data_TiVMo
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.35
_cell_length_b   4.35
_cell_length_c   2.79
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TiVMo
_chemical_formula_sum   'Ti1 V1 Mo1'
_cell_volume   45.71
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti1  1  0.0  0.0  0.86  1.0
  V  V2  1  0.0  0.51  0.97  1.0
  Mo  Mo0  1  0.17  0.26  0.75  1.0

data_TiVMo
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.79
_cell_length_b   4.35
_cell_length_c   4.35
_cell_angle_alpha   120.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TiVMo
_chemical_formula_sum   'Ti1 V1 Mo1'
_cell_volume   45.71
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ti  Ti0  1  0.86  0.0  0.0  1.0
  V  V1  1  0.97  0.0  0.51  1.0
  Mo  Mo2  1  0.75  0.17  0.26  1.0

Ti V Mo
Ti V Mo 0 2 o o o 1 2 o o o 
TiVMo crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one molybdenum;titanium;vanadium molecule. Ti(1) is bonded in a single-bond geometry to one Mo(1) atom. The Ti(1)-Mo(1) bond length is 1.03 Å. V(1) is bonded in a distorted single-bond geometry to one Mo(1) atom. The V(1)-Mo(1) bond length is 1.74 Å. Mo(1) is bonded in a distorted water-like geometry to one Ti(1) and one V(1) atom.