data_LiGaW2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.74
_cell_length_b   2.74
_cell_length_c   8.99
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   109.18
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiGaW2
_chemical_formula_sum   'Li1 Ga1 W2'
_cell_volume   63.64
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li1  1  0.0  0.0  0.33  1.0
  Ga  Ga0  1  0.59  0.0  0.47  1.0
  W  W2  1  0.59  0.0  0.95  1.0
  W  W3  1  0.0  0.0  0.72  1.0

data_LiGaW2
_symmetry_space_group_name_H-M   P1
_cell_length_a   2.74
_cell_length_b   2.74
_cell_length_c   8.99
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   109.18
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiGaW2
_chemical_formula_sum   'Li1 Ga1 W2'
_cell_volume   63.64
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  1  0.0  0.0  0.33  1.0
  Ga  Ga1  1  0.59  0.0  0.47  1.0
  W  W2  1  0.0  0.0  0.72  1.0
  W  W3  1  0.59  0.0  0.95  1.0

Li Ga W W
Li Ga W W 0 1 - o o 0 1 o o o 1 3 + o o 1 3 o o o 2 3 o o o 2 3 + o o 2 2 o + o 2 2 + o o 3 3 o + o 3 3 + o o 
LiW2Ga crystallizes in the triclinic P1 space group. Li(1) is bonded in a distorted L-shaped geometry to one W(1) and two equivalent Ga(1) atoms. The Li(1)-W(1) bond length is 3.58 Å. There is one shorter (1.68 Å) and one longer (2.03 Å) Li(1)-Ga(1) bond length. There are two inequivalent W sites. In the first W site, W(1) is bonded in a 7-coordinate geometry to one Li(1), two equivalent W(2), and four equivalent W(1) atoms. There is one shorter (2.38 Å) and one longer (2.63 Å) W(1)-W(2) bond length. All W(1)-W(1) bond lengths are 2.74 Å. In the second W site, W(2) is bonded in a 1-coordinate geometry to two equivalent W(1) and one Ga(1) atom. The W(2)-Ga(1) bond length is 2.53 Å. Ga(1) is bonded in a 2-coordinate geometry to two equivalent Li(1) and one W(2) atom.