data_ZnInCl2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.28
_cell_length_b   6.28
_cell_length_c   5.36
_cell_angle_alpha   113.95
_cell_angle_beta   113.95
_cell_angle_gamma   35.14
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnInCl2
_chemical_formula_sum   'Zn1 In1 Cl2'
_cell_volume   110.27
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn3  1  0.94  0.0  0.73  1.0
  In  In2  1  0.18  0.0  0.14  1.0
  Cl  Cl0  1  0.14  0.0  0.07  1.0
  Cl  Cl1  1  0.28  0.0  0.35  1.0

data_ZnInCl2
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.79
_cell_length_b   5.36
_cell_length_c   6.28
_cell_angle_alpha   113.95
_cell_angle_beta   107.57
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ZnInCl2
_chemical_formula_sum   'Zn1 In1 Cl2'
_cell_volume   110.27
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Zn  Zn0  1  0.0  0.73  0.94  1.0
  In  In1  1  0.0  0.14  0.18  1.0
  Cl  Cl2  1  0.0  0.07  0.14  1.0
  Cl  Cl3  1  0.0  0.35  0.28  1.0

Zn In Cl Cl
Zn In Cl Cl 0 2 + o + 0 1 + o + 1 2 o o o 1 3 o o o 
ZnInCl2 is Cyanogen Chloride-like structured and crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one ZnInCl2 cluster. Zn(1) is bonded in a single-bond geometry to one Cl(1) atom. The Zn(1)-Cl(1) bond length is 1.76 Å. In(1) is bonded in a linear geometry to one Cl(1) and one Cl(2) atom. The In(1)-Cl(1) bond length is 0.34 Å. The In(1)-Cl(2) bond length is 1.08 Å. There are two inequivalent Cl sites. In the first Cl site, Cl(1) is bonded in a linear geometry to one Zn(1) and one In(1) atom. In the second Cl site, Cl(2) is bonded in a single-bond geometry to one In(1) atom.