data_KTiCd2
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.22
_cell_length_b   3.22
_cell_length_c   10.11
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   KTiCd2
_chemical_formula_sum   'K1 Ti1 Cd2'
_cell_volume   104.93
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K2  1  0.0  0.0  0.98  1.0
  Ti  Ti3  1  0.61  0.61  0.18  1.0
  Cd  Cd0  1  0.0  0.0  0.03  1.0
  Cd  Cd1  1  0.61  0.61  0.11  1.0

data_KTiCd2
_symmetry_space_group_name_H-M   Cm
_cell_length_a   4.55
_cell_length_b   4.55
_cell_length_c   10.11
_cell_angle_alpha   90.0
_cell_angle_beta   90.0
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   8
_chemical_formula_structural   KTiCd2
_chemical_formula_sum   'K2 Ti2 Cd4'
_cell_volume   209.85
_cell_formula_units_Z   2
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
  2  'x, -y, z'
  3  'x+1/2, y+1/2, z'
  4  'x+1/2, -y+1/2, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  K  K0  2  0.0  0.0  0.98  1.0
  Ti  Ti1  2  0.11  0.5  0.18  1.0
  Cd  Cd2  2  0.0  0.0  0.03  1.0
  Cd  Cd3  2  0.11  0.5  0.11  1.0

K Ti Cd Cd
K Ti Cd Cd 0 2 o o + 1 3 o o o 
CdKTiCd is beta oxygen-derived structured and crystallizes in the monoclinic Cm space group. The structure is zero-dimensional and consists of two cadmium;potassium molecules and two TiCd clusters. In each TiCd cluster, Ti(1) is bonded in a single-bond geometry to one Cd(2) atom. The Ti(1)-Cd(2) bond length is 0.71 Å. Cd(2) is bonded in a single-bond geometry to one Ti(1) atom.