data_BeGa4Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.11
_cell_length_b   5.11
_cell_length_c   5.11
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   BeGa4Rh
_chemical_formula_sum   'Be1 Ga4 Rh1'
_cell_volume   94.2
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Be  Be0  1  0.0  0.0  0.0  1.0
  Ga  Ga1  1  0.51  0.51  0.71  1.0
  Ga  Ga2  1  0.51  0.71  0.51  1.0
  Ga  Ga3  1  0.71  0.51  0.51  1.0
  Ga  Ga4  1  0.71  0.71  0.71  1.0
  Rh  Rh5  1  0.42  0.42  0.42  1.0

data_BeGa4Rh
_symmetry_space_group_name_H-M   R3m
_cell_length_a   5.11
_cell_length_b   5.11
_cell_length_c   12.51
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   BeGa4Rh
_chemical_formula_sum   'Be3 Ga12 Rh3'
_cell_volume   282.59
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Be  Be0  3  0.0  0.0  0.0  1.0
  Ga  Ga1  9  0.07  0.13  0.42  1.0
  Ga  Ga2  3  0.0  0.0  0.29  1.0
  Rh  Rh3  3  0.0  0.0  0.58  1.0

Be Ga Ga Ga Ga Rh
Be Ga Ga Ga Ga Rh 0 4 - - o 0 4 - o - 0 4 o - - 0 3 - - o 0 3 - o - 0 2 - - o 0 2 o - - 0 1 - o - 0 1 o - - 0 5 - o o 0 5 o - o 0 5 o o - 1 3 o o o 1 2 o o o 1 4 o o o 1 5 o o o 2 3 o o o 2 4 o o o 2 5 o o o 3 4 o o o 3 5 o o o 
BeRhGa4 crystallizes in the trigonal R3m space group. Be(1) is bonded in a 12-coordinate geometry to three equivalent Rh(1) atoms. All Be(1)-Rh(1) bond lengths are 3.13 Å. Rh(1) is bonded in a 12-coordinate geometry to three equivalent Be(1), three equivalent Ga(2), and six equivalent Ga(1) atoms. All Rh(1)-Ga(2) bond lengths are 2.99 Å. There are three shorter (2.10 Å) and three longer (3.20 Å) Rh(1)-Ga(1) bond lengths. There are two inequivalent Ga sites. In the first Ga site, Ga(1) is bonded in a 2-coordinate geometry to two equivalent Rh(1), one Ga(2), and two equivalent Ga(1) atoms. The Ga(1)-Ga(2) bond length is 1.75 Å. Both Ga(1)-Ga(1) bond lengths are 1.01 Å. In the second Ga site, Ga(2) is bonded in a 6-coordinate geometry to three equivalent Rh(1) and three equivalent Ga(1) atoms.