data_ZnInAg2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.03
_cell_length_b   5.03
_cell_length_c   5.19
_cell_angle_alpha   101.99
_cell_angle_beta   101.99
_cell_angle_gamma   35.89
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnInAg2
_chemical_formula_sum   'Zn1 In1 Ag2'
_cell_volume   75.02
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn3  1  0.0  0.0  0.0  1.0
  In  In2  1  0.22  0.0  0.53  1.0
  Ag  Ag0  1  0.62  0.0  0.87  1.0
  Ag  Ag1  1  0.82  0.0  0.19  1.0

data_ZnInAg2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.1
_cell_length_b   5.03
_cell_length_c   5.19
_cell_angle_alpha   101.99
_cell_angle_beta   90.0
_cell_angle_gamma   107.94
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnInAg2
_chemical_formula_sum   'Zn1 In1 Ag2'
_cell_volume   75.02
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.0  0.0  0.0  1.0
  In  In1  1  0.0  0.78  0.47  1.0
  Ag  Ag2  1  0.0  0.18  0.81  1.0
  Ag  Ag3  1  0.0  0.38  0.13  1.0

Zn In Ag Ag
Zn In Ag Ag 0 3 - o o 0 1 o o o 0 1 o o - 0 2 - o - 1 3 - o o 1 2 o o o 2 3 o o + 
Ag2ZnIn crystallizes in the triclinic P1 space group. There are two inequivalent Ag sites. In the first Ag site, Ag(1) is bonded in a 3-coordinate geometry to one Ag(2), one Zn(1), and two equivalent In(1) atoms. The Ag(1)-Ag(2) bond length is 1.77 Å. The Ag(1)-Zn(1) bond length is 1.89 Å. There is one shorter (2.38 Å) and one longer (3.38 Å) Ag(1)-In(1) bond length. In the second Ag site, Ag(2) is bonded in a distorted single-bond geometry to one Ag(1), one Zn(1), and two equivalent In(1) atoms. The Ag(2)-Zn(1) bond length is 1.50 Å. There is one shorter (2.38 Å) and one longer (3.38 Å) Ag(2)-In(1) bond length. Zn(1) is bonded in a 1-coordinate geometry to one Ag(1), one Ag(2), and two equivalent In(1) atoms. There is one shorter (2.74 Å) and one longer (2.87 Å) Zn(1)-In(1) bond length. In(1) is bonded in a 8-coordinate geometry to two equivalent Ag(1), two equivalent Ag(2), two equivalent Zn(1), and two equivalent In(1) atoms. Both In(1)-In(1) bond lengths are 3.10 Å.