data_LiB2Cl
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   2.76
_cell_length_b   2.76
_cell_length_c   7.52
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   LiB2Cl
_chemical_formula_sum   'Li1 B2 Cl1'
_cell_volume   57.2
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li3  1  0.0  0.0  0.66  1.0
  B  B0  1  0.38  0.38  0.59  1.0
  B  B1  1  0.0  0.0  0.62  1.0
  Cl  Cl2  1  0.38  0.38  0.41  1.0

data_LiB2Cl
_symmetry_space_group_name_H-M   Cm
_cell_length_a   3.9
_cell_length_b   3.9
_cell_length_c   7.52
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   LiB2Cl
_chemical_formula_sum   'Li2 B4 Cl2'
_cell_volume   114.39
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Li  Li0  2  0.0  0.0  0.66  1.0
  B  B1  2  0.0  0.0  0.62  1.0
  B  B2  2  0.38  0.0  0.59  1.0
  Cl  Cl3  2  0.38  0.0  0.41  1.0

Li B B Cl
Li B B Cl 0 2 o o o 0 1 o o o 1 2 o o o 1 3 o o o 
LiBBCl is alpha oxygen-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two chloroborane molecules and two lithium boron hydride molecules.