data_ZrSb2Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.12
_cell_length_b   4.94
_cell_length_c   5.76
_cell_angle_alpha   90.0
_cell_angle_beta   105.7
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZrSb2Rh
_chemical_formula_sum   'Zr1 Sb2 Rh1'
_cell_volume   85.42
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr3  1  0.58  0.0  0.69  1.0
  Sb  Sb1  1  0.04  0.0  0.24  1.0
  Sb  Sb2  1  0.1  0.47  0.64  1.0
  Rh  Rh0  1  0.06  0.47  0.28  1.0

data_ZrSb2Rh
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.12
_cell_length_b   4.94
_cell_length_c   5.76
_cell_angle_alpha   90.0
_cell_angle_beta   105.7
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZrSb2Rh
_chemical_formula_sum   'Zr1 Sb2 Rh1'
_cell_volume   85.42
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zr  Zr0  1  0.58  0.0  0.69  1.0
  Sb  Sb1  1  0.04  0.0  0.24  1.0
  Sb  Sb2  1  0.1  0.47  0.64  1.0
  Rh  Rh3  1  0.06  0.47  0.28  1.0

Zr Sb Sb Rh
Zr Sb Sb Rh 0 2 o - o 0 2 o o o 0 2 + - o 0 2 + o o 0 3 o o o 0 1 o o o 0 1 + o o 0 1 + o + 0 0 + o o 1 3 o - o 1 3 o o o 2 3 o o o 
ZrRhSb2 crystallizes in the triclinic P1 space group. Zr(1) is bonded in a 6-coordinate geometry to two equivalent Sb(1) and four equivalent Sb(2) atoms. There is one shorter (2.71 Å) and one longer (3.07 Å) Zr(1)-Sb(1) bond length. There are a spread of Zr(1)-Sb(2) bond distances ranging from 2.73-3.14 Å. Rh(1) is bonded in a distorted T-shaped geometry to one Sb(2) and two equivalent Sb(1) atoms. The Rh(1)-Sb(2) bond length is 2.03 Å. There is one shorter (2.33 Å) and one longer (2.64 Å) Rh(1)-Sb(1) bond length. There are two inequivalent Sb sites. In the first Sb site, Sb(1) is bonded in a 4-coordinate geometry to two equivalent Zr(1) and two equivalent Rh(1) atoms. In the second Sb site, Sb(2) is bonded in a 5-coordinate geometry to four equivalent Zr(1) and one Rh(1) atom.