data_SbW2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.13
_cell_length_b   3.13
_cell_length_c   8.78
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SbW2Cl
_chemical_formula_sum   'Sb1 W2 Cl1'
_cell_volume   85.77
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb1  1  0.56  0.56  0.16  1.0
  W  W2  1  0.0  0.0  0.38  1.0
  W  W3  1  0.56  0.56  0.89  1.0
  Cl  Cl0  1  0.0  0.0  0.74  1.0

data_SbW2Cl
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.42
_cell_length_b   4.42
_cell_length_c   8.78
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   SbW2Cl
_chemical_formula_sum   'Sb2 W4 Cl2'
_cell_volume   171.53
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sb  Sb0  2  0.06  0.5  0.16  1.0
  W  W1  2  0.0  0.0  0.38  1.0
  W  W2  2  0.06  0.5  0.89  1.0
  Cl  Cl3  2  0.0  0.0  0.74  1.0

Sb W W Cl
Sb W W Cl 0 1 o o o 0 1 o + o 0 1 + o o 0 1 + + o 0 0 + o o 0 0 o + o 0 2 o o - 1 1 + o o 1 1 o + o 1 3 o o o 2 3 o o o 2 3 o + o 2 3 + o o 2 3 + + o 
W2SbCl crystallizes in the monoclinic Cm space group. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 9-coordinate geometry to four equivalent W(1), four equivalent Sb(1), and one Cl(1) atom. All W(1)-W(1) bond lengths are 3.13 Å. There are a spread of W(1)-Sb(1) bond distances ranging from 2.74-3.16 Å. The W(1)-Cl(1) bond length is 3.10 Å. In the second W site, W(2) is bonded in a 5-coordinate geometry to one Sb(1) and four equivalent Cl(1) atoms. The W(2)-Sb(1) bond length is 2.42 Å. There are a spread of W(2)-Cl(1) bond distances ranging from 2.34-2.81 Å. Sb(1) is bonded in a 9-coordinate geometry to one W(2), four equivalent W(1), and four equivalent Sb(1) atoms. All Sb(1)-Sb(1) bond lengths are 3.13 Å. Cl(1) is bonded in a 5-coordinate geometry to one W(1) and four equivalent W(2) atoms.