data_LaPd2W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.15
_cell_length_b   5.15
_cell_length_c   2.97
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   108.98
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LaPd2W
_chemical_formula_sum   'La1 Pd2 W1'
_cell_volume   74.51
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.0  0.0  0.0  1.0
  Pd  Pd1  1  0.5  0.1  0.48  1.0
  Pd  Pd2  1  0.5  0.9  0.48  1.0
  W  W3  1  0.99  0.0  0.0  1.0

data_LaPd2W
_symmetry_space_group_name_H-M   P2
_cell_length_a   5.15
_cell_length_b   2.97
_cell_length_c   5.15
_cell_angle_alpha   90.0
_cell_angle_beta   108.98
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   3
_chemical_formula_structural   LaPd2W
_chemical_formula_sum   'La1 Pd2 W1'
_cell_volume   74.51
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-x, y, -z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  La  La0  1  0.0  0.0  0.0  1.0
  Pd  Pd1  2  0.5  0.52  0.1  1.0
  W  W2  1  0.0  -0.0  0.0  1.0

La Pd Pd W
La Pd Pd W 0 3 - o o 1 2 o - o 
WLa(Pd)2 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one lanthanum;tungsten molecule and one Pd cluster. In the Pd cluster, there are two inequivalent Pd sites. In the first Pd site, Pd(1) is bonded in a distorted single-bond geometry to one Pd(2) atom. The Pd(1)-Pd(2) bond length is 1.01 Å. In the second Pd site, Pd(2) is bonded in a single-bond geometry to one Pd(1) atom.