data_TaVCd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.85
_cell_length_b   4.69
_cell_length_c   5.45
_cell_angle_alpha   90.0
_cell_angle_beta   92.91
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TaVCd2
_chemical_formula_sum   'Ta1 V1 Cd2'
_cell_volume   72.84
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ta  Ta2  1  0.1  0.35  0.73  1.0
  V  V3  1  0.66  0.0  0.07  1.0
  Cd  Cd0  1  0.3  0.35  0.34  1.0
  Cd  Cd1  1  0.37  0.0  0.47  1.0

data_TaVCd2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.85
_cell_length_b   4.69
_cell_length_c   5.45
_cell_angle_alpha   90.0
_cell_angle_beta   92.91
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TaVCd2
_chemical_formula_sum   'Ta1 V1 Cd2'
_cell_volume   72.84
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ta  Ta0  1  0.1  0.35  0.73  1.0
  V  V1  1  0.66  0.0  0.07  1.0
  Cd  Cd2  1  0.3  0.35  0.34  1.0
  Cd  Cd3  1  0.37  0.0  0.47  1.0

Ta V Cd Cd
Ta V Cd Cd 0 1 - o + 0 1 o o + 0 0 + o o 0 3 o o o 0 2 o o o 1 3 o o o 1 3 + o o 1 2 o o o 1 2 + o o 1 1 + o o 2 3 o o o 
TaVCd2 crystallizes in the triclinic P1 space group. Ta(1) is bonded in a 2-coordinate geometry to four equivalent V(1), one Cd(1), and one Cd(2) atom. There are a spread of Ta(1)-V(1) bond distances ranging from 2.81-3.87 Å. The Ta(1)-Cd(1) bond length is 2.28 Å. The Ta(1)-Cd(2) bond length is 2.33 Å. V(1) is bonded in a 12-coordinate geometry to four equivalent Ta(1), two equivalent V(1), three equivalent Cd(1), and three equivalent Cd(2) atoms. Both V(1)-V(1) bond lengths are 2.85 Å. There are a spread of V(1)-Cd(1) bond distances ranging from 2.42-3.55 Å. There are a spread of V(1)-Cd(2) bond distances ranging from 2.35-3.35 Å. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a 2-coordinate geometry to one Ta(1), three equivalent V(1), and one Cd(2) atom. The Cd(1)-Cd(2) bond length is 1.79 Å. In the second Cd site, Cd(2) is bonded in a 3-coordinate geometry to one Ta(1), three equivalent V(1), and one Cd(1) atom.