data_VMoPt2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.47
_cell_length_b   4.47
_cell_length_c   4.47
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   VMoPt2
_chemical_formula_sum   'V1 Mo1 Pt2'
_cell_volume   62.97
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V3  1  0.0  0.0  0.0  1.0
  Mo  Mo0  1  0.16  0.16  0.16  1.0
  Pt  Pt1  1  0.58  0.58  0.58  1.0
  Pt  Pt2  1  0.74  0.74  0.74  1.0

data_VMoPt2
_symmetry_space_group_name_H-M   R3m
_cell_length_a   4.47
_cell_length_b   4.47
_cell_length_c   10.94
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   VMoPt2
_chemical_formula_sum   'V3 Mo3 Pt6'
_cell_volume   188.91
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  V  V0  3  0.0  0.0  0.0  1.0
  Mo  Mo1  3  0.0  0.0  0.84  1.0
  Pt  Pt2  3  0.0  0.0  0.26  1.0
  Pt  Pt3  3  0.0  0.0  0.42  1.0

V Mo Pt Pt
V Mo Pt Pt 0 1 o o o 2 3 o o o 
VMoPt2 crystallizes in the trigonal R3m space group. V(1) is bonded in a single-bond geometry to one Mo(1), three equivalent Pt(1), and four equivalent Pt(2) atoms. The V(1)-Mo(1) bond length is 1.72 Å. All V(1)-Pt(1) bond lengths are 2.75 Å. There are three shorter (2.69 Å) and one longer (2.88 Å) V(1)-Pt(2) bond length. Mo(1) is bonded in a single-bond geometry to one V(1), three equivalent Pt(1), and three equivalent Pt(2) atoms. All Mo(1)-Pt(1) bond lengths are 2.75 Å. All Mo(1)-Pt(2) bond lengths are 2.75 Å. There are two inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a 7-coordinate geometry to three equivalent V(1), three equivalent Mo(1), and one Pt(2) atom. The Pt(1)-Pt(2) bond length is 1.72 Å. In the second Pt site, Pt(2) is bonded in a 8-coordinate geometry to four equivalent V(1), three equivalent Mo(1), and one Pt(1) atom.