data_CsSrV2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   5.9
_cell_length_b   5.9
_cell_length_c   5.9
_cell_angle_alpha   60.0
_cell_angle_beta   60.0
_cell_angle_gamma   60.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   CsSrV2
_chemical_formula_sum   'Cs1 Sr1 V2'
_cell_volume   145.2
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  1  0.17  0.17  0.17  1.0
  Sr  Sr1  1  0.0  0.0  0.0  1.0
  V  V2  1  0.26  0.26  0.26  1.0
  V  V3  1  0.09  0.09  0.09  1.0

data_CsSrV2
_symmetry_space_group_name_H-M   R3m
_cell_length_a   5.9
_cell_length_b   5.9
_cell_length_c   14.45
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   120.0
_symmetry_Int_Tables_number   160
_chemical_formula_structural   CsSrV2
_chemical_formula_sum   'Cs3 Sr3 V6'
_cell_volume   435.61
_cell_formula_units_Z   3
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  '-y, x-y, z'
  3  '-x+y, -x, z'
  4  '-y, -x, z'
  5  '-x+y, y, z'
  6  'x, x-y, z'
  7  'x+1/3, y+2/3, z+2/3'
  8  '-y+1/3, x-y+2/3, z+2/3'
  9  '-x+y+1/3, -x+2/3, z+2/3'
  10  '-y+1/3, -x+2/3, z+2/3'
  11  '-x+y+1/3, y+2/3, z+2/3'
  12  'x+1/3, x-y+2/3, z+2/3'
  13  'x+2/3, y+1/3, z+1/3'
  14  '-y+2/3, x-y+1/3, z+1/3'
  15  '-x+y+2/3, -x+1/3, z+1/3'
  16  '-y+2/3, -x+1/3, z+1/3'
  17  '-x+y+2/3, y+1/3, z+1/3'
  18  'x+2/3, x-y+1/3, z+1/3'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Cs  Cs0  3  0.0  0.0  0.83  1.0
  Sr  Sr1  3  0.0  0.0  0.0  1.0
  V  V2  3  0.0  0.0  0.74  1.0
  V  V3  3  0.0  0.0  0.91  1.0

Cs Sr V V
Cs Sr V V 0 3 o o o 0 2 o o o 1 3 o o o 
CsSrV2 is Copper structured and crystallizes in the trigonal R3m space group. The structure is zero-dimensional and consists of three CsSrV2 clusters. Cs(1) is bonded in a linear geometry to one V(1) and one V(2) atom. The Cs(1)-V(1) bond length is 1.24 Å. The Cs(1)-V(2) bond length is 1.24 Å. Sr(1) is bonded in a single-bond geometry to one V(2) atom. The Sr(1)-V(2) bond length is 1.24 Å. There are two inequivalent V sites. In the first V site, V(1) is bonded in a single-bond geometry to one Cs(1) atom. In the second V site, V(2) is bonded in a linear geometry to one Cs(1) and one Sr(1) atom.