data_InNi2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.24
_cell_length_b   3.24
_cell_length_c   6.14
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   InNi2Cl
_chemical_formula_sum   'In1 Ni2 Cl1'
_cell_volume   64.3
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In1  1  0.0  0.0  0.07  1.0
  Ni  Ni2  1  0.62  0.62  0.41  1.0
  Ni  Ni3  1  0.62  0.62  0.73  1.0
  Cl  Cl0  1  0.0  0.0  0.0  1.0

data_InNi2Cl
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.58
_cell_length_b   4.58
_cell_length_c   6.14
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   InNi2Cl
_chemical_formula_sum   'In2 Ni4 Cl2'
_cell_volume   128.6
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  In  In0  2  0.0  0.0  0.07  1.0
  Ni  Ni1  2  0.12  0.5  0.41  1.0
  Ni  Ni2  2  0.12  0.5  0.73  1.0
  Cl  Cl3  2  0.0  0.0  0.0  1.0

In Ni Ni Cl
In Ni Ni Cl 0 3 o o o 1 2 o o o 
Ni2InCl crystallizes in the monoclinic Cm space group. There are two inequivalent Ni sites. In the first Ni site, Ni(1) is bonded in a 4-coordinate geometry to one Ni(2) and three equivalent In(1) atoms. The Ni(1)-Ni(2) bond length is 1.93 Å. There is one shorter (2.74 Å) and two longer (3.16 Å) Ni(1)-In(1) bond lengths. In the second Ni site, Ni(2) is bonded in a 4-coordinate geometry to one Ni(1) and three equivalent Cl(1) atoms. There is one shorter (2.42 Å) and two longer (2.88 Å) Ni(2)-Cl(1) bond lengths. In(1) is bonded in a single-bond geometry to three equivalent Ni(1) and one Cl(1) atom. The In(1)-Cl(1) bond length is 0.44 Å. Cl(1) is bonded in a single-bond geometry to three equivalent Ni(2) and one In(1) atom.