data_Na2CrPd
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   4.98
_cell_length_b   4.98
_cell_length_c   5.84
_cell_angle_alpha   98.89
_cell_angle_beta   98.89
_cell_angle_gamma   35.84
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Na2CrPd
_chemical_formula_sum   'Na2 Cr1 Pd1'
_cell_volume   83.62
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na1  1  0.5  0.0  0.75  1.0
  Na  Na2  1  0.0  0.0  0.47  1.0
  Cr  Cr0  1  0.56  0.0  0.97  1.0
  Pd  Pd3  1  0.24  0.0  0.21  1.0

data_Na2CrPd
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.06
_cell_length_b   4.98
_cell_length_c   5.84
_cell_angle_alpha   98.89
_cell_angle_beta   90.0
_cell_angle_gamma   107.92
_symmetry_Int_Tables_number   1
_chemical_formula_structural   Na2CrPd
_chemical_formula_sum   'Na2 Cr1 Pd1'
_cell_volume   83.62
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Na  Na0  1  0.0  0.5  0.25  1.0
  Na  Na1  1  0.0  1.0  0.53  1.0
  Cr  Cr2  1  0.0  0.44  0.03  1.0
  Pd  Pd3  1  0.0  0.76  0.79  1.0

Na Na Cr Pd
Na Na Cr Pd 0 2 o o o 1 3 o o o 2 3 o o + 
Na2CrPd crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of one Na2CrPd cluster. There are two inequivalent Na sites. In the first Na site, Na(1) is bonded in a single-bond geometry to one Cr(1) atom. The Na(1)-Cr(1) bond length is 1.24 Å. In the second Na site, Na(2) is bonded in a single-bond geometry to one Pd(1) atom. The Na(2)-Pd(1) bond length is 2.08 Å. Cr(1) is bonded in a distorted single-bond geometry to one Na(1) and one Pd(1) atom. The Cr(1)-Pd(1) bond length is 2.30 Å. Pd(1) is bonded in a distorted linear geometry to one Na(2) and one Cr(1) atom.