data_TlPt2W
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.94
_cell_length_b   4.82
_cell_length_c   4.94
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlPt2W
_chemical_formula_sum   'Tl1 Pt2 W1'
_cell_volume   70.04
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl2  1  0.47  0.0  0.47  1.0
  Pt  Pt0  1  0.0  0.41  0.47  1.0
  Pt  Pt1  1  0.47  0.41  0.0  1.0
  W  W3  1  0.0  0.0  0.0  1.0

data_TlPt2W
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.94
_cell_length_b   4.82
_cell_length_c   4.94
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   TlPt2W
_chemical_formula_sum   'Tl1 Pt2 W1'
_cell_volume   70.04
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tl  Tl0  1  0.47  0.0  0.47  1.0
  Pt  Pt1  1  -0.0  0.41  0.47  1.0
  Pt  Pt2  1  0.47  0.41  0.0  1.0
  W  W3  1  0.0  0.0  0.0  1.0

Tl Pt Pt W
Tl Pt Pt W 0 1 o - o 0 1 o o o 0 1 + o o 0 3 o o o 0 3 o o + 0 3 + o o 0 3 + o + 0 0 + o o 0 2 o o o 1 2 - o o 1 2 - o + 1 2 o o o 1 2 o o + 1 1 + o o 1 3 o o o 2 3 o o o 2 3 o + o 2 3 + o o 2 2 + o o 3 3 + o o 
WPt2Tl crystallizes in the triclinic P1 space group. W(1) is bonded in a 6-coordinate geometry to two equivalent Pt(2) and four equivalent Tl(1) atoms. There is one shorter (2.41 Å) and one longer (2.51 Å) W(1)-Pt(2) bond length. There are a spread of W(1)-Tl(1) bond distances ranging from 2.70-3.05 Å. There are two inequivalent Pt sites. In the first Pt site, Pt(1) is bonded in a 2-coordinate geometry to four equivalent Tl(1) atoms. There are a spread of Pt(1)-Tl(1) bond distances ranging from 2.41-3.24 Å. In the second Pt site, Pt(2) is bonded in a 2-coordinate geometry to two equivalent W(1) atoms. Tl(1) is bonded in a 8-coordinate geometry to four equivalent W(1) and four equivalent Pt(1) atoms.