data_SrV2As
_symmetry_space_group_name_H-M   'P 1'
_cell_length_a   3.32
_cell_length_b   4.83
_cell_length_c   5.23
_cell_angle_alpha   90.0
_cell_angle_beta   94.58
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SrV2As
_chemical_formula_sum   'Sr1 V2 As1'
_cell_volume   83.54
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr1  1  0.45  0.0  0.61  1.0
  V  V2  1  0.39  0.41  0.92  1.0
  V  V3  1  0.51  0.41  0.3  1.0
  As  As0  1  0.0  0.0  0.0  1.0

data_SrV2As
_symmetry_space_group_name_H-M   P1
_cell_length_a   3.32
_cell_length_b   4.83
_cell_length_c   5.23
_cell_angle_alpha   90.0
_cell_angle_beta   94.58
_cell_angle_gamma   90.0
_symmetry_Int_Tables_number   1
_chemical_formula_structural   SrV2As
_chemical_formula_sum   'Sr1 V2 As1'
_cell_volume   83.54
_cell_formula_units_Z   1
loop_
 _symmetry_equiv_pos_site_id
 _symmetry_equiv_pos_as_xyz
  1  'x, y, z'
loop_
 _atom_site_type_symbol
 _atom_site_label
 _atom_site_symmetry_multiplicity
 _atom_site_fract_x
 _atom_site_fract_y
 _atom_site_fract_z
 _atom_site_occupancy
  Sr  Sr0  1  0.45  0.0  0.61  1.0
  V  V1  1  0.39  0.41  0.92  1.0
  V  V2  1  0.51  0.41  0.3  1.0
  As  As3  1  0.0  0.0  0.0  1.0

Sr V V As
Sr V V As 0 3 o o + 0 3 + o + 0 1 o o o 0 2 o o o 1 3 o o + 1 3 + o + 1 3 o + + 1 2 o o + 2 3 + o o 2 3 o o o 
SrV2As crystallizes in the triclinic P1 space group. Sr(1) is bonded in a 7-coordinate geometry to two equivalent V(1), two equivalent V(2), and three equivalent As(1) atoms. There is one shorter (2.59 Å) and one longer (3.27 Å) Sr(1)-V(1) bond length. There is one shorter (2.59 Å) and one longer (3.27 Å) Sr(1)-V(2) bond length. There are two shorter (2.64 Å) and one longer (3.40 Å) Sr(1)-As(1) bond length. There are two inequivalent V sites. In the first V site, V(1) is bonded in a 6-coordinate geometry to two equivalent Sr(1), one V(2), and three equivalent As(1) atoms. The V(1)-V(2) bond length is 2.00 Å. There are a spread of V(1)-As(1) bond distances ranging from 2.44-3.16 Å. In the second V site, V(2) is bonded in a 5-coordinate geometry to two equivalent Sr(1), one V(1), and two equivalent As(1) atoms. There is one shorter (2.98 Å) and one longer (3.07 Å) V(2)-As(1) bond length. As(1) is bonded in a 3-coordinate geometry to three equivalent Sr(1), two equivalent V(2), and three equivalent V(1) atoms.