data_ScBi2Rh
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.42
_cell_length_b   3.42
_cell_length_c   8.51
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   ScBi2Rh
_chemical_formula_sum   'Sc1 Bi2 Rh1'
_cell_volume   99.3
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc3  1  0.0  0.0  0.94  1.0
  Bi  Bi0  1  0.71  0.71  1.0  1.0
  Bi  Bi1  1  0.0  0.0  0.8  1.0
  Rh  Rh2  1  0.71  0.71  0.55  1.0

data_ScBi2Rh
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.83
_cell_length_b   4.83
_cell_length_c   8.51
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   ScBi2Rh
_chemical_formula_sum   'Sc2 Bi4 Rh2'
_cell_volume   198.6
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sc  Sc0  2  0.0  0.0  0.94  1.0
  Bi  Bi1  2  0.0  0.0  0.8  1.0
  Bi  Bi2  2  0.21  0.5  1.0  1.0
  Rh  Rh3  2  0.21  0.5  0.55  1.0

Sc Bi Bi Rh
Sc Bi Bi Rh 0 2 o o o 0 1 - - o 2 3 o - o 2 3 - o o 2 3 - - o 3 3 + o o 3 3 o + o 
ScRhBi2 crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two ScRhBi2 clusters. Sc(1) is bonded in a distorted water-like geometry to one Bi(1) and one Bi(2) atom. The Sc(1)-Bi(1) bond length is 1.49 Å. The Sc(1)-Bi(2) bond length is 1.22 Å. Rh(1) is bonded in a distorted single-bond geometry to one Bi(2) atom. The Rh(1)-Bi(2) bond length is 2.56 Å. There are two inequivalent Bi sites. In the first Bi site, Bi(1) is bonded in a distorted single-bond geometry to one Sc(1) atom. In the second Bi site, Bi(2) is bonded in a single-bond geometry to one Sc(1) and one Rh(1) atom.