data_DySi2Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.58
_cell_length_b   4.58
_cell_length_c   4.58
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   DySi2Rh
_chemical_formula_sum   'Dy1 Si2 Rh1'
_cell_volume   68.14
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  1  0.24  0.24  0.24  1.0
  Si  Si2  1  0.62  0.62  0.62  1.0
  Si  Si3  1  0.86  0.86  0.86  1.0
  Rh  Rh1  1  0.0  0.0  0.0  1.0

data_DySi2Rh
_symmetry_space_group_name_H-M   R3m
_cell_length_a   4.58
_cell_length_b   4.58
_cell_length_c   11.23
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   DySi2Rh
_chemical_formula_sum   'Dy3 Si6 Rh3'
_cell_volume   204.42
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Dy  Dy0  3  0.0  0.0  0.76  1.0
  Si  Si1  3  0.0  0.0  0.14  1.0
  Si  Si2  3  0.0  0.0  0.38  1.0
  Rh  Rh3  3  0.0  0.0  0.0  1.0

Dy Si Si Rh
Dy Si Si Rh 0 3 o o o 0 3 o o + 0 3 + o o 0 3 o + o 0 2 - - o 0 2 - o - 0 2 o - - 0 1 - o o 0 1 o - o 0 1 o o - 1 2 o - o 1 2 - o o 1 2 o o - 1 2 o o o 1 3 o + + 1 3 + o + 1 3 + + o 2 3 + + + 
DyRhSi2 crystallizes in the trigonal R3m space group. Dy(1) is bonded in a 10-coordinate geometry to four equivalent Rh(1), three equivalent Si(1), and three equivalent Si(2) atoms. There is one shorter (2.72 Å) and three longer (2.84 Å) Dy(1)-Rh(1) bond lengths. All Dy(1)-Si(1) bond lengths are 2.70 Å. All Dy(1)-Si(2) bond lengths are 2.70 Å. Rh(1) is bonded in a distorted single-bond geometry to four equivalent Dy(1), one Si(2), and three equivalent Si(1) atoms. The Rh(1)-Si(2) bond length is 1.54 Å. All Rh(1)-Si(1) bond lengths are 2.70 Å. There are two inequivalent Si sites. In the first Si site, Si(1) is bonded in a 7-coordinate geometry to three equivalent Dy(1), three equivalent Rh(1), and one Si(2) atom. The Si(1)-Si(2) bond length is 2.72 Å. In the second Si site, Si(2) is bonded in a single-bond geometry to three equivalent Dy(1), one Rh(1), and one Si(1) atom.