data_TaCd2P
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   9.65
_cell_length_b   9.65
_cell_length_c   9.65
_cell_angle_alpha   18.24
_cell_angle_beta   18.24
_cell_angle_gamma   18.24
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TaCd2P
_chemical_formula_sum   'Ta1 Cd2 P1'
_cell_volume   76.77
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ta  Ta3  1  0.0  0.0  0.23  1.0
  Cd  Cd0  1  0.0  0.0  0.2  1.0
  Cd  Cd1  1  0.0  0.0  0.25  1.0
  P  P2  1  0.0  0.0  0.0  1.0

data_TaCd2P
_symmetry_space_group_name_H-M   Cm
_cell_length_a   5.3
_cell_length_b   3.06
_cell_length_c   9.65
_cell_angle_alpha   90.0
_cell_angle_beta   100.54
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   TaCd2P
_chemical_formula_sum   'Ta2 Cd4 P2'
_cell_volume   153.53
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Ta  Ta0  2  -0.0  0.0  0.77  1.0
  Cd  Cd1  2  -0.0  0.0  0.75  1.0
  Cd  Cd2  2  -0.0  0.0  0.8  1.0
  P  P3  2  -0.0  0.0  0.0  1.0

Ta Cd Cd P
Ta Cd Cd P 0 1 o o o 0 2 o o o 0 3 o o o 1 3 o o o 
TaCd2P is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two TaCd2P clusters. Ta(1) is bonded in a linear geometry to one Cd(1) and one Cd(2) atom. The Ta(1)-Cd(1) bond length is 0.26 Å. The Ta(1)-Cd(2) bond length is 0.26 Å. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a distorted single-bond geometry to one Ta(1) and one P(1) atom. The Cd(1)-P(1) bond length is 1.91 Å. In the second Cd site, Cd(2) is bonded in a single-bond geometry to one Ta(1) atom. P(1) is bonded in a single-bond geometry to one Cd(1) atom.