data_Ga2RhW
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.15
_cell_length_b   3.15
_cell_length_c   6.09
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Ga2RhW
_chemical_formula_sum   'Ga2 Rh1 W1'
_cell_volume   60.24
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  1  0.0  0.0  0.02  1.0
  Ga  Ga1  1  0.57  0.57  0.58  1.0
  Rh  Rh2  1  0.0  0.0  0.94  1.0
  W  W3  1  0.57  0.57  0.59  1.0

data_Ga2RhW
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.45
_cell_length_b   4.45
_cell_length_c   6.09
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   Ga2RhW
_chemical_formula_sum   'Ga4 Rh2 W2'
_cell_volume   120.48
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ga  Ga0  2  0.0  0.0  0.02  1.0
  Ga  Ga1  2  0.07  0.5  0.58  1.0
  Rh  Rh2  2  0.0  0.0  0.94  1.0
  W  W3  2  0.07  0.5  0.59  1.0

Ga Ga Rh W
Ga Ga Rh W 0 2 o o - 1 3 o o o 
WGaRhGa is Cubic alpha N2-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two gallium;tungsten molecules and two RhGa clusters. In each RhGa cluster, Rh(1) is bonded in a single-bond geometry to one Ga(1) atom. The Rh(1)-Ga(1) bond length is 0.45 Å. Ga(1) is bonded in a single-bond geometry to one Rh(1) atom.