data_SiTcCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.3
_cell_length_b   3.31
_cell_length_c   7.68
_cell_angle_alpha   90.0
_cell_angle_beta   98.59
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SiTcCl2
_chemical_formula_sum   'Si1 Tc1 Cl2'
_cell_volume   82.97
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Si  Si2  1  0.46  0.0  0.17  1.0
  Tc  Tc3  1  0.1  0.66  0.44  1.0
  Cl  Cl0  1  0.09  0.0  0.15  1.0
  Cl  Cl1  1  0.08  0.66  0.21  1.0

data_SiTcCl2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.3
_cell_length_b   3.31
_cell_length_c   7.68
_cell_angle_alpha   90.0
_cell_angle_beta   98.59
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SiTcCl2
_chemical_formula_sum   'Si1 Tc1 Cl2'
_cell_volume   82.97
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Tc  Tc0  1  0.1  0.66  0.44  1.0
  Si  Si1  1  0.46  0.0  0.17  1.0
  Cl  Cl2  1  0.08  0.66  0.21  1.0
  Cl  Cl3  1  0.09  0.0  0.15  1.0

Si Tc Cl Cl
Si Tc Cl Cl 0 2 o o o 1 3 o o o 2 3 o - o 
TcClSiCl crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one chlorosilicon molecule and one TcCl cluster. In the TcCl cluster, Tc(1) is bonded in a single-bond geometry to one Cl(2) atom. The Tc(1)-Cl(2) bond length is 1.71 Å. Cl(2) is bonded in a distorted single-bond geometry to one Tc(1) atom.