is 1.05 Å. The Ho(2)-Ge(9) bond length is 0.86 Å. There are four inequivalent Co sites. In the first Co site, Co(1) is bonded in a 6-coordinate geometry to one Ho(1), one Ge(1), one Ge(4), one Ge(5), one Ge(6), and one Ge(7) atom. The Co(1)-Ge(1) bond length is 3.09 Å. The Co(1)-Ge(4) bond length is 2.42 Å. The Co(1)-Ge(5) bond length is 2.42 Å. The Co(1)-Ge(6) bond length is 2.42 Å. The Co(1)-Ge(7) bond length is 2.34 Å. In the second Co site, Co(2) is bonded in a 8-coordinate geometry to one Ho(1), one Ho(2), one Ge(1), one Ge(10), one Ge(3), one Ge(4), one Ge(6), and one Ge(8) atom. The Co(2)-Ge(1) bond length is 3.09 Å. The Co(2)-Ge(10) bond length is 2.34 Å. The Co(2)-Ge(3) bond length is 2.42 Å. The Co(2)-Ge(4) bond length is 2.42 Å. The Co(2)-Ge(6) bond length is 2.42 Å. The Co(2)-Ge(8) bond length is 2.34 Å. In the third Co site, Co(3) is bonded in a 11-coordinate geometry to three equivalent Ho(2), one Ge(1), one Ge(2), three equivalent Ge(3), and three equivalent Ge(9) atoms. The Co(3)-Ge(1) bond length is 3.09 Å. The Co(3)-Ge(2) bond length is 3.09 Å. All Co(3)-Ge(3) bond lengths are 2.42 Å. All Co(3)-Ge(9) bond lengths are 2.34 Å. In the fourth Co site, Co(4) is bonded in a distorted trigonal pyramidal geometry to one Ge(1) and three equivalent Ge(5) atoms. The Co(4)-Ge(1) bond length is 3.09 Å. All Co(4)-Ge(5) bond lengths are 2.42 Å. There are ten inequivalent Ge sites. In the first Ge site, Ge(9) is bonded in a 1-coordinate geometry to one Ho(2), one Co(3), and one Ge(3) atom. The Ge(9)-Ge(3) bond length is 0.68 Å. In the second Ge site, Ge(1) is bonded in a body-centered cubic geometry to one Co(3), one Co(4), three equivalent Co(1), and three equivalent Co(2) atoms. In the third Ge site, Ge(2) is bonded in a single-bond geometry to one Co(3) atom. In the fourth Ge site, Ge(3) is bonded in a 3-coordinate geometry to one Ho(2), one Co(2), one Co(3), one Ge(10), and one Ge(9) atom. The Ge(3)-Ge(10) bond length is 0.68 Å. In the fifth Ge site, Ge(4) is bonded in a 2-coordinate geometry to one Co(1) and one Co(2) atom. In the sixth Ge site, Ge(5) is bonded in a 5-coordinate geometry to one Ho(1), one Co(1), one Co(4), one Ge(7), and one Ge(8) atom. The Ge(5)-Ge(7) bond length is 2.18 Å. The Ge(5)-Ge(8) bond length is 2.18 Å. In the seventh Ge site, Ge(6) is bonded in a 3-coordinate geometry to one Ho(1), one Co(1), one Co(2), one Ge(7), and one Ge(8) atom. The Ge(6)-Ge(7) bond length is 0.68 Å. The Ge(6)-Ge(8) bond length is 0.68 Å. In the eighth Ge site, Ge(7) is bonded in a 1-coordinate geometry to one Ho(1), one Co(1), one Ge(5), and one Ge(6) atom. In the ninth Ge site, Ge(10) is bonded in a 1-coordinate geometry to one Ho(2), one Co(2), and one Ge(3) atom. In the tenth Ge site, Ge(8) is bonded in a 1-coordinate geometry to one Ho(1), one Co(2), one Ge(5), and one Ge(6) atom.