data_TlCd2W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.05
_cell_length_b   6.05
_cell_length_c   6.05
_cell_angle_alpha   150.57
_cell_angle_beta   128.59
_cell_angle_gamma   60.35
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlCd2W
_chemical_formula_sum   'Tl1 Cd2 W1'
_cell_volume   84.34
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl2  1  0.0  0.62  0.14  1.0
  Cd  Cd0  1  0.0  0.62  0.1  1.0
  Cd  Cd1  1  0.0  0.0  0.55  1.0
  W  W3  1  0.0  0.0  0.9  1.0

data_TlCd2W
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.07
_cell_length_b   5.25
_cell_length_c   6.05
_cell_angle_alpha   115.7
_cell_angle_beta   104.72
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlCd2W
_chemical_formula_sum   'Tl1 Cd2 W1'
_cell_volume   84.34
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.86  0.48  0.48  1.0
  Cd  Cd1  1  0.45  0.45  0.45  1.0
  Cd  Cd2  1  0.9  0.52  0.52  1.0
  W  W3  1  0.1  0.1  0.1  1.0

Tl Cd Cd W
Tl Cd Cd W 0 1 o o o 0 2 o + o 1 2 o + o 2 3 o o o 
WCd2Tl crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one WCd2Tl cluster. W(1) is bonded in a distorted single-bond geometry to one Cd(2) atom. The W(1)-Cd(2) bond length is 2.07 Å. There are two inequivalent Cd sites. In the first Cd site, Cd(1) is bonded in a single-bond geometry to one Tl(1) atom. The Cd(1)-Tl(1) bond length is 0.25 Å. In the second Cd site, Cd(2) is bonded in a distorted bent 120 degrees geometry to one W(1) and one Tl(1) atom. The Cd(2)-Tl(1) bond length is 1.23 Å. Tl(1) is bonded in a distorted single-bond geometry to one Cd(1) and one Cd(2) atom.