data_MnRh2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.26
_cell_length_b   5.26
_cell_length_c   5.26
_cell_angle_alpha   148.02
_cell_angle_beta   129.45
_cell_angle_gamma   61.08
_symmetry_Int_Tables_number   1
_chemical_formula_structural   MnRh2Cl
_chemical_formula_sum   'Mn1 Rh2 Cl1'
_cell_volume   58.87
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn1  1  0.45  0.0  0.38  1.0
  Rh  Rh2  1  0.0  0.0  0.05  1.0
  Rh  Rh3  1  0.0  0.24  0.13  1.0
  Cl  Cl0  1  0.0  0.0  0.54  1.0

data_MnRh2Cl
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.9
_cell_length_b   4.49
_cell_length_c   5.26
_cell_angle_alpha   115.28
_cell_angle_beta   105.99
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   MnRh2Cl
_chemical_formula_sum   'Mn1 Rh2 Cl1'
_cell_volume   58.87
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Mn  Mn0  1  0.0  0.38  0.93  1.0
  Rh  Rh1  1  0.0  0.05  0.05  1.0
  Rh  Rh2  1  0.76  0.89  0.89  1.0
  Cl  Cl3  1  0.0  0.54  0.54  1.0

Mn Rh Rh Cl
Mn Rh Rh Cl 0 2 o o o 0 1 o o o 0 3 + o o 1 2 o o o 1 3 o o o 1 3 o o - 2 3 o o - 2 3 o + o 
MnRh2Cl crystallizes in the triclinic P1 space group. Mn(1) is bonded in a 1-coordinate geometry to one Rh(1), one Rh(2), and two equivalent Cl(1) atoms. The Mn(1)-Rh(1) bond length is 1.83 Å. The Mn(1)-Rh(2) bond length is 2.47 Å. There is one shorter (2.45 Å) and one longer (2.97 Å) Mn(1)-Cl(1) bond length. There are two inequivalent Rh sites. In the first Rh site, Rh(1) is bonded in a 3-coordinate geometry to one Mn(1), one Rh(2), and one Cl(1) atom. The Rh(1)-Rh(2) bond length is 0.96 Å. The Rh(1)-Cl(1) bond length is 2.57 Å. In the second Rh site, Rh(2) is bonded in a 4-coordinate geometry to one Mn(1), one Rh(1), and two equivalent Cl(1) atoms. There is one shorter (2.12 Å) and one longer (2.43 Å) Rh(2)-Cl(1) bond length. Cl(1) is bonded in a 5-coordinate geometry to two equivalent Mn(1), one Rh(1), and two equivalent Rh(2) atoms.