data_Ga2Ag
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   7.19
_cell_length_b   7.19
_cell_length_c   4.92
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   154.95
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ga2Ag
_chemical_formula_sum   'Ga4 Ag2'
_cell_volume   107.88
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga2  1  0.56  0.4  0.69  1.0
  Ga  Ga3  1  0.56  0.7  0.69  1.0
  Ga  Ga4  1  0.56  0.3  0.23  1.0
  Ga  Ga5  1  0.56  0.6  0.23  1.0
  Ag  Ag0  1  0.56  0.0  0.69  1.0
  Ag  Ag1  1  0.56  1.0  0.23  1.0

data_Ga2Ag
_symmetry_space_group_name_H-M   P-1
_cell_length_a   3.12
_cell_length_b   4.92
_cell_length_c   7.19
_cell_angle_alpha   90.0
_cell_angle_beta   102.53
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   2
_chemical_formula_structural   Ga2Ag
_chemical_formula_sum   'Ga4 Ag2'
_cell_volume   107.88
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-x, -y, -z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  2  0.3  0.73  0.3  1.0
  Ga  Ga1  2  0.4  0.27  0.4  1.0
  Ag  Ag2  2  0.0  0.27  0.0  1.0

Ga Ga Ga Ga Ag Ag
Ga Ga Ga Ga Ag Ag 0 3 o o o 0 1 o o o 0 2 o o o 1 4 o + o 1 3 o o o 2 3 o o o 2 5 o - o 4 5 o - o 4 5 o - + 
AgGa2 crystallizes in the triclinic P-1 space group. Ag(1) is bonded in a 1-coordinate geometry to one Ga(1) and one Ga(2) atom. The Ag(1)-Ga(1) bond length is 2.85 Å. The Ag(1)-Ga(2) bond length is 2.21 Å. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 8-coordinate geometry to one Ag(1), three equivalent Ga(2), and four equivalent Ga(1) atoms. There are a spread of Ga(1)-Ga(2) bond distances ranging from 2.14-2.74 Å. There are a spread of Ga(1)-Ga(1) bond distances ranging from 2.69-3.12 Å. In the second Ga site, Ga(2) is bonded in a 4-coordinate geometry to one Ag(1) and three equivalent Ga(1) atoms.