data_NaCoPt
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   6.74
_cell_length_b   6.74
_cell_length_c   6.74
_cell_angle_alpha   156.2
_cell_angle_beta   156.2
_cell_angle_gamma   33.91
_symmetry_Int_Tables_number   1
_chemical_formula_structural   NaCoPt
_chemical_formula_sum   'Na1 Co1 Pt1'
_cell_volume   49.7
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na1  1  0.0  0.0  0.27  1.0
  Co  Co0  1  0.0  0.0  0.27  1.0
  Pt  Pt2  1  0.0  0.0  0.34  1.0

data_NaCoPt
_symmetry_space_group_name_H-M   Cm
_cell_length_a   3.93
_cell_length_b   3.93
_cell_length_c   6.74
_cell_angle_alpha   90.0
_cell_angle_beta   106.95
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   NaCoPt
_chemical_formula_sum   'Na2 Co2 Pt2'
_cell_volume   99.4
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  2  0.27  0.0  0.27  1.0
  Co  Co1  2  0.27  0.0  0.27  1.0
  Pt  Pt2  2  0.34  0.0  0.34  1.0

Na Co Pt 0 1 o o o 0 2 o o o 1 2 o o o 
NaCoPt is Cyanogen Chloride-like structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two NaCoPt clusters. Na(1) is bonded in a linear geometry to one Co(1) and one Pt(1) atom. The Na(1)-Co(1) bond length is 0.02 Å. The Na(1)-Pt(1) bond length is 0.49 Å. Co(1) is bonded in a single-bond geometry to one Na(1) atom. Pt(1) is bonded in a single-bond geometry to one Na(1) atom.