data_AgSbP2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.65
_cell_length_b   3.65
_cell_length_c   5.99
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   AgSbP2
_chemical_formula_sum   'Ag1 Sb1 P2'
_cell_volume   79.79
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  1  0.0  0.0  0.0  1.0
  Sb  Sb3  1  0.0  0.0  0.99  1.0
  P  P1  1  0.82  0.82  0.1  1.0
  P  P2  1  0.82  0.82  0.89  1.0

data_AgSbP2
_symmetry_space_group_name_H-M   Amm2
_cell_length_a   5.99
_cell_length_b   5.16
_cell_length_c   5.16
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   38
_chemical_formula_structural   AgSbP2
_chemical_formula_sum   'Ag2 Sb2 P4'
_cell_volume   159.58
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-x, -y, z'
  3  '-x, y, z'
  4  'x, -y, z'
  5  'x, y+1/2, z+1/2'
  6  '-x, -y+1/2, z+1/2'
  7  '-x, y+1/2, z+1/2'
  8  'x, -y+1/2, z+1/2'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ag  Ag0  2  0.0  0.0  0.0  1.0
  Sb  Sb1  2  0.0  0.0  0.0  1.0
  P  P2  4  0.1  0.0  0.82  1.0

Ag Sb P P
Ag Sb P P 0 1 o o - 0 2 - - o 0 3 - - - 1 2 - - + 1 3 - - o 2 3 o o - 
AgSbP2 is alpha Niobium phosphide-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two AgSbP2 clusters. Ag(1) is bonded in a single-bond geometry to one Sb(1) and one P(1) atom. The Ag(1)-Sb(1) bond length is 0.03 Å. The Ag(1)-P(1) bond length is 1.07 Å. Sb(1) is bonded in a single-bond geometry to one Ag(1) and one P(2) atom. The Sb(1)-P(2) bond length is 1.09 Å. There are two inequivalent P sites. In the first P site, P(1) is bonded in a 2-coordinate geometry to one Ag(1) and one P(2) atom. The P(1)-P(2) bond length is 1.23 Å. In the second P site, P(2) is bonded in a 2-coordinate geometry to one Sb(1) and one P(1) atom.